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Vinyl iodide functional group information


General structure of vinyl iodides

In organic chemistry, a vinyl iodide (also known as an iodoalkene) functional group is an alkene with one or more iodide substituents. Vinyl iodides are versatile molecules that serve as important building blocks and precursors in organic synthesis. They are commonly used in carbon-carbon forming reactions in transition-metal catalyzed cross-coupling reactions, such as Stille reaction, Heck reaction, Sonogashira coupling, and Suzuki coupling.[1] Synthesis of well-defined geometry or complexity vinyl iodide is important in stereoselective synthesis of natural products and drugs.

  1. ^ Xie, Meihua; Wang, Jialiang; Zhang, Wei; Wang, Shaowu (2009-06-15). "Regio- and stereospecific synthesis of vinyl halides via carbozincation of acetylenic sulfones followed by halogenation". Journal of Organometallic Chemistry. 694 (14): 2258–2262. doi:10.1016/j.jorganchem.2009.03.006. ISSN 0022-328X.

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Vinyl iodide functional group

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chemistry, a vinyl iodide (also known as an iodoalkene) functional group is an alkene with one or more iodide substituents. Vinyl iodides are versatile...

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Vinyl group

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In organic chemistry, a vinyl group (abbr. Vi; IUPAC name: ethenyl group) is a functional group with the formula −CH=CH2. It is the ethylene (IUPAC name:...

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Vinyl halide

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Suzuki-Miyaura coupling, Stille coupling, Heck coupling, etc.). Vinyl iodide functional group E.-L. Dreher; T. R. Torkelson; K. K. Beutel (2011). "Chlorethanes...

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Functional group

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a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will...

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Carbonyl group

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For organic chemistry, a carbonyl group is a functional group with the formula C=O, composed of a carbon atom double-bonded to an oxygen atom, and it...

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Halocarbon

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action of thioamides (TH synthesis blockers). In addition, the functionality of iodides fades after the initial treatment period. An "escape from block"...

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Phenyl group

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be replaced by some other element or compound to serve as a functional group. A phenyl group has six carbon atoms bonded together in a hexagonal planar...

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Acetyl group

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In organic chemistry, acetyl is a functional group with the chemical formula −COCH3 and the structure −C(=O)−CH3. It is sometimes represented by the symbol...

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Benzyl group

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temperature Ozone N-Bromosuccinimide (NBS) N-Iodosuccinimide (NIS) Trimethylsilyl iodide (Me3SiI) in dichloromethane at ambient temperature (selectivity can be achieved...

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Methine group

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In organic chemistry, a methine group or methine bridge is a trivalent functional group =CH−, derived formally from methane. It consists of a carbon atom...

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Hydroxy group

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In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula −OH and composed of one oxygen atom covalently bonded to one...

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Benzoyl group

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the functional group with the formula −COC6H5 and structure −C(=O)−C6H5. It can be viewed as benzaldehyde missing one hydrogen. The benzoyl group has...

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Nitro compound

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contain one or more nitro functional groups (−NO2). The nitro group is one of the most common explosophores (functional group that makes a compound explosive)...

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Alkoxy group

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alkoxy group is an alkyl group which is singularly bonded to oxygen; thus R−O. Denoted usually with apostrophe('). The range of alkoxy groups is vast...

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Methoxy group

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organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen. This alkoxy group has the formula R−O−CH3. On...

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Ethyl group

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"ethyl" was coined in 1835 by the Swedish chemist Jöns Jacob Berzelius. Functional group Welch, Vincent A.; Fallon, Kevin J.; Gelbke, Heinz-Peter (2005). "Ethylbenzene"...

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Imine

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In organic chemistry, an imine (/ɪˈmiːn/ or /ˈɪmɪn/) is a functional group or organic compound containing a carbon–nitrogen double bond (C=N). The nitrogen...

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Alkyl group

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In organic chemistry, an alkyl group is an alkane missing one hydrogen. The term alkyl is intentionally unspecific to include many possible substitutions...

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Carboxylic acid

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participate in hydrogen bonding. Together, the hydroxyl and carbonyl group form the functional group carboxyl. Carboxylic acids usually exist as dimers in nonpolar...

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Methyl group

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that reacts by the SN2 pathway: CH3OH + H+ → [CH3OH2]+ Similarly, methyl iodide and methyl triflate are viewed as the equivalent of the methyl cation because...

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Allyl group

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an allyl group is a substituent with the structural formula −CH2−HC=CH2. It consists of a methylene bridge (−CH2−) attached to a vinyl group (−CH=CH2)...

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Acetoxy group

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In organic chemistry, the acetoxy group (abbr. AcO or OAc; IUPAC name: acetyloxy), is a functional group with the formula −OCOCH3 and the structure −O−C(=O)−CH3...

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Sulfonyl halide

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In inorganic chemistry, sulfonyl halide groups occur when a sulfonyl (>S(=O)2) functional group is singly bonded to a halogen atom. They have the general...

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Aldehyde

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(/ˈældɪhaɪd/) is an organic compound containing a functional group with the structure R−CH=O. The functional group itself (without the "R" side chain) can be...

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Isocyanate

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chemistry, isocyanate is the functional group with the formula R−N=C=O. Organic compounds that contain an isocyanate group are referred to as isocyanates...

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Methylene group

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A methylene group is any part of a molecule that consists of two hydrogen atoms bound to a carbon atom, which is connected to the remainder of the molecule...

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Organic sulfide

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sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity R−S−R' as shown on right. Like many other sulfur-containing...

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Butyl group

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non-specific functional group. Butyl is the largest substituent for which trivial names are commonly used for all isomers. The butyl group's carbon that...

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