Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Geranyl pyrophosphate (GPP), also known as geranyl diphosphate (GDP), is the pyrophosphate ester of the terpenoid geraniol. Its salts are colorless. It is a precursor to many natural products.
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Geranylpyrophosphate (GPP), also known as geranyl diphosphate (GDP), is the pyrophosphate ester of the terpenoid geraniol. Its salts are colorless. It...
inorganic pyrophosphate has a reference range of 0.58–3.78 μM (95% prediction interval). Isopentenyl pyrophosphate converts to geranylpyrophosphate, the precursor...
isopentenyl pyrophosphate isomerase. IPP and DMAPP condense to give geranylpyrophosphate, the precursor to monoterpenes and monoterpenoids. Geranyl pyrophosphate...
3-isopentenyl pyrophosphate to form geranylpyrophosphate: Geranylpyrophosphate then reacts with another molecule of 3-isopentenyl pyrophosphate to form farnesyl...
the ketone-containing carvone. In nature, limonene is formed from geranylpyrophosphate, via cyclization of a neryl carbocation or its equivalent as shown...
Dimethylallyl pyrophosphate (DMAPP; or alternatively, dimethylallyl diphosphate (DMADP); also isoprenyl pyrophosphate) is an isoprenoid precursor. It...
resulting from fermentation of sorbic acid by lactic acid bacteria. Geranylpyrophosphate is important in biosynthesis of other terpenes such as myrcene and...
linalool are referred to as linalyl, e.g. linalyl pyrophosphate, an isomer of geranylpyrophosphate. The word linalool is based on linaloe (a type of...
differentiate into eggs and spermatozoa (sperm). Farnesyl pyrophosphate Geranylgeraniol Geranylpyrophosphate Davis, Edward M.; Croteau, Rodney (2000). "Cyclization...
Isopentenyl pyrophosphate (IPP, isopentenyl diphosphate, or IDP) is an isoprenoid precursor. IPP is an intermediate in the classical, HMG-CoA reductase...
carbocationic intermediates produced from geranylpyrophosphate. Analogously hydrolysis of intermediates from farnesyl pyrophosphate gives sesquiterpenoids, and hydrolysis...
isopentenyl pyrophosphate isomerase. Geranylpyrophosphate is the precursor to monoterpenes (and hence monoterpenoids). Elimination of the pyrophosphate group...
of plants. One of the two end-products of MEP pathway, dimethylallyl pyrophosphate (DMAPP), is cleaved by the enzyme isoprene synthase to form isoprene...
biosynthesis, camphor is produced from geranylpyrophosphate, via cyclisation of linaloyl pyrophosphate to bornyl pyrophosphate, followed by hydrolysis to borneol...
α-Pinene and β-pinene are both produced from geranylpyrophosphate, via cyclisation of linaloyl pyrophosphate followed by loss of a proton from the carbocation...
biosynthesized through the head-to-head condensation of two farnesyl pyrophosphate units. This coupling converts a pair of C15 components into a C30 product...
species of Aster. It is biosynthesized from geranylpyrophosphate via isomerization to linalyl pyrophosphate. Oxidation of fenchol gives fenchone. Datasheet...
Geranyl diphosphate diphosphatase (EC 3.1.7.11, geraniol synthase', geranylpyrophosphate pyrophosphatase) is an enzyme with systematic name geranyl-diphosphate...
atmosphere. The reaction of geranylpyrophosphate with isopentenyl pyrophosphate results in the 15-carbon farnesyl pyrophosphate (FPP), which is an intermediate...
Archaea. Squalene is biosynthesised by coupling two molecules of farnesyl pyrophosphate. The condensation requires NADPH and the enzyme squalene synthase. Click...
4-terpineol. The biosynthesis of α-terpineol proceeds from geranylpyrophosphate, which releases pyrophosphate to give the terpinyl cation. This carbocation is...
Secologanin is a secoiridoid monoterpene synthesized from geranylpyrophosphate in the mevalonate pathway. Secologanin then proceeds with dopamine or...
biosynthesize myrcene via geranylpyrophosphate (GPP), which isomerizes into linalyl pyrophosphate. The release of the pyrophosphate (OPP) and a proton completes...
dimethylallyl pyrophosphate. This is then condensed with three molecules of isopentenyl pyrophosphate (an isomer of dimethylallyl pyrophosphate), to give...
isomerization of geranylpyrophosphate to linalyl pyrophosphate (LPP). LPP then forms a resonance-stabilized cation by loss of the pyrophosphate group. Cyclization...
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