Organogallium chemistry is the chemistry of organometallic compounds containing a carbon to gallium (Ga) chemical bond. Despite their high toxicity [citation needed], organogallium compounds have some use in organic synthesis. The compound trimethylgallium is of some relevance to MOCVD as a precursor to gallium arsenide via its reaction with arsine at 700 °C:
Ga(CH3)3 + AsH3 → GaAs + 3CH4
Gallium trichloride is an important reagent for the introduction of gallium into organic compounds.
The main gallium oxidation state is Ga(III), as in all lower group 13 elements (such as aluminium).[1][2]
^C. Elschenbroich, A. Salzer Organometallics : A Concise Introduction (2nd Ed) (1992) from Wiley-VCH: Weinheim. ISBN 3-527-28165-7
^Chemistry of aluminium, gallium, indium, and thallium Anthony John Downs (Ed.) ISBN 978-0-7514-0103-5, 1993
and 19 Related for: Organogallium chemistry information
Organogalliumchemistry is the chemistry of organometallic compounds containing a carbon to gallium (Ga) chemical bond. Despite their high toxicity [citation...
formation of dimers: an example is [Ga(η6-C6H6)2] [GaCl4]·3C6H6. Organogalliumchemistry Category:Gallium compounds Aluminium compounds Indium compounds...
> Ga > In and as a result organogallium compounds do not form bridged dimers as organoaluminium compounds do. Organogallium compounds are also less reactive...
of compounds with a carbon-carbon triple bond. It is a precursor to organogallium reagents. It is also used as a catalyst in many organic reactions. 110...
Haynes, p. 12.86 Haynes, p. 12.81 Moss, S. J.; Ledwith, A. (1987). The Chemistry of the Semiconductor Industry. Springer. ISBN 978-0-216-92005-7. Scheel...
are known. WebElements Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8...
Trimethylgallium, often abbreviated to TMG or TMGa, is the organogallium compound with the formula Ga(CH3)3. It is a colorless, pyrophoric liquid. Unlike...
Epitaxy Lithium-ion battery Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.64. ISBN 1-4398-5511-0...
Hydrogallation and Hydroindation: Novel Access to Organogalliums and Organoindiums". The Journal of Organic Chemistry. 68 (17): 6627–6631. doi:10.1021/jo0344790...
PMID 20052186. S2CID 15879811. Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. ISBN 9781498754293. GaP. refractiveindex...
at drugs.com Green, MA; Welch, MJ (1989). "Gallium radiopharmaceutical chemistry". Int J Rad Appl Instrum B. 16 (5): 435–448. doi:10.1016/0883-2897(89)90053-6...
shipping". www.ottokemi.com. Retrieved 2022-05-05. Funk, H.; Paul, A. Chemistry of gallium. II. Reactions between gallium and organic compounds. Zeitschrift...
include tetrahydrofuran, and diethyl ether. Digallane "Gallane". The Chemistry of Aluminium, Gallium, Indium and Thallium, Anthony John Downs, 1993,...
metal and iodine in the presence of an alkyl iodide. Since then, other organogallium complexes have been synthesized, as well as Lewis base adducts and gallium...
doi:10.1021/ja00014a003. N.N. Greenwood (2001). "Main group element chemistry at the millennium". J. Chem. Soc., Dalton Trans. (14): 2055–2066. doi:10...
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