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Metal cluster compound information


Structure of the Mn4O5Ca cluster of the oxygen evolving complex of Photosystem II at a resolution of 1.9 Å. This cluster converts water into (all of) the O2 in our atmosphere.[1]

Metal cluster compounds are a molecular ion or neutral compound composed of three or more metals and featuring significant metal-metal interactions.[2]

  1. ^ Umena, Yasufumi; Kawakami, Keisuke; Shen, Jian-Ren; Kamiya, Nobuo (May 2011). "Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å" (PDF). Nature. 473 (7345): 55–60. Bibcode:2011Natur.473...55U. doi:10.1038/nature09913. PMID 21499260. S2CID 205224374.
  2. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.

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Metal cluster compound

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Metal cluster compounds are a molecular ion or neutral compound composed of three or more metals and featuring significant metal-metal interactions. The...

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Nanocluster

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tremendous work on nanoclusters of semiconductor elements, compound clusters and transition metal nanoclusters. According to the Japanese mathematical physicist...

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Butterfly cluster compound

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In the area of metal cluster chemistry, a butterfly cluster compound usually describes tetrametallic clusters containing five M-M bonds. A prototype of...

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Metal aromaticity

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metal-containing compounds. The first experimental evidence for the existence of aromaticity in metals was found in aluminium cluster compounds of the type...

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Metal carbonyl cluster

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In chemistry, a metal carbonyl cluster is a compound that contains two or more metal atoms linked in part by metalmetal bonds and containing carbon monoxide...

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Coordination complex

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as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that belong to...

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Alkali metal

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vigorously than the lighter ones. All of the discovered alkali metals occur in nature as their compounds: in order of abundance, sodium is the most abundant, followed...

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Fluorine compounds

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includes inorganic compounds formed with hydrogen, metals, nonmetals, and even noble gases; as well as a diverse set of organic compounds. For many elements...

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Organic compound

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define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical...

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Metal

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or molecules of the metal. A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polymeric sulfur...

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Inorganic chemistry

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chemistry, compounds with metal-carbon bonds. This area touches on organic synthesis, which employs many organometallic catalysts and reagents. cluster chemistry...

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Carbide

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describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece...

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Carbon compounds

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tetraiodide (CI4), and a large number of other carbon-halogen compounds. A carborane is a cluster composed of boron and carbon atoms such as H2C2B10H10. There...

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Bismuth organometallic chemistry

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bismuth-transition metal compounds and clusters with interesting electronics and 3D structures. Due to the inert pair effect of the heavy, organometallic compounds of...

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Polyhedral skeletal electron pair theory

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S2CID 250797537. Fehlner, Thomas P. (2006). "Cluster Compounds: Inorganometallic Compounds Containing Transition Metal & Main Group Elements". Encyclopedia of...

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Nickel compounds

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nickel are found in biological systems. Nickel forms simple binary compounds with non metals including halogens, chalcogenides, and pnictides. Nickel ions...

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Lanthanide

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similar cluster compound with chlorine, Sc7Cl12 Unlike many transition metal clusters these lanthanide clusters do not have strong metal-metal interactions...

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Metallaborane

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chemistry, a metallaborane is a compound that contains one or more metal atoms and one or more boron hydride. These compounds are related conceptually and...

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Silicon compounds

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unusual compounds have been discovered that differ from expectations based on its valence electrons, including the silicides and some silanes. Metal silicides...

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Transition metal

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electrons, as are many of their compounds. All of the elements that are ferromagnetic near room temperature are transition metals (iron, cobalt and nickel)...

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Nido

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applied boranes, derivatives such as carboranes, and deltahedral metal cluster compounds such as stannides, plumbides and bismuth polycations. The term...

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Argon compounds

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2. Metal ions can also form with more than one argon atom, in a kind of argon metal cluster. Different sized metal ions at the centre of a cluster can...

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Triruthenium dodecacarbonyl

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Triruthenium dodecacarbonyl is the chemical compound with the formula Ru3(CO)12. Classified as metal carbonyl cluster, it is a dark orange-colored solid that...

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Suboxide

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oxides. When the electropositive element is a metal, the compounds are sometimes referred to as “metal-rich”. Thus the normal oxide of caesium is Cs2O...

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Boron compounds

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ceramic composed of boron-carbon cluster anions and cations, to carboranes, carbon-boron cluster chemistry compounds that can be halogenated to form reactive...

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Metal carbonyl

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modes in metal carbonyl dimers and clusters. In the most common bridging mode, denoted μ2 or simply μ, the CO ligand bridges a pair of metals. This bonding...

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