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Permanganate information


Permanganate
Lewis structure of the manganate(VII) anion
Names
Systematic IUPAC name
Permanganate
Identifiers
CAS Number
  • 14333-13-2
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:25939
ChemSpider
  • 22811
PubChem CID
  • 24401
UNII
  • 2BL953CCZ2
CompTox Dashboard (EPA)
  • DTXSID90912340
InChI
  • InChI=1S/Mn.4O/q;;;;-1
    Key: NPDODHDPVPPRDJ-UHFFFAOYSA-N
SMILES
  • [O-] [Mn](=O)(=O)=O
Properties
Chemical formula
MnO
4
Molar mass 118.934 g·mol−1
Conjugate acid Permanganic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

A permanganate (/pərˈmæŋɡənt, pɜːr-/)[1] is a chemical compound with the manganate(VII) ion, MnO
4
, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure.[2] Permanganate solutions are purple in colour and are stable in neutral or slightly alkaline media. The exact chemical reaction depends on the carbon-containing reactants present and the oxidant used. For example, trichloroethane (C2H3Cl3) is oxidised by permanganate ions to form carbon dioxide (CO2), manganese dioxide (MnO2), hydrogen ions (H+), and chloride ions (Cl).[3]

8MnO
4
+ 3C
2
H
3
Cl
3
→ 6CO
2
+ 8MnO
2
+ H+
+ 4H
2
O
+ 9Cl

In an acidic solution, permanganate(VII) is reduced to the pale pink manganese(II) (Mn2+) with an oxidation state of +2.

H+
+ MnO
4
+ 5 e → Mn2+ + 4 H2O

In a strongly basic or alkaline solution, permanganate(VII) is reduced to the green manganate ion, MnO2−
4
with an oxidation state of +6.

MnO
4
+ eMnO2−
4

In a neutral solution, however, it gets reduced to the brown manganese dioxide MnO2 with an oxidation state of +4.

2 H2O + MnO
4
+ 3 e → MnO2 + 4 OH
  1. ^ "permanganate". Merriam-Webster.com Dictionary.
  2. ^ Sukalyan Dash, Sabita Patel & Bijay K. Mishra (2009). "Oxidation by permanganate: synthetic and mechanistic aspects". Tetrahedron. 65 (4): 707–739. doi:10.1016/j.tet.2008.10.038.
  3. ^ "Geo-Cleanse International, INC. | Permanganate".

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Potassium permanganate

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Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+...

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Permanganate

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A permanganate (/pərˈmæŋɡəneɪt, pɜːr-/) is a chemical compound with the manganate(VII) ion, MnO− 4, the conjugate base of permanganic acid. Because the...

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Sodium permanganate

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Sodium permanganate is the inorganic compound with the formula NaMnO4. It is closely related to the more commonly encountered potassium permanganate, but...

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Lithium permanganate

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permanganate is an inorganic compound with the chemical formula LiMnO4. It can be produced by the reaction of lithium sulfate and barium permanganate...

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Caesium permanganate

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Caesium permanganate is the permanganate salt of caesium, with the chemical formula CsMnO4. Caesium permanganate can be formed by the reaction of potassium...

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Ammonium permanganate

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Ammonium permanganate is the chemical compound NH4MnO4, or NH3·HMnO4. It is a water soluble, violet-brown or dark purple salt. Ammonium permanganate was first...

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Permanganate index

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The permanganate index is an assessment of water quality. It involves the detection of oxidation by potassium permanganate in an acid medium under hot...

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Calcium permanganate

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Calcium permanganate is an oxidizing agent and chemical compound with the chemical formula Ca(MnO4)2. This salt consists of the metal calcium and two permanganate...

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Glycerol and potassium permanganate

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between potassium permanganate and glycerol is often used to demonstrate the powerful oxidizing property of potassium permanganate, especially in the...

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Silver permanganate

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Silver permanganate is an inorganic compound with the chemical formula AgMnO4. This salt is a purple crystal adopting a monoclinic crystal system. It decomposes...

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Magnesium permanganate

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Magnesium permanganate is an inorganic compound with the chemical formula Mg(MnO4)2. It can be used as an oxidant. Magnesium permanganate hexahydrate...

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Rubidium permanganate

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Rubidium permanganate is the permanganate salt of rubidium, with the chemical formula RbMnO 4. Rubidium permanganate can be formed by the reaction of...

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Oxidizing agent

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compounds such as Sodium dichromate (Na2Cr2O7) Permanganate compounds such as potassium permanganate (KMnO4) Sodium perborate ([Na+ ] 2·[B 2O 4(OH) 4]2−...

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Permanganic acid

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oxoacid has been isolated as its dihydrate. It is the conjugate acid of permanganate salts. It is the subject of few publications and its characterization...

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Barium permanganate

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Barium permanganate is a chemical compound, with the formula Ba(MnO4)2. It forms violet to brown crystals that are sparingly soluble in water. Barium permanganate...

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Cadmium permanganate

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Cadmium permanganate is an inorganic compound with the chemical formula Cd(MnO4)2. It can form the hexahydrate Cd(MnO4)2·6H2O. Cadmium permanganate can be...

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Potassium manganate

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synthesis of potassium permanganate (KMnO4), a common chemical. Occasionally, potassium manganate and potassium permanganate are confused, but each compound's...

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Manganese

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familiar in the laboratory in the form of the deep violet salt potassium permanganate. It occurs at the active sites in some enzymes. Of particular interest...

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Chemical chameleon

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Glauber reported the first description of the production of potassium permanganate when he noted that manganese dioxide (as the mineral pyrolusite) could...

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Sodium oxalate

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and it may be used as a primary standard for standardizing potassium permanganate (KMnO4) solutions. The mineral form of sodium oxalate is natroxalate...

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Permanganometry

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titration of the analyte with potassium permanganate solution and then the standardization of potassium permanganate solution with standard sodium oxalate...

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Kappa number

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range of 1–100. The Kappa number is a measurement of standard potassium permanganate solution that the pulp will consume. The measurement is inflated by the...

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Manganate

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compounds. Other manganates include hypomanganate or manganate(V), MnO3− 4, permanganate or manganate(VII), MnO− 4, and the dimanganate or dimanganate(III) Mn...

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Carboxylic acid

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strong oxidants such as potassium dichromate, Jones reagent, potassium permanganate, or sodium chlorite. The method is more suitable for laboratory conditions...

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Redox

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drops of glycerol (mild reducing agent) are added to powdered potassium permanganate (strong oxidizing agent), a violent redox reaction accompanied by self-ignition...

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Methcathinone

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Potassium permanganate (KMnO4) is most commonly used as the oxidant. In clandestine laboratories, synthesizing methcathinone using potassium permanganate is...

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Petroleum ether

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of a concentrated solution of potassium permanganate in 10% sulfuric acid until the color of the permanganate remains unchanged. The solvent is then thoroughly...

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In situ chemical oxidation

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Fenton's reagent (hydrogen peroxide catalyzed with iron) and potassium permanganate are the oxidants that have been used the longest and remain used widely...

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