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Transition metal oxalate complex information


Transition metal oxalate complexes are coordination complexes with oxalate (C2O42−) ligands. Some are useful commercially, but the topic has attracted regular scholarly scrutiny. Oxalate (C2O42-) is a kind of dicarboxylate ligand.[1] As a small, symmetrical dinegative ion, oxalate commonly forms five-membered MO2C2 chelate rings. Mixed ligand complexes are known, e.g., [Co(C2O4)(NH3)4]κ+.[2]

  1. ^ Krishnamurty, Kotra V.; Harris, Gordon M. (1961). "The Chemistry of the Metal Oxalato Complexes". Chemical Reviews. 61 (3): 213–246. doi:10.1021/cr60211a001.
  2. ^ Bernal, Ivan; Cetrullo, James (1990). "The phenomenon of conglomerate crystallization. XIX. Clavic dissymmetry in coordination compounds. XVII". Structural Chemistry. 1 (2–3): 235–243. doi:10.1007/BF00674267. S2CID 96021604.

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Transition metal oxalate complex

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Transition metal oxalate complexes are coordination complexes with oxalate (C2O42−) ligands. Some are useful commercially, but the topic has attracted...

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Potassium ferrioxalate

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K+. The anion is a transition metal oxalate complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate C2O2−4 ligands. Potassium...

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Coordination complex

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turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that...

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Transition metal

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Transition metals in the periodic table In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic...

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Transition metal carboxylate complex

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Transition metal carboxylate complexes are coordination complexes with carboxylate (RCO2−) ligands. Reflecting the diversity of carboxylic acids, the...

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Oxalic acid

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dimethyl oxalate (m.p. 52.5 to 53.5 °C, 126.5 to 128.3 °F). It forms an acid chloride called oxalyl chloride. Transition metal oxalate complexes are numerous...

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Potassium ferrooxalate

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K2Fe(C2O4)2(H2O)x. The anion is a transition metal oxalate complex, consisting of an atom of iron in the +2 oxidation state bound to oxalate (C 2O2− 4) ligands and...

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Octahedral molecular geometry

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compounds. Octahedral transition-metal complexes containing amines and simple anions are often referred to as Werner-type complexes. When two or more types...

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Metal ions in aqueous solution

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of the chloro complex [Mo2Cl8]4−. There are a few divalent and trivalent aqua ions of transition metals in the second and third transition series: ruthenium(II)...

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Oxalate chloride

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fluorides and oxalate bromides. Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved...

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Sodium ferrioxalate

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cations Na+. The anion is a transition metal complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate ions C2O2−4 anions serving...

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Silver

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lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in...

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Ate complex

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was introduced by Georg Wittig in 1958. Ate complexes are common for metals, including the transition metals (groups 3-11), as well as the metallic or semi-metallic...

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Oxalate nitrate

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anions. Oxalate acts as a ligand, which normally complexes two metal atoms. An oxalate nitrate compound may also be called a nitrate oxalate. In chemical...

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Oxalate sulfate

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compounds include the sulfite oxalates and oxalate selenates. Oxalate sulfates may be deposited from a solution in water of the metal anions and sulfate with...

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Caesium oxalate

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element in addition to the oxalate anion are double salts of caesium and oxalate. The oxalate may form a complex with a metal that can make a salt with...

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Metal dithiolene complex

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Dithiolene metal complexes are complexes containing 1,2-dithiolene ligands. 1,2-Dithiolene ligands, a particular case of 1,2-dichalcogenolene species...

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Ligand

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functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...

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Ferrioxalate

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[Fe(C2O4)3]3−. It is a transition metal complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate ions C2O2−4 anions acting...

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Indene

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a ligand in organometallic chemistry, giving rise to many transition metal indenyl complexes. Indane Indole Isoindene Indenyl effect Indenone International...

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Inner sphere electron transfer

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thiocyanate. More complex bridging ligands are also well known including oxalate, malonate, and pyrazine. Prior to ET, the bridged complex must form, and...

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Carbon compounds

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important oxalates include Ag2C2O4, BaC2O4, CaC2O4, Ce2(C2O4)3, K2C2O4, and Na2C2O4. Carbonyls are coordination complexes between transition metals and carbonyl...

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Salsola tragus

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needle-like crystals of calcium oxalate monohydrate inside such cells, called Raphides. Calcium along with other metal ions are sequestered in idioblast...

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Nickel organic acid salts

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dihydrate dehydrates at 258° and decomposes to Ni metal over 316 °C. Double oxalate salts where oxalate is a ligand on the nickel atom may be called oxalatonickelates...

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Iron compounds

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Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of...

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Iron

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(from Latin ferrum 'iron') and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass...

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Carbonylation

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These reactions require metal catalysts, which bind and activate the CO. These processes involve transition metal acyl complexes as intermediates. Much...

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Yttrium

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element; it has symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified...

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