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Ethyldichloroarsine information


Ethyldichloroarsine
Names
Preferred IUPAC name
Ethylarsonous dichloride
Other names
ED
Dichloroethylarsane; DICK
Identifiers
CAS Number
  • 598-14-1 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 11219 checkY
ECHA InfoCard 100.009.019 Edit this at Wikidata
EC Number
  • 209-919-3
PubChem CID
  • 11711
RTECS number
  • CH3500000
UNII
  • 4Z7627500U
UN number 1892
CompTox Dashboard (EPA)
  • DTXSID6060505 Edit this at Wikidata
InChI
  • InChI=1S/C2H5AsCl2/c1-2-3(4)5/h2H2,1H3
    Key: LQSFEOMOHFPNEB-UHFFFAOYSA-N
SMILES
  • CC[As](Cl)Cl
Properties
Chemical formula
C2H5AsCl2
Molar mass 174.8893 g/mol
Appearance Colorless, mobile liquid
Density 1.742 @ 14 °C
Melting point −65 °C (−85 °F; 208 K)
Boiling point 156 °C (313 °F; 429 K) (decomposes)
Solubility in water
Soluble in alcohol, benzene, ether, and water
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Highly toxic, irritant
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Ethyldichloroarsine, sometimes abbreviated as "ED" and "CY" and also known as ethyl Dick,[1] is an organoarsenic compound with the formula CH3CH2AsCl2. This colourless volatile liquid is a highly toxic obsolete vesicant or blister agent that was used during World War I in chemical warfare.[2] The molecule is pyramidal with the Cl-As-Cl and C-As-Cl angles approaching 90° (see image). Ethyldichloroarsine has high chronic toxicity, similar to lewisite.[3]

  1. ^ Wood JR (May 1944). "Chemical Warfare-A Chemical and Toxicological Review". American Journal of Public Health and the Nation's Health. 34 (5): 455–60. doi:10.2105/AJPH.34.5.455. PMC 1625133. PMID 18015982.
  2. ^ "Methyldichloroarsine". NorthShore University HealthSystem. Archived from the original on March 7, 2011.
  3. ^ Okumura A, Takada Y, Watanabe S, Hashimoto H, Ezawa N, Seto Y, et al. (July 2016). "In-Line Reactions and Ionizations of Vaporized Diphenylchloroarsine and Diphenylcyanoarsine in Atmospheric Pressure Chemical Ionization Mass Spectrometry". Journal of the American Society for Mass Spectrometry. 27 (7): 1219–26. Bibcode:2016JASMS..27.1219O. doi:10.1007/s13361-016-1394-0. PMID 27098411.

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Ethyldichloroarsine

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Ethyldichloroarsine, sometimes abbreviated as "ED" and "CY" and also known as ethyl Dick, is an organoarsenic compound with the formula CH3CH2AsCl2. This...

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List of chemical warfare agents

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Bis(2-chloroethylthiomethyl) ether Bis(2-chloroethylthioethyl) ether (O Mustard; T) Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD)...

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Blister agent

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Moscow hostage crisis chemical agent

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Novichok

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Chemical warfare

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Incapacitating agent

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Pepper spray

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Nerve agent

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Chemical weapons in World War I

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(dichloromethyl ether) 1918 Irritant, can blur vision Central Powers Ethyldichloroarsine 1918 Vesicant Central Powers N-Ethylcarbazole 679 1918 Irritant Central...

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Chemical weapon

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Arsenical

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were used extensively as insecticides, especially lead arsenate. Ethyldichloroarsine Lewisite Methyldichloroarsine Phenyldichloroarsine Arsine Adamsite...

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Lewisite

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preceding twenty years from accidental exposure to these stockpiles. Ethyldichloroarsine Blue Cross (chemical warfare) Lewisite I – Compound Summary, PubChem...

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Pulmonary agent

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Nettle agent

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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Blood agent

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Cyanogen chloride (CK) Hydrogen cyanide (AC) Arsine (SA) Blister Ethyldichloroarsine (ED) Methyldichloroarsine (MD) Phenyldichloroarsine (PD) Lewisite...

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List of UN numbers 1801 to 1900

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(UN No. no longer in use) UN 1891 6.1 Ethyl bromide UN 1892 6.1 Ethyldichloroarsine UN 1893 ? (UN No. no longer in use) UN 1894 6.1 Phenylmercuric hydroxide...

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Methyldichloroarsine

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agents useful for decontamination of MD are bleach and caustic soda. Ethyldichloroarsine Phenyldichloroarsine Lewisite Wood JR (May 1944). "Chemical Warfare-A...

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Phenyldichloroarsine

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the other three are lewisite (L), methyldichloroarsine (MD), and ethyldichloroarsine (ED). PD is considered an analog of lewisite. At its freezing point...

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