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Aluminium sulfate information


Aluminium sulfate
Aluminium sulphate hexadecahydrate
Names
IUPAC name
Aluminium sulfate
Other names
  • Aluminum sulfate
  • Aluminium sulphate
  • Cake alum
  • Filter alum
  • Papermaker's alum
  • Alunogenite
  • aluminium salt (3:2)
Identifiers
CAS Number
  • 10043-01-3 checkY
  • 7784-31-8 (octadecahydrate) checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 23233 checkY
ECHA InfoCard 100.030.110 Edit this at Wikidata
EC Number
  • 233-135-0
E number E520 (acidity regulators, ...)
PubChem CID
  • 24850
RTECS number
  • BD1700000
UNII
  • I7T908772F checkY
  • TCS9L00G8F (octadecahydrate) checkY
CompTox Dashboard (EPA)
  • DTXSID2040317 Edit this at Wikidata
InChI
  • InChI=1S/2Al.3H2O4S/c;;3*1-5(2,3)4/h;;3*(H2,1,2,3,4)/q2*+3;;;/p-6 checkY
    Key: DIZPMCHEQGEION-UHFFFAOYSA-H checkY
  • InChI=1/2Al.3H2O4S/c;;3*1-5(2,3)4/h;;3*(H2,1,2,3,4)/q2*+3;;;/p-6
    Key: DIZPMCHEQGEION-CYFPFDDLAS
SMILES
  • [Al+3].[Al+3].[O-]S(=O)(=O)[O-].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
Properties
Chemical formula
Al2(SO4)3
Molar mass 342.15 g/mol (anhydrous)
666.44 g/mol (octadecahydrate)
Appearance white crystalline solid
hygroscopic
Density 2.672 g/cm3 (anhydrous)
1.62 g/cm3 (octadecahydrate)
Melting point 770 °C (1,420 °F; 1,040 K) (decomposes, anhydrous)
86.5 °C (octadecahydrate)
Solubility in water
31.2 g/100 mL (0 °C)
36.4 g/100 mL (20 °C)
89.0 g/100 mL (100 °C)
Solubility slightly soluble in alcohol, dilute mineral acids
Acidity (pKa) 3.3–3.6
Magnetic susceptibility (χ)
−93.0×10−6 cm3/mol
Refractive index (nD)
1.47[1]
Structure
Crystal structure
monoclinic (hydrate)
Thermochemistry
Std enthalpy of
formation fH298)
-3440 kJ/mol
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
NIOSH (US health exposure limits):
PEL (Permissible)
none[2]
REL (Recommended)
2 mg/m3[2]
IDLH (Immediate danger)
N.D.[2]
Related compounds
Other cations
Gallium sulfate
Magnesium sulfate
Related compounds
See Alum
Supplementary data page
Aluminium sulfate (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Aluminium sulfate is a salt with the formula Al2(SO4)3. It is soluble in water and is mainly used as a coagulating agent (promoting particle collision by neutralizing charge) in the purification of drinking water[3][4] and wastewater treatment plants, and also in paper manufacturing.

The anhydrous form occurs naturally as a rare mineral millosevichite, found for example in volcanic environments and on burning coal-mining waste dumps. Aluminium sulfate is rarely, if ever, encountered as the anhydrous salt. It forms a number of different hydrates, of which the hexadecahydrate Al2(SO4)3·16H2O and octadecahydrate Al2(SO4)3·18H2O are the most common. The heptadecahydrate, whose formula can be written as [Al(H2O)6]2(SO4)3·5H2O, occurs naturally as the mineral alunogen.

Aluminium sulfate is sometimes called alum or papermaker's alum in certain industries. However, the name "alum" is more commonly and properly used for any double sulfate salt with the generic formula XAl(SO
4
)
2
·12H
2
O
, where X is a monovalent cation such as potassium or ammonium.[5]

  1. ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0-07-049439-8
  2. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0024". National Institute for Occupational Safety and Health (NIOSH).
  3. ^ Global Health and Education Foundation (2007). "Conventional Coagulation-Flocculation-Sedimentation". Safe Drinking Water is Essential. National Academy of Sciences. Archived from the original on 2007-10-07. Retrieved 2007-12-01.
  4. ^ Kvech S, Edwards M (2002). "Solubility controls on aluminum in drinking water at relatively low and high pH". Water Research. 36 (17): 4356–4368. Bibcode:2002WatRe..36.4356K. doi:10.1016/S0043-1354(02)00137-9. PMID 12420940.
  5. ^ Austin, George T. (1984). Shreve's Chemical process industries (5th ed.). New York: McGraw-Hill. p. 357. ISBN 9780070571471. Archived from the original on 2014-01-03.

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Potassium alum, potash alum, or potassium aluminium sulfate is a chemical compound first found mentioned under various Sanskrit names in Ayurvedic medicinal...

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Baking powder

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acid phosphate). High-temperature acid salts include sodium aluminium sulfate, sodium aluminium phosphate, and sodium acid pyrophosphate. Baking powders...

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(/ˈæləm/) is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula XAl(SO 4) 2·12 H 2O, such that X is a...

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Aluminium nitrate

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reacting nitric acid with aluminium hydroxide. Aluminium nitrate may also be prepared a metathesis reaction between aluminium sulfate and a nitrate salt with...

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Aluminium chlorohydrate

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destabilizing and removing suspended materials than other aluminium salts such as aluminium sulfate, aluminium chloride and various forms of polyaluminium chloride...

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drying agent or absorbent. Several sulfates of aluminium have industrial and commercial application. Aluminium sulfate (in its hydrate form) is produced...

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Sodium alum

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Sodium aluminium sulfate is the inorganic compound with the chemical formula NaAl(SO4)2·12H2O (sometimes written Na2SO4·Al2(SO4)3·24H2O). Also known as...

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Aluminium hydroxide

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for the manufacture of other aluminium compounds: calcined aluminas, aluminium sulfate, polyaluminium chloride, aluminium chloride, zeolites, sodium aluminate...

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Aluminium sulfacetate

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Al 2SO 4(CH 3CO 2) 4. It is an evenly balanced mixture of aluminium sulfate and aluminium acetate. It can be used as a mordant, which is a substance...

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Anodizing

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plating materials. The most common anodizing effluents, aluminium hydroxide and aluminium sulfate, are recycled for the manufacturing of alum, baking powder...

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Sulfuric acid

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bisulfate: NaCl + H2SO4 → NaHSO4 + HCl Aluminium sulfate, also known as paper maker's alum, aluminium sulfate is made by treating bauxite with sulfuric...

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Aluminium carbonate

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response to its presence. The reaction of aluminium sulfate and sodium bicarbonate forms carbon dioxide and aluminium hydroxide which stabilises the formation...

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Vitriol

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color, such as green vitriol for hydrated iron(II) sulfate and blue vitriol for hydrated copper(II) sulfate. These materials were found originally as crystals...

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Aluminium triacetate

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NaCl   +   26 H 2O The mordants aluminium triacetate and aluminium sulfacetate can be prepared from aluminium sulfate, the product formed being determined...

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Clarifying agent

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aqueous solution. alum aluminium chlorohydrate aluminium sulfate calcium oxide calcium hydroxide iron(II) sulfate (ferrous sulfate) iron(III) chloride (ferric...

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Ettringite

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Ettringite is a hydrous calcium aluminium sulfate mineral with formula: Ca6Al2(SO4)3(OH)12·26H2O. It is a colorless to yellow mineral crystallizing in...

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Leavening agent

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List of inorganic compounds

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AlF3 Aluminium hydroxide – Al(OH)3 Aluminium nitrate – Al(NO3)3 Aluminium sulfide – Al2S3 Aluminium sulfate – Al2(SO4)3 Aluminium potassium sulfate – KAl(SO4)2...

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Sodium hydroxide

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treatment. Aluminium hydroxide is prepared at the treatment plant from aluminium sulfate by reacting it with sodium hydroxide or bicarbonate. Al2(SO4)3 + 6...

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Molluscicide

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employed as a molluscicide: Metal salts such as iron(III) phosphate, aluminium sulfate, and ferric sodium EDTA, relatively non-toxic, most are approved for...

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Antihemorrhagic

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Hydrangea macrophylla

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