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Hydrogen iodide information


Hydrogen iodide
Hydrogen iodide
Hydrogen iodide
Names
IUPAC name
Hydrogen iodide
Systematic IUPAC name
Iodane
Other names
Hydroiodic acid (aqueous solution)
Iodine hydride
Identifiers
CAS Number
  • 10034-85-2 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:43451
ChemSpider
  • 23224 checkY
ECHA InfoCard 100.030.087 Edit this at Wikidata
EC Number
  • 233-109-9
KEGG
  • C05590
PubChem CID
  • 24841
RTECS number
  • MW3760000
UNII
  • 694C0EFT9Q checkY
UN number 1787 2197
CompTox Dashboard (EPA)
  • DTXSID2044349 Edit this at Wikidata
InChI
  • InChI=1S/HI/h1H checkY
    Key: XMBWDFGMSWQBCA-UHFFFAOYSA-N checkY
SMILES
  • I
Properties
Chemical formula
HI
Molar mass 127.912 g·mol−1
Appearance Colorless gas
Odor acrid
Density 2.85 g/mL (−47 °C)
Melting point −50.80 °C (−59.44 °F; 222.35 K)
Boiling point −35.36 °C (−31.65 °F; 237.79 K)
Solubility in water
approximately 245 g/100 ml
Acidity (pKa) −10 (in water, estimate);[1] −9.5 (±1.0)[2]

2.8 (in acetonitrile)[3]

Conjugate acid Iodonium
Conjugate base Iodide
Refractive index (nD)
1.466 (16 °C)[4]
Structure
Molecular shape
Terminus
Dipole moment
0.38 D
Thermochemistry[4]
Heat capacity (C)
29.2 J·mol−1·K−1
Std molar
entropy (S298)
206.6 J·mol−1·K−1
Std enthalpy of
formation fH298)
26.5 kJ·mol−1
Gibbs free energy fG)
1.7 kJ·mol−1
Enthalpy of fusion fHfus)
2.87 kJ·mol−1
Enthalpy of vaporization fHvap)
17.36 kJ·mol−1
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic, corrosive, harmful and irritant
GHS labelling:
Pictograms
GHS05: CorrosiveGHS06: Toxic
Signal word
Danger
Hazard statements
H302, H314
Precautionary statements
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazard COR: Corrosive; strong acid or base. E.g. sulfuric acid, potassium hydroxide
3
0
1
COR
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
345 mg/kg (rat, orally)[5]
Safety data sheet (SDS) hydrogen iodide
Related compounds
Other anions
Hydrogen fluoride
Hydrogen chloride
Hydrogen bromide
Hydrogen astatide
Supplementary data page
Hydrogen iodide (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Hydrogen iodide (HI) is a diatomic molecule and hydrogen halide. Aqueous solutions of HI are known as hydroiodic acid or hydriodic acid, a strong acid. Hydrogen iodide and hydroiodic acid are, however, different in that the former is a gas under standard conditions, whereas the other is an aqueous solution of the gas. They are interconvertible. HI is used in organic and inorganic synthesis as one of the primary sources of iodine and as a reducing agent.

  1. ^ Bell, R.P. The Proton in Chemistry. 2nd ed., Cornell University Press, Ithaca, NY, 1973.
  2. ^ Trummal, A.; Lipping, L.; Kaljurand, I.; Koppel, I. A.; Leito, I. "Acidity of Strong Acids in Water and Dimethyl Sulfoxide" J. Phys. Chem. A. 2016, 120, 3663-3669. doi:10.1021/acs.jpca.6b02253
  3. ^ Raamat, E.; Kaupmees, K.; Ovsjannikov, G.; Trummal, A.; Kütt, A.; Saame, J.; Koppel, I.; Kaljurand, I.; Lipping, L.; Rodima, T.; Pihl, V.; Koppel, I. A.; Leito, I. "Acidities of strong neutral Brønsted acids in different media." J. Phys. Org. Chem. 2013, 26, 162-170. doi:10.1002/poc.2946
  4. ^ a b CRC handbook of chemistry and physics: a ready-reference book of chemical and physical data. William M. Haynes, David R. Lide, Thomas J. Bruno (2016-2017, 97th ed.). Boca Raton, Florida. 2016. ISBN 978-1-4987-5428-6. OCLC 930681942.{{cite book}}: CS1 maint: location missing publisher (link) CS1 maint: others (link)
  5. ^ Hydrogen iodide: toxicity

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Hydrogen iodide

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Iodine

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smallest of the hydrogen halides, at 295 kJ/mol. Aqueous hydrogen iodide is known as hydroiodic acid, which is a strong acid. Hydrogen iodide is exceptionally...

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Iodine compounds

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smallest of the hydrogen halides, at 295 kJ/mol. Aqueous hydrogen iodide is known as hydroiodic acid, which is a strong acid. Hydrogen iodide is exceptionally...

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Iodide

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An iodide ion is the ion I−. Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered...

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Magnesium iodide

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salt of magnesium and hydrogen iodide. These salts are typical ionic halides, being highly soluble in water. Magnesium iodide has few commercial uses...

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Aluminium iodide

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from a reaction between metallic aluminum or aluminum hydroxide with hydrogen iodide or hydroiodic acid. Like the related chloride and bromide, AlI 3 is...

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HI

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United States of America Hotel Indonesia, a hotel in Jakarta, Indonesia Hydrogen iodide, in chemistry, a diatomic molecule Health informatics, a discipline...

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Iodomethane

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Iodomethane can also be prepared by the reaction of methanol with aqueous hydrogen iodide: CH3OH + HI → CH3I + H2O The generated iodomethane can be distilled...

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Hydroiodic acid

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Hydroiodic acid (or hydriodic acid) is a colorless and aqueous solution of hydrogen iodide (HI). It is a strong acid, which is ionized completely in an aqueous...

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History and culture of substituted amphetamines

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phosphorous acid, regenerating hydrogen iodide). Because hydrogen iodide exists in a chemical equilibrium with iodine and hydrogen, the phosphorus reaction...

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Halogen

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hydrogen known as the hydrogen halides: hydrogen fluoride (HF), hydrogen chloride (HCl), hydrogen bromide (HBr), hydrogen iodide (HI), and hydrogen astatide...

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Ethyl iodide

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Because iodide is a good leaving group, ethyl iodide is an excellent ethylating agent. It is also used as the hydrogen radical promoter. Ethyl iodide is prepared...

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Hofmann elimination

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beta-proton is allowed to react with hydrogen iodide to the quaternary ammonium salt which when heated degrades to methyl iodide and the secondary amine. Cope...

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Hydrogen chloride

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The compound hydrogen chloride has the chemical formula HCl and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white...

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Phosphonium iodide

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atmospheric pressure, phosphonium iodide sublimates and dissociates reversibly into phosphine and hydrogen iodide (HI). It oxidizes slowly in air to...

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Hydrogen bromide

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Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves...

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Hydrogen fluoride

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Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water...

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Thyroid peroxidase

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peroxidase or iodide peroxidase, is an enzyme expressed mainly in the thyroid where it is secreted into colloid. Thyroid peroxidase oxidizes iodide ions to...

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Beryllium iodide

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Beryllium iodide is also formed when beryllium carbide reacts with hydrogen iodide in the gas phase: Be2C + 4 HI → 2 BeI2 + CH4 Beryllium iodide reacts with...

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Arsonium

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(AsH+ 4Br− ) and arsonium iodide (AsH+ 4I− ), which can be synthesized by reacting arsine with hydrogen bromide or hydrogen iodide. Or more commonly, as organic...

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Standard enthalpy of formation

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for most organic compounds are hypothetical. For instance, carbon and hydrogen will not directly react to form methane (CH4), so that the standard enthalpy...

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Isopropyl iodide

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to the formation of iodine. Isopropyl iodide is prepared by iodination of isopropyl alcohol using hydrogen iodide or, equivalently, with a mixture of glycerol...

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Zeisel determination

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acetic acid and hydrogen iodide in a test tube. The ensuing reaction results in the cleavage of the ether or the ester into an alkyl iodide and respectively...

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Bunsen reaction

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sulfuric acid and hydrogen iodide: 2H2O + SO2 + I2 → H2SO4 + 2HI This reaction is the first step in the sulfur-iodine cycle to produce hydrogen. The products...

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Methylammonium iodide

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Methylammonium iodide in an organic halide with a formula of CH3NH3I. It is an ammonium salt composed of methylamine and hydrogen iodide. The primary application...

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Demethylation

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iodide. A slightly milder set of conditions uses cyclohexyl iodide (CyI, 10.0 equiv) in N,N-dimethylformamide to generate a small amount of hydrogen iodide...

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