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Chlorine trifluoride oxide information


Chlorine trifluoride oxide
Names
IUPAC name
trifluoro(oxo)-λ5-chlorane
Identifiers
CAS Number
  • 30708-80-6[1]
3D model (JSmol)
  • Interactive image
PubChem CID
  • 15388485
CompTox Dashboard (EPA)
  • DTXSID001278020 Edit this at Wikidata
InChI
  • InChI=1S/ClF3O/c2-1(3,4)5
    Key: QPKQQPNQDSQNHS-UHFFFAOYSA-N
SMILES
  • O=Cl(F)(F)F
Properties
Chemical formula
ClF3O
Molar mass 108.44 g·mol−1
Density 1.865
Melting point −42 °C (−44 °F; 231 K)
Boiling point 29 °C (84 °F; 302 K)
Structure
Crystal structure
monoclinic
Space group
C2/m
Lattice constant
a = 9.826, b = 12.295, c = 4.901
α = 90°, β = 90.338°, γ = 90°[2]
Lattice volume (V)
592.1
Formula units (Z)
8
Hazards
GHS labelling:
Pictograms
GHS03: OxidizingGHS05: CorrosiveGHS06: ToxicGHS09: Environmental hazard
Signal word
Danger
Related compounds
Related compounds
BrOF3; IOF3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Chlorine oxide trifluoride or chlorine trifluoride oxide is a corrosive liquid molecular compound with formula ClOF3. It was developed secretly as a rocket fuel oxidiser.

  1. ^ Urben, Peter (2017). Bretherick's Handbook of Reactive Chemical Hazards. Elsevier. p. 784. ISBN 9780081010594.
  2. ^ Ellern, Arkady; Boatz, Jerry A.; Christe, Karl O.; Drews, Thomas; Seppelt, Konrad (September 2002). "The Crystal Structures of ClF3O, BrF3O, and [NO]+[BrF4O]". Zeitschrift für anorganische und allgemeine Chemie. 628 (9–10): 1991–1999. doi:10.1002/1521-3749(200209)628:9/10<1991::AID-ZAAC1991>3.0.CO;2-1.

and 28 Related for: Chlorine trifluoride oxide information

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Chlorine trifluoride oxide

Last Update:

Chlorine oxide trifluoride or chlorine trifluoride oxide is a corrosive liquid molecular compound with formula ClOF3. It was developed secretly as a rocket...

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Chlorine trifluoride

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Chlorine trifluoride is an interhalogen compound with the formula ClF3. It is a colorless, poisonous, corrosive, and extremely reactive gas that condenses...

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Chlorine trifluoride dioxide

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Chlorine trifluoride dioxide is an inorganic compound of chlorine, fluorine, and oxygen with the chemical formula ClO2F3. Synthesis of chlorine trifluoride...

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Dichlorine monoxide

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B.; Schack, Carl J.; Wilson, R. D.; Christe, Karl O. (1972). "Chlorine trifluoride oxide. I. Preparation and properties". Inorganic Chemistry. 11 (9):...

Word Count : 1319

Xenon compounds

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1021/ic00111a039. Christe, K. O.; Schack, C. J.; Pilipovich, D. (1972). "Chlorine trifluoride oxide. V. Complex formation with Lewis acids and bases". Inorg. Chem...

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Chlorine

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Helmont. Carl Wilhelm Scheele wrote a description of chlorine gas in 1774, supposing it to be an oxide of a new element. In 1809, chemists suggested that...

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Ethylene oxide

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Reactions of ethylene oxide with fatty alcohols proceed in the presence of sodium metal, sodium hydroxide or boron trifluoride and are used for the synthesis...

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Chlorine pentafluoride

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preparation was classified. It was first prepared by fluorination of chlorine trifluoride at high temperatures and high pressures: ClF3 + F2 → ClF5 ClF + 2F2...

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Nitrogen trifluoride

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Nitrogen trifluoride is the inorganic compound with the formula (NF 3). It is a colorless, non-flammable, toxic gas with a slightly musty odor. In contrast...

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Bromine

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bromine trifluoride at high temperatures. Bromine monochloride (BrCl), a red-brown gas, quite readily dissociates reversibly into bromine and chlorine at room...

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Xenon

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1021/ic00111a039. Christe, K. O.; Schack, C. J.; Pilipovich, D. (1972). "Chlorine trifluoride oxide. V. Complex formation with Lewis acids and bases". Inorg. Chem...

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Oxidizing agent

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(H2O2) and other inorganic peroxides, Fenton's reagent Fluorine (F2), chlorine (Cl2), and other halogens Nitric acid (HNO3) and nitrate compounds such...

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Nitrogen trichloride

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and chlorine (for example, in swimming pools). Alongside monochloramine and dichloramine, trichloramine is responsible for the distinctive 'chlorine smell'...

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Einsteinium trifluoride

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alternative preparation procedure is to expose einsteinium(III) oxide to chlorine trifluoride (ClF3) or F2 gas at a pressure of 1–2 atmospheres and a temperature...

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Perchloryl fluoride

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is completely miscible with all-halogen oxidizers such as chlorine trifluoride and chlorine pentafluoride, and such a mixture provides the needed oxygen...

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List of inorganic compounds

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pentafluoride – ClF5 Chlorine perchlorate – Cl2O4 Chlorine tetroxide – O3ClOOClO3 Chlorine trifluoride – ClF3 Chlorine trifluoride – ClF3 Chlorine trioxide – ClO3...

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Iodine

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(IF7) is an extremely powerful fluorinating agent, behind only chlorine trifluoride, chlorine pentafluoride, and bromine pentafluoride among the interhalogens:...

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Interhalogen

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fluorinating agent. It has the same molecular shape as chlorine trifluoride. Iodine trifluoride (IF3) is a yellow solid that decomposes above −28 °C. It...

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Phosgene

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PMID 597296. John Davy (1812). "On a gaseous compound of carbonic oxide and chlorine". Philosophical Transactions of the Royal Society of London. 102:...

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Polyoxymethylene

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Acetal resins are sensitive to acid hydrolysis and oxidation by agents such as mineral acid and chlorine. POM homopolymer is also susceptible to alkaline...

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Bromine compounds

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compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive...

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Oxygen fluoride

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discharge, it results in the formation of nitrogen trifluoride, oxide fluorides and other oxides. O2F2 precipitates as a brown solid upon the UV irradiation...

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Potassium peroxymonosulfate

Last Update:

Paolini, John (1995). "Reaction of Sulfoxides with Diethylaminosulfur Trifluoride". Organic Syntheses. 72: 209. doi:10.15227/orgsyn.072.0209. Frohn, Michael;...

Word Count : 664

Pnictogen

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arsenic(III) oxide, and it forms all four trihalides. Antimony forms antimony(III) oxide and antimonite but not oxyacids. Its trihalides, antimony trifluoride, antimony...

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Lanthanide

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Eugen; Wang, Shu-Guang (2013). "On structure and bonding of lanthanoid trifluorides LnF3 (Ln = La to Lu)". Physical Chemistry Chemical Physics. 2013 (15):...

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Chlorosyl fluoride

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inorganic compound of chlorine, fluorine, and oxygen with the chemical formula OClF. Partial hydrolysis of chlorine trifluoride in diluted gas phase at...

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Iodine compounds

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using multiple oxidation states. Iodine is quite reactive, but it is much less reactive than the other halogens. For example, while chlorine gas will halogenate...

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Fire

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oxygen, other compounds are able to fulfill the role. For instance, chlorine trifluoride is able to ignite sand. Fires start when a flammable or a combustible...

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