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Potassium manganate information


Potassium manganate
Names
IUPAC names
Potassium manganate
Potassium manganate(VI)
Identifiers
CAS Number
  • 10294-64-1 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 141385 checkY
ECHA InfoCard 100.030.592 Edit this at Wikidata
EC Number
  • 233-665-2
PubChem CID
  • 160931
UNII
  • 5PI213D3US checkY
CompTox Dashboard (EPA)
  • DTXSID10893107 Edit this at Wikidata
InChI
  • Key: XKYFHUXZPRFUTH-UHFFFAOYSA-N
  • InChI=1S/2K.Mn.4O/q2*+1;;;;2*-1
SMILES
  • [O-][Mn](=O)(=O)[O-].[K+].[K+]
Properties
Chemical formula
K2MnO4
Molar mass 197.132 g/mol
Appearance green crystals (darkening with time)[1]
Density 2.78 g/cm3, solid
Melting point 190 °C (374 °F; 463 K) (decomposition)
Solubility in water
decomposes
Acidity (pKa) 7.1
Structure
Crystal structure
isomorphous with K2SO4
Coordination geometry
tetrahedral anion
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
oxidizer
GHS labelling:
Pictograms
GHS03: OxidizingGHS07: Exclamation mark
Signal word
Warning
Hazard statements
H272, H315, H319, H335
Precautionary statements
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
1
0
1
OX
Related compounds
Related compounds
Potassium permanganate
Manganese dioxide
Potassium chromate
Potassium ferrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Potassium manganate is the inorganic compound with the formula K2MnO4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate (KMnO4), a common chemical.[1] Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.

  1. ^ a b Cite error: The named reference Ullmann was invoked but never defined (see the help page).

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Potassium manganate

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Potassium manganate is the inorganic compound with the formula K2MnO4. This green-colored salt is an intermediate in the industrial synthesis of potassium...

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Potassium permanganate

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dioxide, MnO2) and potassium carbonate to obtain a material that, when dissolved in water, gave a green solution (potassium manganate) which slowly shifted...

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Manganate

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O2 Potassium manganate is prepared industrially, as an intermediate to potassium permanganate, by dissolving manganese dioxide in molten potassium hydroxide...

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Barium manganate

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conditions. Barium manganate can be prepared from potassium manganate and barium chloride by salt metathesis to give insoluble barium manganate: BaCl2 + K2MnO4...

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Sodium manganate

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Sodium manganate is the inorganic compound with the formula Na2MnO4. This deep green solid is a rarely encountered analogue of the related salt K2MnO4...

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Chemical chameleon

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that still used in the production of potassium permanganate, oxidized manganese dioxide to potassium manganate which, acidified by carbon dioxide absorbed...

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Potassium hypomanganate

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Potassium hypomanganate is the inorganic compound with the formula K3MnO4. Also known as potassium manganate(V), this bright blue solid is a rare example...

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Permanganate

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not very stable thermally. For instance, potassium permanganate decomposes at 230 °C to potassium manganate and manganese dioxide, releasing oxygen gas:...

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Manganese dioxide

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example, an oxidation with potassium permanganate). Heating a mixture of KOH and MnO 2 in air gives green potassium manganate: 2 MnO 2 + 4 KOH + O 2 → 2...

Word Count : 1858

Potassium ferrate

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3 O2 → 4 K2FeO4 + 4 H2O The composition corresponded to that of potassium manganate. In the laboratory, K2FeO4 is prepared by oxidizing an alkaline solution...

Word Count : 632

List of inorganic compounds

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KIO3 Potassium manganate – K2MnO4 Potassium monopersulfate – K2SO4·KHSO4·2KHSO5 Potassium nitrate – KNO3 Potassium perbromate – KBrO4 Potassium perchlorate...

Word Count : 8726

IUPAC nomenclature of inorganic chemistry

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calling it "iron(III) chloride"), but names like "potassium permanganate" (instead of "potassium manganate(VII)") and "sulfuric acid" abound. An ionic compound...

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List of inorganic pigments

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synthetic pigment discovered in 2009 (YIn1−xMnxO3). Manganese blue: barium manganate(VI) sulfate. Arsenic Pigments Scheele's Green: yellowish-green pigment...

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Stock nomenclature

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FeCl3: iron(III) chloride KMnO4: potassium manganate(VII) (rarely used except in pre-university education; potassium permanganate is ubiquitous) [Co(NH3)6]3+:...

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Glossary of chemical formulae

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KNO2 potassium nitrite 7758-09-0 K2CO3 potassium carbonate 584-08-7 K2MnO4 potassium manganate 10294-64-1 K2N2O2 potassium hyponitrite KNbO3 potassium niobate...

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Oxidizing agent

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illustrated by the conversion of MnO− 4 to MnO2− 4,ie permanganate to manganate. Oxygen (O2) Ozone (O3) Hydrogen peroxide (H2O2) and other inorganic peroxides...

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Ammonium permanganate

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NH4Cl → AgCl + NH4MnO4 It can also be prepared in a similar way from potassium permanganate and ammonium chloride. KMnO4 +NH4Cl → KCl + NH4MnO4 Ammonium...

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Sodium permanganate

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prepared analogously to the route to KMnO4 because the required intermediate manganate salt, Na2MnO4, does not form. Thus less direct routes are used including...

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Rubidium permanganate

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decomposition of rubidium permanganate leads to the formation of rubidium manganate intermediates. It breaks down into manganese dioxide, rubidium oxide and...

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Hypomanganate

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In chemistry, hypomanganate, also called manganate(V) or tetraoxidomanganate(3−), is a trivalent anion (negative ion) composed of manganese and oxygen...

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Permanganometry

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concentration c(NaOH) >1 mol dm−3, only one electron is accepted to produce manganate: MnO−4 + e− → MnO2−4; E° = +0.56 V Redox titrations: Permanganometry....

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Psilomelane

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(Ba,H2O)2Mn5O10. It is sometimes considered to be a hydrous manganese manganate, but of doubtful composition. The amount of manganese present corresponds...

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Barium permanganate

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Barium permanganate may be produced by disproportionation of barium manganate in a mildly acidic solution, including solutions carbon dioxide or sulfuric...

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Caesium permanganate

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decomposition of caesium permanganate leads to the formation of caesium manganate intermediates. It breaks down into manganese dioxide, caesium oxide and...

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Color of chemicals

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pink Manganese(III) Mn3+   Crimson Manganate(V) MnO3− 4   Deep blue Manganate(VI) MnO2− 4   Dark green Manganate(VII) (permanganate) MnO− 4   Deep purple...

Word Count : 751

Transition metal oxalate complex

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S2CID 96021604. Lis, T.; Matuszewski, J. (1980). "Structure of potassium tris(oxalato)manganate(III) trihydrate". Acta Crystallographica Section B. 36 (8):...

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Manganese

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example of Mn in the +6 oxidation state is the green anion manganate, [MnO4]2−. Manganate salts are intermediates in the extraction of manganese from...

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Blue pigments

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synthetic pigment discovered in 2009 (YIn1−xMnxO3). Manganese blue: barium manganate(VI) sulfate. Bomford and Roy, "A Closer Look at Colour" (2009), p. 28-37...

Word Count : 2218

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