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Miscibility information


Diesel fuel is immiscible in water. The bright rainbow pattern is the result of thin-film interference.

Miscibility (/ˌmɪsɪˈbɪlɪti/) is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration), forming a homogeneous mixture (a solution). Such substances are said to be miscible (etymologically equivalent to the common term "mixable"). The term is most often applied to liquids but also applies to solids and gases. An example in liquids is the miscibility of water and ethanol as they mix in all proportions.[1]

By contrast, substances are said to be immiscible if the mixture does not form a solution for certain proportions. For one example, oil is not soluble in water, so these two solvents are immiscible. As another example, butanone (methyl ethyl ketone) is significantly soluble in water, but these two solvents are also immiscible because in some proportions the mixture will separate into two phases.[2]

  1. ^ Wade, Leroy G. (2003). Organic Chemistry. Pearson Education. p. 412. ISBN 0-13-033832-X.
  2. ^ Stephen, H.; Stephen, T. (2013-10-22). Binary Systems: Solubilities of Inorganic and Organic Compounds, Volume 1P1. Elsevier. ISBN 9781483147123.

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Miscibility

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determines the compound's miscibility with water. For example, among the alcohols, ethanol has two carbon atoms and is miscible with water, whereas 1-butanol...

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Miscibility gap

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the boundary on a phase diagram between a miscibility gap and other phases. Thermodynamically, miscibility gaps indicate a maximum (e.g. of Gibbs energy)...

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Dichloromethane

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is widely used as a solvent. Although it is not miscible with water, it is slightly polar, and miscible with many organic solvents. Natural sources of...

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Upper critical solution temperature

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miscible in all proportions. The word upper indicates that the UCST is an upper bound to a temperature range of partial miscibility, or miscibility for...

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Toluene

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cyclohexylamine (Cesium Cyclohexylamide) using a Bronsted correlation. Toluene is miscible (soluble in all proportions) with ethanol, benzene, diethyl ether, acetone...

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Indium arsenide antimonide

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such as LPE, to those outside of the miscibility gap. However, compositions of InAsSb within the miscibility gap can be obtained with non-equilibrium...

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Thermoplastic polyurethane

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linked by covalent links so that they actually form block-copolymers. The miscibility of the hard and soft segments in TPU depends on the differences in their...

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Ethanol

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Ethanol's miscibility with water contrasts with the immiscibility of longer-chain alcohols (five or more carbon atoms), whose water miscibility decreases...

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Azeotrope

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the components of a mixture are not completely miscible, an azeotrope can be found inside the miscibility gap. This type of azeotrope is called a heterogeneous...

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Lower critical solution temperature

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miscible in all proportions. The word lower indicates that the LCST is a lower bound to a temperature interval of partial miscibility, or miscibility...

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Glycerol

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pharmaceutical formulations. Because of its three hydroxyl groups, glycerol is miscible with water and is hygroscopic in nature. Although achiral, glycerol is...

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Thermal energy storage

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must be carefully designed in order to avoid unnecessary loss of heat. Miscibility gap alloys rely on the phase change of a metallic material (see: latent...

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Third law of thermodynamics

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The third law of thermodynamics states that the entropy of a closed system at thermodynamic equilibrium approaches a constant value when its temperature...

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Tetrahydrofuran

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product. In the laboratory, THF is a popular solvent when its water miscibility is not an issue. It is more basic than diethyl ether and forms stronger...

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Entropy of mixing

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always favors miscibility and opposes phase separation. For ideal solutions, the enthalpy of mixing is zero so that the components are miscible in all proportions...

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Augite

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sodium and other elements. The calcium content of augite is limited by a miscibility gap between it and pigeonite and orthopyroxene: when occurring with either...

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Isopropyl alcohol

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pungent alcoholic odor. Isopropyl alcohol, an organic polar molecule, is miscible in water, ethanol, and chloroform, demonstrating its ability to dissolve...

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Dimethylacetamide

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This colorless, water-miscible, high-boiling liquid is commonly used as a polar solvent in organic synthesis. DMA is miscible with most other solvents...

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Propylene glycol

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CH3CH(OH)CH2OH. As it contains two alcohol groups, it is classed as a diol. It is miscible with a broad range of solvents, including water, acetone, and chloroform...

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Boiling point

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be affected by the presence of dissolved impurities (solutes) or other miscible compounds, the degree of effect depending on the concentration of the impurities...

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Painting

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the general working characteristics of the paint, such as viscosity, miscibility, solubility, drying time, etc. Encaustic painting, also known as hot...

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Water

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ethers. Improved solubility in carboxylates, alcohols, ketones, amines. Miscible with methanol, ethanol, propanol, isopropanol, acetone, glycerol, 1,4-dioxane...

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Chloroform

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between the 19th century and the first half of the 20th century. It is miscible with many solvents but it is only very slightly soluble in water (only...

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Water miscible oil paint

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Water-miscible oil paint (also called water-soluble oil paint or water-mixable oil paint) is oil paint either engineered or to which an emulsifier has...

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Properties of water

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global system of currents called the thermohaline circulation. Water is miscible with many liquids, including ethanol in all proportions. Water and most...

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Solvation shell

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Supersaturation Serial dilution Dilution (equation) Apparent molar property Miscibility gap Concentration and related quantities Molar concentration Mass concentration...

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