Organochromium chemistry is a branch of organometallic chemistry that deals with organic compounds containing a chromium to carbon bond and their reactions.[1][2] The field is of some relevance to organic synthesis. The relevant oxidation states for organochromium complexes encompass the entire range of possible oxidation states from –4 (d10) in Na4[Cr–IV(CO)4] to +6 (d0) in oxo-alkyl complexes like Cp*CrVI(=O)2Me.
^Review: Carbon-Carbon Bond Formations Involving Organochromium(III) Reagents Furstner, A. Chem. Rev.; (Review); 1999; 99(4); 991-1046. doi:10.1021/cr9703360
^Review: From Hein to Hexene: Recent Advances in the Chemistry of Organochromium -Complexes Jolly, P. W. Acc. Chem. Res.; (Article); 1996; 29(11); 544-551. doi:10.1021/ar9502588
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Organochromiumchemistry is a branch of organometallic chemistry that deals with organic compounds containing a chromium to carbon bond and their reactions...
and tungsten form organometallic compounds similar to those in organochromiumchemistry but higher oxidation states tend to be more common. Molybdenum...
Bis(benzene)chromium and chromium hexacarbonyl are highlights in organochromiumchemistry. Chromium(II) compounds are uncommon, in part because they readily...
Bis(benzene)chromium and chromium hexacarbonyl are highlights in organochromiumchemistry. Chromium(II) compounds are uncommon, in part because they readily...
the Nobel Prize in Chemistry in 1967 and is nine years younger than Fischer was. Organochromiumchemistry Organouranium chemistry Chromocene Metallocene...
concentration is 10−2 mol/L. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 637. ISBN 978-0-08-037941-8...
original on 2020-09-01. Moody, B.J. (1965). "22". Comparative Inorganic Chemistry (1 ed.). London: Edward Arnold. p. 381. ISBN 0-7131-3679-0. Sisler, Harry...
Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a07_067. ISBN 978-3527306732. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the...
secondary alcohol to ketone (cyclooctanone) and nortricyclanone. In organic chemistry, dilute solutions of chromic acid can be used to oxidize primary or secondary...
generated from a phenyl sulfone. The Takai olefination based on an organochromium intermediate also delivers E-products. A titanium compound, Tebbe's...
Takai, who first reported it in 1986. In the original reaction, the organochromium species is generated from iodoform or bromoform and an excess of chromium(II)...
being the structure of the active species, which is assumed to be an organochromium compound. Robert L. Banks and J. Paul Hogan, both at Phillips Petroleum...
of element 120. The 54Cr beam was produced by feeding the volatile organochromium compound chromocene (Cr(C5H5)2) into an ion source: the chromocene itself...
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