Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Rhodium(III) fluoride or rhodium trifluoride is the inorganic compound with the formula RhF3. It is a red-brown, diamagnetic solid.
^hrsg. von Georg Brauer. Unter Mitarb. von M. Baudler (1975). Handbuch der präparativen anorganischen Chemie / 1 (in German). Stuttgart: Enke. p. 280. ISBN 3-432-02328-6. OCLC 310719485.
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Rhodium(III) fluoride or rhodiumtrifluoride is the inorganic compound with the formula RhF3. It is a red-brown, diamagnetic solid. The compound is prepared...
range of possible oxidation states. Rhodium(III) chloride, rhodiumtrifluoride, rhodium pentafluoride and rhodium hexafluoride are examples. The lower...
Rhodium pentafluoride is an inorganic compound with the formula Rh4F20. It is a red solid. It is prepared by fluorination of rhodiumtrifluoride at 400 °C...
Iridium trifluoride is a binary chemical compound of iridium and fluorine with the chemical formula IrF 3. Reduction of iridium hexafluoride by metallic...
also be used. Tertiary alcohols undergo facile reduction using boron trifluoride etherate as the Lewis acid. Primary alcohols require an excess of the...
exception. Bromine forms a monofluoride and monochloride, as well as a trifluoride and pentafluoride. Some cationic and anionic derivatives are also characterised...
oxidation reactions. Osmium pentafluoride (OsF 5) is known, but osmium trifluoride (OsF 3) has not yet been synthesized. The lower oxidation states are...
tetrachloride, normally incombustible, may explode. Although nitrogen trifluoride is stable, nitrogen requires an electric discharge at elevated temperatures...
easily obtained by burning lanthanum trifluoride in air at 800 °C for an hour, similar treatment of actinium trifluoride yields no AcOF and only results in...
salts may be prepared by the reaction of dioxygen difluoride with boron trifluoride or phosphorus pentafluoride at −126 °C: 2 O2F2 + 2 BF3 → 2 O2BF4 + F2...
isolated at low temperatures, and nitrous acid is unstable. Nitrogen trifluoride is the only stable nitrogen trihalide, with nitrogen trichloride, nitrogen...
exception. Iodine forms all three possible diatomic interhalogens, a trifluoride and trichloride, as well as a pentafluoride and, exceptionally among...
disproportionates at 100–120 °C to the trifluoride and the pentafluoride. The tetrafluorides of iridium, platinum, palladium, and rhodium all share the same structure...
observed in the neighboring metals niobium (41), molybdenum (42), and rhodium (45). Ruthenium has four crystal modifications and does not tarnish at...
gas; it burns in fluorine with a greenish-yellow flame to give nitrogen trifluoride. Reactions with the other nonmetals are very complex and tend to lead...
is that of gramine with phenylboronic acid catalyzed by cyclooctadiene rhodium chloride dimer: Boronic esters are oxidized to the corresponding alcohols...
such as sulfuric acid or the combination of phosphoric acid and boron trifluoride. The reaction is less applicable to simple alkene. The industrial synthesis...
225 °C, though it must then be separated and purified from chlorine trifluoride and its reactants. Its properties are mostly intermediate between those...
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