Vinyllithium
Identifiers
CAS Number
3D model (JSmol)
Beilstein Reference
3587231
ChEBI
ChemSpider
ECHA InfoCard
100.011.844
EC Number
Gmelin Reference
723
DTXSID10238670
InChI=1S/C2H3.Li/c1-2;/h1H,2H2;
Key: PGOLTJPQCISRTO-UHFFFAOYSA-N
Properties
Chemical formula
C 2 H 3 Li
Molar mass
33.99 g·mol−1
Appearance
white solid
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
pyrophoric
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Vinyllithium is an organolithium compound with the formula LiC2 H3 . A colorless or white solid, it is encountered mainly as a solution in tetrahydrofuran (THF). It is a reagent in synthesis of organic compounds, especially for vinylations.[1]
^ Eisenhart, Eric K.; Bessieres, Bernard (2007). "Vinyllithium". E-EROS Encyclopedia of Reagents for Organic Synthesis . doi:10.1002/047084289X.rv015.pub2. ISBN 978-0-471-93623-7 . .
Last Update: 2023-09-30T19:58:37Z
Vinyllithium is an organolithium compound with the formula LiC2H3. A colorless or white solid, it is encountered mainly as a solution in tetrahydrofuran...
Word Count : 328
Last Update: 2024-05-25T02:35:17Z
This diazonium anion is then lost as molecular nitrogen resulting in a vinyllithium species (7), which can then be reacted with various electrophiles, including...
Word Count : 1020
Last Update: 2024-06-29T08:19:53Z
conjugate addition (Michael addition) can occur. Vinyl organometallics, e.g. vinyllithium and vinyl tributyltin, participate in vinylations including coupling...
Word Count : 469
Last Update: 2024-03-06T08:36:05Z
lithium–halogen exchange cyclized to form the vinyllithium through 5-exo-trig ring closure. The vinyllithium species further reacts with electrophiles and...
Word Count : 5971
Last Update: 2024-03-10T23:44:18Z
An illustrative application of Trapp solvent is the preparation of vinyllithium by lithium halogen exchange from vinyl bromide and tert-butyllithium...
Word Count : 198
Last Update: 2024-06-24T07:24:15Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 3209
Last Update: 2024-06-25T14:07:36Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 233
Last Update: 2024-04-02T13:55:45Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 1427
Last Update: 2024-06-21T09:35:26Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 13743
Last Update: 2024-03-18T14:05:15Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 533
Last Update: 2024-06-26T15:05:08Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 4174
Last Update: 2024-01-17T04:57:17Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 1012
Last Update: 2024-06-17T04:24:11Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 2350
Last Update: 2024-06-20T15:20:25Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 2641
Last Update: 2024-01-18T21:33:24Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 965
Last Update: 2024-02-25T18:33:34Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 184
Last Update: 2023-12-03T04:19:43Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 218
Last Update: 2024-02-21T17:24:21Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 211
Last Update: 2023-12-03T03:13:18Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 294
Last Update: 2024-03-29T03:27:15Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 1424
Last Update: 2024-06-01T21:34:13Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 720
Last Update: 2024-02-22T14:27:34Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 392
Last Update: 2024-06-24T03:22:01Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 253
Last Update: 2024-02-26T10:25:55Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 188
Last Update: 2024-06-12T01:12:11Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 1928
Last Update: 2024-06-29T18:32:11Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 287
Last Update: 2024-05-16T23:57:48Z
LiC2CH3 LiO2C(CH2)16CH3 C4H5LiO4 LiEt3BH LiOC(CH3)3 C9H18LiN LiC2H3 Vinyllithium LiC 11H 23COO Minerals Amblygonite Berezanskite Brannockite Cryolithionite...
Word Count : 776