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Carbon disulfide information


Carbon disulfide
Carbon disulfide
Names
IUPAC name
Carbon disulfide
Systematic IUPAC name
Methanedithione
Other names
Carbon bisulfide
Dithiocarbonic anhydride[1]
Identifiers
CAS Number
  • 75-15-0 checkY
3D model (JSmol)
  • Interactive image
Beilstein Reference
1098293
ChEBI
  • CHEBI:23012 checkY
ChEMBL
  • ChEMBL1365180
ChemSpider
  • 6108 checkY
ECHA InfoCard 100.000.767 Edit this at Wikidata
EC Number
  • 200-843-6
KEGG
  • C19033 checkY
PubChem CID
  • 6348
RTECS number
  • FF6650000
UNII
  • S54S8B99E8 checkY
UN number 1131
CompTox Dashboard (EPA)
  • DTXSID6023947 Edit this at Wikidata
InChI
  • InChI=1S/CS2/c2-1-3 checkY
    Key: QGJOPFRUJISHPQ-UHFFFAOYSA-N checkY
  • InChI=1/CS2/c2-1-3
    Key: QGJOPFRUJISHPQ-UHFFFAOYAS
SMILES
  • S=C=S
Properties
Chemical formula
CS2
Molar mass 76.13 g·mol−1
Appearance Colorless liquid
Impure: light-yellow
Odor Pleasant, ether- or chloroform-like
Commercial: Foul, like rotten radish
Density 1.539 g/cm3 (−186°C)
1.2927 g/cm3 (0 °C)
1.266 g/cm3 (25 °C)[2]
Melting point −111.61 °C (−168.90 °F; 161.54 K)
Boiling point 46.24 °C (115.23 °F; 319.39 K)
Solubility in water
2.58 g/L (0 °C)
2.39 g/L (10 °C)
2.17 g/L (20 °C)[3]
0.14 g/L (50 °C)[2]
Solubility Soluble in alcohol, ether, benzene, oil, CHCl3, CCl4
Solubility in formic acid 4.66 g/100 g[2]
Solubility in dimethyl sulfoxide 45 g/100 g (20.3 °C)[2]
Vapor pressure 48.1 kPa (25 °C)
82.4 kPa (40 °C)[4]
Magnetic susceptibility (χ)
−42.2·10−6 cm3/mol
Refractive index (nD)
1.627[5]
Viscosity 0.436 cP (0 °C)
0.363 cP (20 °C)
Structure
Molecular shape
Linear
Dipole moment
0 D (20 °C)[2]
Thermochemistry
Heat capacity (C)
75.73 J/(mol·K)[2]
Std molar
entropy (S298)
151 J/(mol·K)[2]
Std enthalpy of
formation fH298)
88.7 kJ/mol[2]
Gibbs free energy fG)
64.4 kJ/mol[2]
Std enthalpy of
combustion cH298)
1687.2 kJ/mol[4]
Hazards
Occupational safety and health (OHS/OSH):
Inhalation hazards
Irritant; neurotoxic
Eye hazards
Irritant
Skin hazards
Irritant
GHS labelling:[5]
Pictograms
GHS02: Flammable GHS06: Toxic GHS08: Health hazard
Signal word
Danger
Hazard statements
H225, H315, H319, H361, H372
Precautionary statements
P210, P281, P305+P351+P338, P314
ICSC 0022
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
4
0
Flash point −43 °C (−45 °F; 230 K)[2]
Autoignition
temperature
102 °C (216 °F; 375 K)[2]
Explosive limits 1.3–50%[6]
Lethal dose or concentration (LD, LC):
LD50 (median dose)
3188 mg/kg (rat, oral)
LC50 (median concentration)
>1670 ppm (rat, 1 h)
15500 ppm (rat, 1 h)
3000 ppm (rat, 4 h)
3500 ppm (rat, 4 h)
7911 ppm (rat, 2 h)
3165 ppm (mouse, 2 h)[7]
LCLo (lowest published)
4000 ppm (human, 30 min)[7]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 20 ppm C 30 ppm 100 ppm (30-minute maximum peak)[6]
REL (Recommended)
TWA 1 ppm (3 mg/m3) ST 10 ppm (30 mg/m3) [skin][6]
IDLH (Immediate danger)
500 ppm[6]
Related compounds
Related compounds
Carbon dioxide
Carbonyl sulfide
Carbon diselenide
Supplementary data page
Carbon disulfide (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Carbon disulfide (also spelled as carbon disulphide) is an inorganic compound with the chemical formula CS2 and structure S=C=S. It is also considered as the anhydride of thiocarbonic acid.[8] It is a colorless, flammable, neurotoxic liquid that is used as a building block in organic synthesis. Pure carbon disulfide has a pleasant, ether- or chloroform-like odor, but commercial samples are usually yellowish and are typically contaminated with foul-smelling impurities.[9]

  1. ^ Anhydride "Dithiocarbonic". PubChem. Retrieved August 24, 2022. {{cite web}}: Check |url= value (help)
  2. ^ a b c d e f g h i j k "Properties of substance: carbon disulfide". chemister.ru.
  3. ^ Seidell, Atherton; Linke, William F. (1952). Solubilities of Inorganic and Organic Compounds. Van Nostrand.
  4. ^ a b Carbon disulfide in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD) (retrieved 2014-05-27).
  5. ^ a b Sigma-Aldrich Co., Carbon disulfide. Retrieved on 2014-05-27.
  6. ^ a b c d NIOSH Pocket Guide to Chemical Hazards. "#0104". National Institute for Occupational Safety and Health (NIOSH).
  7. ^ a b "Carbon disulfide". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  8. ^ Informatics, NIST Office of Data and. "Carbon disulfide". webbook.nist.gov. Retrieved 2024-05-07.
  9. ^ Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, ISBN 0-12-352651-5.

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Carbon disulfide

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Carbon disulfide (also spelled as carbon disulphide) is an inorganic compound with the chemical formula CS2 and structure S=C=S. It is also considered...

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Rayon

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today, using alkali and carbon disulfide The Lyocell process, using amine oxide, which avoids producing neurotoxic carbon disulfide but is more expensive...

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Carbon tetrachloride

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over carbon disulfide through a porcelain tube. Prior to the 1950s, carbon tetrachloride was manufactured by the chlorination of carbon disulfide at 105...

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Carbon disulfide hydrolase

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Carbon disulfide hydrolase is an enzyme with a molecular mass of 23,576 Da. The enzyme is hexadecameric. It catalyzes the hydrolysis of carbon disulfide...

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Carbon diselenide

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analogue of carbon disulfide (CS2) and carbon dioxide (CO2). This light-sensitive compound is insoluble in water and soluble in organic solvents. Carbon diselenide...

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Disulfide

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In chemistry, a disulfide (or disulphide in British English) is a compound containing a R−S−S−R′ functional group or the S2− 2 anion. The linkage is also...

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Aniline

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These derivatives are of importance in the color industry. Boiled with carbon disulfide, it gives sulfocarbanilide (diphenylthiourea) (S=C(−NH−C6H5)2), which...

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Cellophane

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be obtained from biomaterials. The original production process uses carbon disulfide (CS2), which has been found to be highly toxic to workers. The newer...

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Carbon dioxide

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source of available carbon in the carbon cycle, atmospheric CO2 is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent...

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Sulfide

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whereas carbon disulfide has no S–S bond, being S=C=S (linear molecule analog to CO2). Most often in sulfur chemistry and in biochemistry, the disulfide term...

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Buckminsterfullerene

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molecules. Fullerenes are sparingly soluble in aromatic solvents and carbon disulfide, but insoluble in water. Solutions of pure C60 have a deep purple color...

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Carbon compounds

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inorganic carbon-sulfur compounds are the carbon sulfides carbon disulfide (CS2) and carbonyl sulfide (OCS). Carbon monosulfide (CS) unlike carbon monoxide...

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Carbon

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control the carbon content of steel: Fe 3O 4 + 4 C(s) + 2 O 2 → 3 Fe(s) + 4 CO 2(g). Carbon reacts with sulfur to form carbon disulfide, and it reacts...

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Carbon tetroxide

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(July 2013). "On the detection of higher order carbon sulfides (CSx; x=4–6) in low temperature carbon disulfide ices". Chemical Physics Letters. 577: 42–47...

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Carbon subsulfide

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compound is analogous to carbon suboxide whose structure is O=C=C=C=O. Lengyel first synthesized this compound by passing carbon disulfide (CS2) vapor through...

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Lyocell

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the more common viscose processes, Lyocell production does not use carbon disulfide, which is toxic to workers and the environment. Lyocell was originally...

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Solvent

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solvents should be stored open and upside down. Both diethyl ether and carbon disulfide have exceptionally low autoignition temperatures which increase greatly...

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Bamboo textile

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The viscose rayon process then treats the fibers with lye, and adds carbon disulfide to form sodium cellulose xanthate. After time, temperature, and various...

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Courtaulds

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£14 million and the Lancashire Cotton Corporation for £22 million. Carbon disulfide, used in rayon production, increases the risk of heart attacks and...

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Sulfur

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(68 °F) and 50 °C (122 °F). Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as...

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Resorcinol

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soluble in water, alcohol, and ether, but insoluble in chloroform and carbon disulfide. Resorcinol is produced in several steps from benzene, starting with...

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Organic compound

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cyaphide anion CP−, CSe2, COS; although carbon disulfide CS2 is often classed as an organic solvent). Halides of carbon without hydrogen (e.g., CF4 and CClF3)...

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Organosulfur chemistry

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with double bonds between carbon and sulfur are relatively uncommon, but include the important compounds carbon disulfide, carbonyl sulfide, and thiophosgene...

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Holland Tunnel fire

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incident. At 8:30 a.m. a truck carrying eighty 55-gallon (210 L) drums of carbon disulfide entered the southern tube at the New Jersey portal. The tunnel has...

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Xanthate

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alkali metals are produced by the treatment of an alcohol, alkali, and carbon disulfide. The process is called xanthation. In chemical terminology, the alkali...

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Petroleum jelly

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is soluble in dichloromethane, chloroform, benzene, diethyl ether, carbon disulfide and turpentine. Petroleum jelly is slightly soluble in alcohol. It...

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Carbonyl sulfide

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Carbonyl sulfide can be considered to be intermediate between carbon dioxide and carbon disulfide, both of which are valence isoelectronic with it. Carbonyl...

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Barking dog reaction

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exothermic chemical reaction that results from the ignition of a mixture of carbon disulfide and nitrous oxide. When ignited in a cylindrical tube, the reaction...

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Selenium

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form in bi-elemental solutions with nonpolar solvents, such as carbon disulfide and carbon tetrachloride; but even these appear to decompose under illumination...

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