Anodizing is an electrolytic passivation process used to increase the thickness of the natural oxide layer on the surface of metal parts.
The process is called anodizing because the part to be treated forms the anode electrode of an electrolytic cell. Anodizing increases resistance to corrosion and wear, and provides better adhesion for paint primers and glues than bare metal does. Anodic films can also be used for several cosmetic effects, either with thick porous coatings that can absorb dyes or with thin transparent coatings that add reflected light wave interference effects.
Anodizing is also used to prevent galling of threaded components and to make dielectric films for electrolytic capacitors. Anodic films are most commonly applied to protect aluminium alloys, although processes also exist for titanium, zinc, magnesium, niobium, zirconium, hafnium, and tantalum. Iron or carbon steel metal exfoliates when oxidized under neutral or alkaline micro-electrolytic conditions; i.e., the iron oxide (actually ferric hydroxide or hydrated iron oxide, also known as rust) forms by anoxic anodic pits and large cathodic surface, these pits concentrate anions such as sulfate and chloride accelerating the underlying metal to corrosion. Carbon flakes or nodules in iron or steel with high carbon content (high-carbon steel, cast iron) may cause an electrolytic potential and interfere with coating or plating. Ferrous metals are commonly anodized electrolytically in nitric acid or by treatment with red fuming nitric acid to form hard black Iron(II,III) oxide. This oxide remains conformal even when plated on wiring and the wiring is bent.
Anodizing changes the microscopic texture of the surface and the crystal structure of the metal near the surface. Thick coatings are normally porous, so a sealing process is often needed to achieve corrosion resistance. Anodized aluminium surfaces, for example, are harder than aluminium but have low to moderate wear resistance that can be improved with increasing thickness or by applying suitable sealing substances. Anodic films are generally much stronger and more adherent than most types of paint and metal plating, but also more brittle. This makes them less likely to crack and peel from ageing and wear, but more susceptible to cracking from thermal stress.
A galvanic anode, or sacrificial anode, is the main component of a galvanic cathodic protection system used to protect buried or submerged metal structures...
Anodic bonding is a wafer bonding process to seal glass to either silicon or metal without introducing an intermediate layer; it is commonly used to seal...
An anode ray (also positive ray or canal ray) is a beam of positive ions that is created by certain types of gas-discharge tubes. They were first observed...
Anodic protection (AP) otherwise referred to as Anodic Control is a technique to control the corrosion of a metal surface by making it the anode of an...
McGraw-Hill. pp. 624–628. Brace, A.W; Sheasby, P.G. (1979). The Technology of Anodizing Aluminum. Gloucestershire: Technicopy Limited. pp. 218–220. Wernick, S...
materials. The basis of all these is still using two electrodes, anodes and cathodes. 'Anode' was coined by William Whewell at Michael Faraday's request,...
thickness. Anodizing aluminum has been widely used since early last century for corrosion protection and decorative purposes. The porous nature of anodic alumina...
be protected to a more easily corroded "sacrificial metal" to act as the anode. The sacrificial metal then corrodes instead of the protected metal. For...
Conductive anodic filament, also called CAF, is a metallic filament that forms from an electrochemical migration process and is known to cause printed...
for an accelerated attack on the anode metal, which dissolves into the electrolyte. This leads to the metal at the anode corroding more quickly than it...
treatment process for generating oxide coatings on metals. It is similar to anodizing, but it employs higher potentials, so that discharges occur and the resulting...
explanation for them, and introduced terminology such as electrode, electrolyte, anode, cathode, anion, and cation. 1875 – Paul Émile Lecoq de Boisbaudran discovered...
grid) is inserted between the cathode and the anode, the flow of electrons between the cathode and anode can be regulated by varying the voltage on this...
electro-oxidation (i.e positive or anodic current on the working electrode), although such processes are more commonly referred to as anodizing rather than electroplating...
electron-emitting cathode and an anode. Electrons can flow in only one direction through the device—from the cathode to the anode. Adding one or more control...
Hong-Hsiang (Harry); Kia, Sheila (2006). "Effect of alloy types on the anodizing process of aluminum". Surface and Coatings Technology. 200 (8): 2634–41...
electrochemistry, partial current is defined as the electric current associated with (anodic or cathodic) half of the electrode reaction. Depending on the electrode...
Electropolishing, also known as electrochemical polishing, anodic polishing, or electrolytic polishing (especially in the metallography field), is an electrochemical...
precisely, the anode heel effect is a variation of the intensity of X-rays emitted by the anode depending on the direction of emission along the anode-cathode...
cathode. In electrorefining, the anode consists of the impure metal (e.g., copper) to be refined. The impure metallic anode is oxidized and the metal dissolves...
is determined by the anodizing voltage. The image to the left shows the color spectrum range that can be achieved by anodizing. The colors, which are...
calibre rounds. Aluminium oxide can be grown as a coating on aluminium by anodizing or by plasma electrolytic oxidation (see the "Properties" above). Both...
allows complex shapes to be formed with very smooth surfaces fit for anodizing and so is popular for visible architectural applications such as window...