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Triruthenium dodecacarbonyl information


Triruthenium dodecacarbonyl
Names
IUPAC name
cyclo-tris(tetracarbonylruthenium)(3 RuRu)
Other names
Ruthenium carbonyl
Identifiers
CAS Number
  • 15243-33-1 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 24589240
ECHA InfoCard 100.035.701 Edit this at Wikidata
EC Number
  • 239-287-4
PubChem CID
  • 6096991
InChI
  • InChI=1S/12CO.3Ru/c12*1-2;;;
    Key: NQZFAUXPNWSLBI-UHFFFAOYSA-N
SMILES
  • [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru].[Ru].[Ru]
Properties
Chemical formula
C12O12Ru3
Molar mass 639.33 g/mol
Appearance orange solid
Density 2.48 g/cm3
Melting point 224 °C (435 °F; 497 K)
Boiling point sublimes in vacuum
Solubility in water
insoluble
Solubility in organic solvents soluble
Structure
Molecular shape
D3h cluster
Dipole moment
0 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic, CO Source
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H302, H315, H319, H332, H335
Precautionary statements
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
Related compounds
Related compounds
Triiron dodecacarbonyl
Triosmium dodecacarbonyl
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Triruthenium dodecacarbonyl is the chemical compound with the formula Ru3(CO)12. Classified as metal carbonyl cluster, it is a dark orange-colored solid that is soluble in nonpolar organic solvents. The compound serves as a precursor to other organoruthenium compounds.

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Triruthenium dodecacarbonyl

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Triruthenium dodecacarbonyl is the chemical compound with the formula Ru3(CO)12. Classified as metal carbonyl cluster, it is a dark orange-colored solid...

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Organoruthenium chemistry

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the introduction of ruthenium are ruthenium(III) chloride and triruthenium dodecacarbonyl. In its organometallic compounds, ruthenium is known to adopt...

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Triiron dodecacarbonyl

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ISBN 3-527-28165-7 McFarlane, W.; Wilkinson, G. W. (1966). Triiron dodecacarbonyl. Inorganic Syntheses. Vol. 8. pp. 181–3. doi:10.1002/9780470132395.ch47...

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Iron pentacarbonyl

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nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Nickel tetracarbonyl...

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Nickel tetracarbonyl

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nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Except where...

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Ruthenium

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converts in the absence of CO pressure to the dark red solid triruthenium dodecacarbonyl. Ruthenium trichloride reacts with carbon monoxide to give many...

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Shvo catalyst

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the effect of diphenylacetylene on the catalytic properties of triruthenium dodecacarbonyl. The reaction of diphenylacetylene and Ru3(CO)12 gives the piano...

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Haber process

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catalysts. Such catalysts are prepared by the decomposition of triruthenium dodecacarbonyl on graphite. A drawback of activated-carbon-supported ruthenium-based...

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Ruthenium compounds

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converts in the absence of CO pressure to the dark red solid triruthenium dodecacarbonyl. Ruthenium trichloride reacts with carbon monoxide to give many...

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Dichlororuthenium tricarbonyl dimer

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+ 2 CO It reacts with potassium hydroxide in alcohol to give triruthenium dodecacarbonyl. Dichlororuthenium tricarbonyl dimer reacts with glycine to give...

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Chromium hexacarbonyl

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nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Nickel tetracarbonyl...

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Ruthenium pentacarbonyl

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reducing agent. A more recent preparation involves photolysis of triruthenium dodecacarbonyl in the presence of carbon monoxide: Ru3(CO)12 + 3 CO ⇌ 3 Ru(CO)5...

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Vanadium hexacarbonyl

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nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Nickel tetracarbonyl...

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Chemical vapor deposition of ruthenium

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favorable way. Before metal-organic precursors were explored, triruthenium dodecacarbonyl (Ru3(CO)12) was tested as a CVD precursor. While this precursor...

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