Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Boron monofluoride monoxide or oxoboryl fluoride[2] or fluoroxoborane is an unstable inorganic molecular substance with formula FBO. It is also called boron fluoride oxide, fluoro(oxo)borane or fluoro-oxoborane. The molecule is stable at high temperatures, but below 1000 °C condenses to a trimer (BOF)3 called trifluoroboroxin. FBO can be isolated as a triatomic non-metallic molecule in an inert gas matrix, and has been condensed in solid neon and argon.[3] When an attempt is made to condense the gas to a solid in bulk, a polymeric glass is formed, which is deficient in fluoride, and when heated forms a glassy froth like popcorn.[4][5] Boron fluoride oxide has been studied because of its production in high energy rocket fuels that contain boron and fluorine, and in the form of an oxyfluoride glass. BOF glass is unusual in that it can condense directly from gas.[6]
^Larson, J. W.; McMahon, T. B. (1987). "Boron monofluoride monoxide". 26 (24). NIST: 4018. doi:10.1021/ic00271a011. Retrieved 20 May 2015. {{cite journal}}: Cite journal requires |journal= (help)
^Kuchitsu, Kozo (2013-03-09). Structure of Free Polyatomic Molecules: Basic Data. Springer Science & Business Media. p. 28. ISBN 9783642457487.
^Jacox, Marilyn E. (December 1994). "The vibrational energy levels of small transient molecules isolated in neon and argon matrices". Chemical Physics. 189 (2): 149–170. Bibcode:1994CP....189..149J. doi:10.1016/0301-0104(94)00143-X.
^Boussard-Plédel, Catherine; Le Floch, Marie; Fonteneau, Gilles; Lucas, Jacques (July 1997). "Vapor Phase Deposition of Foaming Boron Oxyfluoride Vitreous Materials". Materials Research Bulletin. 32 (7): 805–811. doi:10.1016/S0025-5408(97)00050-0.
^Cite error: The named reference bous was invoked but never defined (see the help page).
^Polishchuk, S. A.; Ignat’eva, L. N.; Marchenko, Yu. V.; Bouznik, V. M. (5 March 2011). "Oxyfluoride glasses (A review)". Glass Physics and Chemistry. 37 (1): 1–20 (14). doi:10.1134/S108765961101010X. S2CID 97609959.
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