Hydrosilanes information

Hydrosilanes are tetravalent silicon compounds containing one or more Si-H bond. The parent hydrosilane is silane (SiH4). Commonly, hydrosilane refers...

reduction with hydrosilanes enjoys diverse if specialized applications. Some alcohols are reduced to alkanes when treated with hydrosilanes in the presence...

organosilicon compounds. Some contain Si-H bonds and are discussed under hydrosilanes. Silane SiH 4, the parent. Binary silicon-hydrogen compounds (which are...

(also called hydrosilation). In this process, compounds with Si-H bonds (hydrosilanes) add to unsaturated substrates. Commercially, the main substrates are...

is more electropositive than hydrogen (2.20), hydrosilanes exhibit (mild) hydridic character. Hydrosilanes can serve as hydride donors to highly electrophilic...

series Triisopropylsilyl, a type of silyl ether Triisopropylsilane, a hydrosilane Turkish Institute for Police Studies, University of North Texas Tip (disambiguation)...

acid by the Monsanto process. It is also used to catalyze addition of hydrosilanes to molecular double bonds, a process important in manufacture of certain...

NaCl A related reaction is the oxidative addition of silyl halides. Hydrosilanes oxidatively add to low-valent metal complexes to give silyl metal hydrides...

Nagashima, Hideo (2005). "Catalytic Reduction of Amides to Amines with Hydrosilanes Using a Triruthenium Carbonyl Cluster as the Catalyst". Organic Syntheses...

Speier and colleagues from Dow Corning, it catalyzes the addition of hydrosilanes to olefins, i.e. hydrosilylation. Early demonstration reactions used...

product can be purified by flash chromatography. Ketones react with hydrosilanes in the presence of metal catalysts. Reaction with acids or fluorides...

recommended for applications. An alternative route involves oxidation of hydrosilanes. A wide range of oxidants have been employed including air, peracids...

Iwata, K.; Inoue, K. (1994). "Dehydrogenative coupling reactions between hydrosilanes and monosubstituted alkynes catalyzed by solid bases". Journal of Organometallic...

Typically metal complexes are used to catalyze the reaction, using hydrosilanes as the stoichiometric reductant. The deoxygenation of dimethylsulfoxide...

hydride: GeCl4 + 2 Bu3SnH + C4H8O2 → GeCl2(O2C4H8) + 2 Bu3SnCl + H2 Hydrosilanes have also been used as reductants. The complex has a polymeric structure...

1039/C2CP41589E. PMID 22930067. Corey, Joyce Y. (2011-02-09). "Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products"...

Sons Corey, Joyce Y.; Braddock-Wilking, Janet (1999). "Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal...

marinus has been engineered to catalyze new carbon–silicon bonds between hydrosilanes and diazo compounds. Boranes are dangerously explosive in Earth's atmosphere...

and R. A. Pascal, Jr., Exceptional Steric Congestion in an in,in-Bis(hydrosilane), J. Am. Chem. Soc. 2013, 135, 13235-13237. Echeverría, Jorge; Aullón...

version of the catalytic cycle is shown below for the ortho borylation of hydrosilane compounds. Kinetic data show that an observed trisboryl complex coordinated...

acids ((RO)2PO2H) catalyze the deoxygenation of phosphine oxides by hydrosilanes. Phosphine oxides are ligands in various applications of homogeneous...

"Erythro-directive reduction of .alpha.-substituted alkanones by means of hydrosilanes in acidic media", The Journal of Organic Chemistry, 53 (23): 5415–5421...

a silicone elastomer curing agent. This mixture consists of a short hydrosilane crosslinker that contains a catalyst made from a platinum complex. After...

The latter species can undergo a final transmetalation with an alkyl hydrosilane (stoichiometric) to regenerate the active ligated copper (I) hydride...

reduction of α,β-unsaturated carbonyl compounds. H2 (at least 80 psi) and hydrosilanes can be used as the terminal reductant, allowing a catalytic amount of...