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Nitrogen triiodide information


Nitrogen triiodide
Nitrogen triiodide (structural formula)
Nitrogen triiodide
Nitrogen triiodide
Nitrogen triiodide
Nitrogen triiodide
Names
IUPAC names
Nitrogen triiodide[1]
Triiodoazane[1]
Triiodidonitrogen[1]
Other names
Nitrogen iodide
Ammonia triiodide
Touch Powder
Triiodine nitride
Triiodine mononitride
Triiodamine[citation needed]
Triiodoamine[citation needed]
Iodine nitride
Identifiers
CAS Number
  • 13444-85-4 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 55511 checkY
PubChem CID
  • 61603
CompTox Dashboard (EPA)
  • DTXSID40893670 Edit this at Wikidata
InChI
  • InChI=1S/I3N/c1-4(2)3 checkY
    Key: FZIONDGWZAKCEX-UHFFFAOYSA-N checkY
  • InChI=1/I3N/c1-4(2)3
    Key: FZIONDGWZAKCEX-UHFFFAOYAL
SMILES
  • IN(I)I
Properties
Chemical formula
NI3
Molar mass 394.719 g/mol
Appearance dark solid
Boiling point sublimes at −20 °C
Solubility in water
Insoluble
Solubility organic solvents,[2] such as diethyl ether
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Extremely explosive and unstable
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 4: Readily capable of detonation or explosive decomposition at normal temperatures and pressures. E.g. nitroglycerinSpecial hazards (white): no code
3
0
4
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Nitrogen triiodide is an inorganic compound with the formula NI3. It is an extremely sensitive contact explosive: small quantities explode with a loud, sharp snap when touched even lightly, releasing a purple cloud of iodine vapor; it can even be detonated by alpha radiation. NI3 has a complex structural chemistry that is difficult to study because of the instability of the derivatives. Although nitrogen is more electronegative than iodine, the compound was so named due to its analogy to the compound nitrogen trichloride.[citation needed]

  1. ^ a b c per analogiam, see NF3 names, IUPAC Red Book 2005, p. 314
  2. ^ 4. Analytical techniques. acornusers.org

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Nitrogen triiodide

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Nitrogen triiodide is an inorganic compound with the formula NI3. It is an extremely sensitive contact explosive: small quantities explode with a loud...

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Triiodide

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separate iodine atoms or iodide ions. Examples include nitrogen triiodide (NI3) and phosphorus triiodide (PI3), where individual iodine atoms are covalently...

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Contact explosive

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explosively. Nitrogen triiodide is a perfect example of this property. The three huge iodine atoms try to attach themselves to one small nitrogen ion, which...

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Ammonium triiodide

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different compound, nitrogen triiodide (NI3), or more precisely, the slightly more stable ammine, NI3 · NH3. "Ammonium triiodide | H4I3N - PubChem". pubchem...

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Pnictogen

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unstable. Nitrogen trifluoride is the only stable nitrogen trihalide, with nitrogen trichloride, nitrogen tribromide, and nitrogen triiodide being explosive—nitrogen...

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Nitrogen trichloride

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Jander, J. (1976). Recent Chemistry and Structure Investigation of Nitrogen Triiodide, Tribromide, Trichloride, and Related Compounds. Advances in Inorganic...

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Nitrogen trifluoride

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other nitrogen trihalides nitrogen trichloride, nitrogen tribromide and nitrogen triiodide, all of which are explosive. Alone among the nitrogen trihalides...

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Ammonia

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and certain plastics. Ammonia reacts violently with the halogens. Nitrogen triiodide, a primary high explosive, is formed when ammonia comes in contact...

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Nitrogen

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currents, or even alpha particles. For this reason, small amounts of nitrogen triiodide are sometimes synthesised as a demonstration to high school chemistry...

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Phosphorus triiodide

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Phosphorus triiodide (PI3) is an inorganic compound with the formula PI3. A red solid, it is too unstable to be stored for long periods of time; it is...

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NFPA 704

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decomposition at normal temperatures and pressures (e.g., nitroglycerin, chlorine dioxide, nitrogen triiodide, manganese heptoxide, TNT, Picric acid)...

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Nitrogen compounds

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currents, or even alpha particles. For this reason, small amounts of nitrogen triiodide are sometimes synthesised as a demonstration to high school chemistry...

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Explosive

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nitrate Nickel hydrazine perchlorate Nitrogen trihalides: Nitrogen trichloride Nitrogen tribromide Nitrogen triiodide Nitroglycerin Nitronium perchlorate...

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Iodine

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known) are known to form binary compounds with iodine. Until 1990, nitrogen triiodide was only known as an ammonia adduct. Ammonia-free NI3 was found to...

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Ni

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insemination i.e. sexual intercourse, in contrast to artificial insemination Nitrogen Triiodide, a sensitive contact explosive Natural intelligence, a term used to...

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Iodine monofluoride

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monofluoride: I2 + AgF → IF + AgI Iodine monofluoride is used to produce pure nitrogen triiodide: BN + 3 IF → NI3 + BF3 Iodine trifluoride Iodine pentafluoride Iodine...

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List of CAS numbers by chemical compound

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L M N O P R S T U V W X Y Z See also External links Chemistry portal "Nitrogen" (PDF). Safety Data Sheet. Airgas - Air Liquide Company. 31 August 2021...

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List of inorganic compounds

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"Arsenic triiodide". pubchem.ncbi.nlm.nih.gov. Retrieved 2023-01-19. "arsenic triiodide". webbook.nist.gov. Retrieved 2023-01-19. "T3DB: Arsenic triiodide"....

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Explosophore

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azide NH4N3) III. −RnNXm The halogenated nitrogen group X:halogen (e.g. nitrogen triiodide NI3 and nitrogen trichloride NCl3) IV. −C=N−O− The fulminate...

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Iodine compounds

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halides of iodine. (Nonetheless, nitrogen triiodide is named as an iodide as it is analogous to the other nitrogen trihalides.) Given the large size...

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Shock sensitivity

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used to measure sensitivity to blast shock. A few materials such as nitrogen triiodide cannot be touched at all without detonating, and so are of purely...

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Glossary of chemical formulae

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(NH4)2SO4 ammonium sulfate 7783-20-2 NI3 nitrogen triiodide 13444-85-4 NO nitric oxide nitrogen oxide nitrogen(II) oxide 10102-43-9 NOCl nitrosyl chloride...

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Iodine in biology

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average). When mixed with ammonia and water, elemental iodine forms nitrogen triiodide, which is extremely shock-sensitive and can explode unexpectedly....

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Boron nitride

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1021/cr00099a004. Tornieporth-Oetting, I.; Klapötke, T. (1990). "Nitrogen Triiodide". Angewandte Chemie International Edition. 29 (6): 677–679. doi:10...

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Ammonium iodate

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iodine in an ammonium hydroxide solution, instead the highly explosive nitrogen triiodide is formed. 3 I2 + 5 NH3 → 3 NH4I + NH3·NI3 Because ammonium iodate...

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List of Wikipedia pages banned in Russia

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Russian Federation. Information about the manufacture of the explosive "Nitrogen triiodide" has been posted, including from publicly available materials. Information...

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Catenation

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stable at room temperature, of which the most prominent example being triiodide. In all these anions, the halogen atoms of the same element bond to each...

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