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Benzophenone imine information


Benzophenone imine
Names
Preferred IUPAC name
Diphenylmethanimine
Identifiers
CAS Number
  • 1013-88-3
3D model (JSmol)
  • Interactive image
ChemSpider
  • 120561
ECHA InfoCard 100.103.715 Edit this at Wikidata
EC Number
  • 600-205-0
  • 440-870-2
PubChem CID
  • 136809
UNII
  • EJJ21NA7VI
CompTox Dashboard (EPA)
  • DTXSID10870832 Edit this at Wikidata
InChI
  • InChI=1S/C13H11N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
    Key: SXZIXHOMFPUIRK-UHFFFAOYSA-N
SMILES
  • C1=CC=C(C=C1)C(=N)C2=CC=CC=C2
Properties
Chemical formula
C13H11N
Molar mass 181.238 g·mol−1
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H315, H319, H335
Precautionary statements
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Benzophenone imine is an organic compound with the formula of (C6H5)2C=NH. A pale yellow liquid, benzophenone imine is used as a reagent in organic synthesis.[1]

  1. ^ Cite error: The named reference :2 was invoked but never defined (see the help page).

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Benzophenone imine

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Benzophenone imine is an organic compound with the formula of (C6H5)2C=NH. A pale yellow liquid, benzophenone imine is used as a reagent in organic synthesis...

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Imine

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example, benzophenone imine can also be synthesized by addition of phenylmagnesium bromide to benzonitrile followed by careful hydrolysis (lest the imine be...

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Diphenyldichloromethane

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tetraphenylethylene, diphenylmethane imine hydrochloride and benzoic anhydride. Andrews, L. J.; W. W. Kaeding (1951). "The Formation of Benzophenone and its Diethylketal...

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Ketone

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generally used for the most important ketones, for example acetone and benzophenone. These nonsystematic names are considered retained IUPAC names, although...

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Sedaxane

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required for sedaxane formation by Buchwald–Hartwig amination using benzophenone imine in the presence of a palladium catalyst, followed by hydroxylamine...

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C13H11N

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molecular formula C13H11N (molar mass: 181.238 g/mol) may refer to: Benzophenone imine, an organic compound with the formula of (C6H5)2C=NH 2-Aminofluorene...

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Stieglitz rearrangement

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group and dissociation of the phosphorus(V) species to form N-phenyl benzophenone imine. Additionally to N-hydroxy trityl amines, rearrangements in N-alkoxy...

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Peroxide process

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individual steps are as follows. Imine formation through condensation: Me(Et)C=O + NH3 → Me(Et)C=NH + H2O Oxidation of the imine to the oxaziridine: Me(Et)C=NH...

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Benzoyl group

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benzoyl group. They have the formula C6H5CO–R, an important example being benzophenone. Benzoyl esters and amides are common in organic chemistry. The esters...

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Hydrogenation

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hydrogenation of phenylacetylene using the Lindlar catalyst. Hydrogenation of an imine using a Raney nickel catalyst, a popular heterogeneous catalyst. Partial...

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Hydrazone

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DNP-derived hydrazone of benzophenone. Selected parameters: C=N, 128 pm; N-N, 138 pm, N-N-C(Ar), 119 pm Azo compound Imine Nitrosamine Hydrogenation...

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Outline of organic chemistry

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Aromatics Acetophenones Anilines Anisoles Benzene Benzenesulfonic acids Benzophenones Nitrobenzenes Phenols Aromatic hydrocarbons Toluene Xylenes m-Xylenes...

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Functional group

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Benzophenone...

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Thioketone

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that dissolves readily in organic solvents. It photooxidizes in air to benzophenone and sulfur. Since its discovery, a variety of related thiones have been...

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Ionic hydrogenation

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these cases, triflic acid is a typical proton donor. Ketones such as benzophenones, and 1,1-disubstituted olefins are typical substrates. Hydrides of tungsten...

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Silicon compounds

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to illustrate the similarity of chemical formulae between Ph 2SiO and benzophenone, Ph 2CO, although he also stressed the lack of chemical resemblance due...

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Organic acid anhydride

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dianhydride (PMDA), 3,3’, 4,4’ - oxydiphtalic dianhydride (ODPA), 3,3’, 4,4’-benzophenone tetracarboxylic dianhydride (BTDA), 4,4’-diphtalic (hexafluoroisopropylidene)...

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Pinacol coupling reaction

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Mukaiyama Taxol total synthesis and the Nicolaou Taxol total synthesis. Benzophenone may undergo the pinacol coupling photochemically. Benzaldehyde may also...

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IUPAC nomenclature of organic chemistry

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as separate words followed by the word ketone. Acetone Acetophenone Benzophenone Ethyl isopropyl ketone Diethyl ketone The first three of the names shown...

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DuPhos

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amino acids in a formal reductive amination for example starting from benzophenone and the hydrazone of benzoyl chloride: In the original scope the metal...

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Photolabile protecting group

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yield. Nevertheless, the photoproducts of this PPG are known to undergo imine formation when irradiated at wavelengths above 300 nm. This side product...

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