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Boron nitride information


Boron nitride
Magnified sample of crystalline hexagonal boron nitride
Names
IUPAC name
Boron nitride
Identifiers
CAS Number
  • 10043-11-5 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:50883 checkY
ChemSpider
  • 59612 checkY
ECHA InfoCard 100.030.111 Edit this at Wikidata
EC Number
  • 233-136-6
Gmelin Reference
216
MeSH Elbor
PubChem CID
  • 66227
RTECS number
  • ED7800000
UNII
  • 2U4T60A6YD ☒N
CompTox Dashboard (EPA)
  • DTXSID5051498 Edit this at Wikidata
InChI
  • InChI=1S/BN/c1-2 checkY
    Key: PZNSFCLAULLKQX-UHFFFAOYSA-N checkY
  • InChI=1S/B2N2/c1-3-2-4-1
    Key: AMPXHBZZESCUCE-UHFFFAOYSA-N
  • InChI=1S/B3N3/c1-4-2-6-3-5-1
    Key: WHDCVGLBMWOYDC-UHFFFAOYSA-N
  • InChI=1/BN/c1-2
    Key: PZNSFCLAULLKQX-UHFFFAOYAL
SMILES
  • [B].[N]
Properties
Chemical formula
BN
Molar mass 24.82 g/mol
Appearance Colorless crystals
Density 2.1 g/cm3 (h-BN); 3.45 g/cm3 (c-BN)
Melting point 2,973 °C (5,383 °F; 3,246 K) sublimates (c-BN)
Solubility in water
Insoluble
Electron mobility 200 cm2/(V·s) (c-BN)
Refractive index (nD)
1.8 (h-BN); 2.1 (c-BN)
Structure
Crystal structure
Hexagonal, sphalerite, wurtzite
Thermochemistry
Heat capacity (C)
19.7 J/(K·mol)[1][2]
Std molar
entropy (S298)
14.8 J/K mol[3][2]
Std enthalpy of
formation fH298)
−254.4 kJ/mol[4][2]
Gibbs free energy fG)
−228.4 kJ/mol[5][2]
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H319, H335, H413
Precautionary statements
P261, P264, P271, P273, P280, P304+P340, P305+P351+P338, P312, P337+P313, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
0
0
0
Related compounds
Related compounds
  • Boron arsenide
  • Boron carbide
  • Boron phosphide
  • Boron trioxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the chemical formula BN. It exists in various crystalline forms that are isoelectronic to a similarly structured carbon lattice. The hexagonal form corresponding to graphite is the most stable and soft among BN polymorphs, and is therefore used as a lubricant and an additive to cosmetic products. The cubic (zincblende aka sphalerite structure) variety analogous to diamond is called c-BN; it is softer than diamond, but its thermal and chemical stability is superior. The rare wurtzite BN modification is similar to lonsdaleite but slightly softer than the cubic form.[6]

Because of excellent thermal and chemical stability, boron nitride ceramics are used in high-temperature equipment and metal casting. Boron nitride has potential use in nanotechnology.

  1. ^ for h-BN
  2. ^ a b c d Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 5.6. ISBN 1-4398-5511-0.
  3. ^ for h-BN
  4. ^ for h-BN
  5. ^ for h-BN
  6. ^ Brazhkin, Vadim V.; Solozhenko, Vladimir L. (2019). "Myths about new ultrahard phases: Why materials that are significantly superior to diamond in elastic moduli and hardness are impossible". Journal of Applied Physics. 125 (13): 130901. arXiv:1811.09503. Bibcode:2019JAP...125m0901B. doi:10.1063/1.5082739. S2CID 85517548.

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