Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Lithium triflate (lithium triflouromethanesulfonate or LiOTf) is a salt with the chemical formula LiCF3SO3. It is composed of the lithium cation (Li+) and triflate anion (CF3SO3−; TfO−). It is very hygroscopic. The salt is used in lithium-ion battery production.[1]
Lithium triflate is hygroscopic and absorbs water from air humidity
Lithiumtriflate (lithium triflouromethanesulfonate or LiOTf) is a salt with the chemical formula LiCF3SO3. It is composed of the lithium cation (Li+)...
bridge. Triflates have also been applied as ligands for group 11 and 13 metals along with lanthanides. Lithiumtriflates are used in some lithium ion batteries...
trimethylsilyl chloride. To increase the rate of reaction, trimethylsilyl triflate may also be used in the place of trimethylsilyl chloride as a more electrophilic...
that are good solvents for salts such as lithiumtriflate. These solutions function as electrolytes for lithium ion transport, and they were incorporated...
SN2 pathway: CH3OH + H+ → [CH3OH2]+ Similarly, methyl iodide and methyl triflate are viewed as the equivalent of the methyl cation because they readily...
magnesium bromide: and a second one with an amine chiral ligand and a triflate salt catalyst: Utilization of chiral Lewis acid complexes and Lewis bases...
BuLi → SnBu4 + 4 LiCH=CH2 The reaction of ethylene and lithium affords vinyl lithium and lithium hydride, together with other organolithium compounds,...
Their reactivity generally mirrors that of the more commonly encountered triflate electrophiles, but nonaflates tend to be less prone to hydrolysis to ketones...
can be used to install the PMB group in presence of: Scandium (III) triflate (Sc(OTf)3) in toluene at 0 °C Trifluoromethanesulfonic acid (TfOH) in dichloromethane...
Hafnium(IV) triflate or hafnium trifluoromethansulfonate is a salt with the formula Hf(OSO2CF3)4, also written as Hf(OTf)4. Hafnium triflate is used as...
ultimately derived from the Heck reaction of enol triflate 38, which was used to close the B-ring. Enol triflate 38 resulted from a rearrangement of compound...
Swern oxidation ketone 9. Reaction with LDA / PhNTf2 gave enol triflate 10 and the triflate group was removed in alkene 11 by reaction with Pd(OAc)2 and...
Dalla, V.; Duñach, E. (2010). "Metal Triflimidates: Better than Metal Triflates as Catalysts in Organic Synthesis—The Effect of a Highly Delocalized Counteranion"...
nucleophile is a boron enolate derived from reaction with dibutylboron triflate (nBu2BOTf), the base is N,N-diisopropylethylamine. The thioether is removed...
preparation of (+)-xestoquinone from triflate substrate 75 (Scheme 16). Oxidative addition of the aryl–triflate bond into the palladium(0) complex in...
Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates". Tetrahedron Letters. 38 (36): 6367–6370. doi:10.1016/S0040-4039(97)01465-2...
Y3+ and La3+ ions, coordination numbers of 8 and 9 are common. Scandium triflate is sometimes used as a Lewis acid catalyst in organic chemistry. Scandium...
aldehyde 1.10. The TIPS silyl enol ether 1.11 was formed by reaction with the triflate TIPSOtf and DBU in DMAP setting the stage for asymmetric dihydroxylation...
palladium-catalyzed cross-coupling reactions involving vinyl and aryl triflates to give arylalkenes and biaryl compounds in good yields and under mild...
(1989). "Major effect of the leaving group in dialkylboron chlorides and triflates in controlling the stereospecific conversion of ketones into either E-...
between axially chiral BINOL-based phosphoramidites and aryl halides or triflates proceeds with excellent stereoselectivity due to the presence of BINOL...
is typically a halide, such as Cl, Br, or I, yet pseudohalides such as triflates and sulfonates and phosphates can also be used. Several reviews have been...
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