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Manganese dioxide information


Manganese dioxide
Manganese(IV) oxideMn4O2
Names
IUPAC names
Manganese dioxide
Manganese(IV) oxide
Other names
Pyrolusite, hyperoxide of manganese, black oxide of manganese, manganic oxide
Identifiers
CAS Number
  • 1313-13-9 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:136511 ☒N
ChemSpider
  • 14117 checkY
ECHA InfoCard 100.013.821 Edit this at Wikidata
EC Number
  • 215-202-6
PubChem CID
  • 14801
RTECS number
  • OP0350000
UNII
  • TF219GU161 checkY
CompTox Dashboard (EPA)
  • DTXSID501314019 DTXSID6042109, DTXSID501314019 Edit this at Wikidata
InChI
  • InChI=1S/Mn.2O checkY
    Key: NUJOXMJBOLGQSY-UHFFFAOYSA-N checkY
SMILES
  • O=[Mn]=O
Properties
Chemical formula
MnO
2
Molar mass 86.9368 g/mol
Appearance Brown-black solid
Density 5.026 g/cm3
Melting point 535 °C (995 °F; 808 K) (decomposes)
Solubility in water
Insoluble
Magnetic susceptibility (χ)
+2280.0×10−6 cm3/mol[1]
Structure[2]
Crystal structure
Tetragonal, tP6, No. 136
Space group
P42/mnm
Lattice constant
a = 0.44008 nm, b = 0.44008 nm, c = 0.28745 nm
Formula units (Z)
2
Thermochemistry[3]
Heat capacity (C)
54.1 J·mol−1·K−1
Std molar
entropy (S298)
53.1 J·mol−1·K−1
Std enthalpy of
formation fH298)
−520.0 kJ·mol−1
Gibbs free energy fG)
−465.1 kJ·mol−1
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H302, H332
Precautionary statements
P261, P264, P270, P271, P301+P312, P304+P312, P304+P340, P312, P330, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g. white phosphorusSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
2
1
2
OX
Flash point 535 °C (995 °F; 808 K)
Safety data sheet (SDS) ICSC 0175
Related compounds
Other anions
Manganese disulfide
Other cations
Technetium dioxide
Rhenium dioxide
Related manganese oxides
Manganese(II) oxide
Manganese(II,III) oxide
Manganese(III) oxide
Manganese heptoxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Manganese dioxide is the inorganic compound with the formula MnO
2
. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO
2
is for dry-cell batteries, such as the alkaline battery and the zinc–carbon battery.[4] MnO
2
is also used as a pigment and as a precursor to other manganese compounds, such as KMnO
4
. It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. MnO
2
has an α-polymorph that can incorporate a variety of atoms (as well as water molecules) in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in α-MnO
2
as a possible cathode for lithium-ion batteries.[5][6]

  1. ^ Rumble, p. 4.71
  2. ^ Haines, J.; Léger, J.M.; Hoyau, S. (1995). "Second-order rutile-type to CaCl2-type phase transition in β-MnO2 at high pressure". Journal of Physics and Chemistry of Solids. 56 (7): 965–973. Bibcode:1995JPCS...56..965H. doi:10.1016/0022-3697(95)00037-2.
  3. ^ Rumble, p. 5.25
  4. ^ Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. pp. 1218–20. ISBN 978-0-08-022057-4..
  5. ^ Barbato, S (31 May 2001). "Hollandite cathodes for lithium ion batteries. 2. Thermodynamic and kinetics studies of lithium insertion into BaMMn7O16 (M=Mg, Mn, Fe, Ni)". Electrochimica Acta. 46 (18): 2767–2776. doi:10.1016/S0013-4686(01)00506-0. hdl:10533/173039.
  6. ^ Tompsett, David A.; Islam, M. Saiful (25 June 2013). "Electrochemistry of Hollandite α-MnO : Li-Ion and Na-Ion Insertion and Li Incorporation". Chemistry of Materials. 25 (12): 2515–2526. CiteSeerX 10.1.1.728.3867. doi:10.1021/cm400864n.

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