Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Nitrosyl bromide is the chemical compound with the chemical formula NOBr. It is a red gas with a condensing point just below room temperature.[1] It reacts with water.[1]
Nitrosyl bromide can be formed by the reversible reaction of nitric oxide with bromine.[2] This reaction is of interest as it is one of very few third-order homogeneous gas reactions. NOBr is prone to photodissociation at standard pressure and temperature.
2 NO + Br2 ⇌ 2 NOBr
Another way to make it is by way of nitric oxide reacting with potassium bromide.[1]
2NO2 + KBr → BrNO + KNO3
^ abcRatcliffe, Charles T.; Shreeve, Jean'ne M.; Wynne, Kenneth J. (January 1968). "Nitrosyl Halides". Inorganic Syntheses. Vol. 11. pp. 194–200. doi:10.1002/9780470132425.ch39. ISBN 9780470131701.
^Esposti, C.D.; Tamassia, F.; Cazzoli, G.; Kisiel, Z. (April 1995). "Millimeter-Wave Spectrum of Nitrosyl Bromide in the Low-Lying Excited States: Equilibrium Structure and Cubic Force Field". Journal of Molecular Spectroscopy. 170 (2): 582–600. Bibcode:1995JMoSp.170..582E. doi:10.1006/jmsp.1995.1093.
Nitrosylbromide is the chemical compound with the chemical formula NOBr. It is a red gas with a condensing point just below room temperature. It reacts...
Nitrosyl chloride is the chemical compound with the formula NOCl. It is a yellow gas that is commonly encountered as a component of aqua regia, a mixture...
much the same way and has often been used as an ionising solvent. Nitrosylbromide (NOBr) is red. The reactions of the nitryl halides are mostly similar:...
Nitrosyl fluoride (NOF) is a covalently bonded nitrosyl compound. The compound is a colorless gas, with bent molecular shape. The VSEPR model explains...
fluorinating agent. Nitrosyl chloride (NOCl) behaves in much the same way and has often been used as an ionising solvent. Nitrosylbromide (NOBr) is red. The...
isolated. Anhydrous hydrogen bromide is a poor solvent, only able to dissolve small molecular compounds such as nitrosyl chloride and phenol, or salts...
prepared by Adolf von Baeyer by the reaction of diphenylmercury and nitrosylbromide: (C6H5)2Hg + BrNO → C6H5NO + C6H5HgBr A modern synthesis entails reduction...
oxide reacts with fluorine, chlorine, and bromine to form the nitrosyl halides, such as nitrosyl chloride: 2 •NO + Cl2 → 2 NOCl With NO2, also a radical, NO...
Nickelocene reacts with nitric acid to produce cyclopentadienyl nickel nitrosyl, a highly toxic organonickel compound. International Union of Pure and...
isolated. Anhydrous hydrogen bromide is a poor solvent, only able to dissolve small molecular compounds such as nitrosyl chloride and phenol, or salts...
Related compounds Related compounds Nitroxyl Nitrous acid NitrosylbromideNitrosyl chloride Nitrosyl fluoride Except where otherwise noted, data are given...
insoluble in cold. Diammine, monoammine, and dihydrazine nickel bromides also exist. With four bromide atoms nickel(II) forms a series of salts called tetrabromonickelates...
258 K) Related compounds Other anions nitryl fluoride, nitryl bromide Other cations nitrosyl chloride, sulfuryl chloride Related compounds chloro nitrite...
SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium...
angles are 106.2 and 92.2°, respectively. Thionyl chloride and thionyl bromide have similar structures, although these compounds are liquid at room temperature...
halogenate carbon monoxide, nitric oxide, and sulfur dioxide (to phosgene, nitrosyl chloride, and sulfuryl chloride respectively), iodine will not do so. Furthermore...
whereas bromoform is the solvent of choice for the synthesis of aryl bromides. Amyl nitrite, in common with other alkyl nitrites, is a potent vasodilator;...
3 Dinitrogen tetroxide UN 1068 ? (UN No. no longer in use) UN 1069 2.3 Nitrosyl chloride UN 1070 2.2 Nitrous oxide UN 1071 2.3 Oil gas, compressed UN 1072...
1021/ic50010a048. Faloon, Albert V.; Kenna, William B. (1951). "The Preparation of Nitrosyl Fluoride and Nitryl Fluoride1". Journal of the American Chemical Society...
compounds containing anions composed of bromide (Br−) and antimony (Sb). They can be considered as double bromides, metallohalides or halometallates. They...
phenylmagnesium bromide with chromium(III) chloride to give a new product (after hydrolysis) which he incorrectly identified as pentaphenyl chromium bromide (Ph5CrBr)...
halogenate carbon monoxide, nitric oxide, and sulfur dioxide (to phosgene, nitrosyl chloride, and sulfuryl chloride respectively), iodine will not do so. Furthermore...
Global Information
