Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Allyl chloride is the organic compound with the formula CH2=CHCH2Cl. This colorless liquid is insoluble in water but soluble in common organic solvents. It is mainly converted to epichlorohydrin, used in the production of plastics. It is a chlorinated derivative of propylene. It is an alkylating agent, which makes it both useful and hazardous to handle.[4]
^ abcdefghNIOSH Pocket Guide to Chemical Hazards. "#0018". National Institute for Occupational Safety and Health (NIOSH).
^Viswanath, D.S.; Natarajan, G. (1989). Data Book on the Viscosity of Liquids. Hemisphere Publishing Corporation. ISBN 0-89116-778-1.
^"Allyl chloride". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
^Cite error: The named reference Ullmann was invoked but never defined (see the help page).
Allylchloride is the organic compound with the formula CH2=CHCH2Cl. This colorless liquid is insoluble in water but soluble in common organic solvents...
or of everyday importance, for example, allylchloride. Allylation is any chemical reaction that adds an allyl group to a substrate. A site adjacent to...
alkylating agent. Allyl bromide is more reactive but more expensive than allylchloride, and these considerations guide its use. Allyl bromide is produced...
allylchloride route is that it does not generate salt. Also avoiding chloride-containing intermediates is the "acetoxylation" of propylene to allyl acetate:...
the adduct of cycloheptatriene and dimethyl acetylenedicarboxylate. Allylchloride undergoes dehydrohalogenation upon treatment with the base sodium amide...
extender in food packaging.: 118–120 Allyl isothiocyanate is produced commercially by the reaction of allylchloride and potassium thiocyanate: CH2=CHCH2Cl...
and elastomers. Epichlorohydrin is traditionally manufactured from allylchloride in two steps, beginning with the addition of hypochlorous acid, which...
and a green chemical. Allyl alcohol is also produced primarily from allylchloride, but production via the hydrolysis of allyl acetate route avoids the...
breath" is attributed to its presence. It is prepared by the reaction of allylchloride with sodium hydroxide and methanethiol. CH2=CHCH2Cl + NaOH (aq) + CH3SH...
lacrymator. It is an alkylating agent that is used in organic synthesis. Allylchloride Propargyl Propargyl alcohol *Merck Index, 11th Edition, 7820 M. Olomucki...
are produced by the treating allylchloride with ammonia followed by distillation. Or by the reaction of allylchloride with Hexamine. Pure samples can...
ethers – from the condensation of glycols acrylic acid acrylic polymers allylchloride epichlorohydrin – chloro-oxirane; used in epoxy resin formation epoxy...
hexadienoic acids, which are available via a nickel-catalyzed reaction of allylchloride, acetylene, and carbon monoxide. The route used commercially, however...
Calgon Corp. The monomer DADMAC is formed by reacting two equivalents of allylchloride with dimethylamine. PolyDADMAC is then synthesized by radical polymerization...
precursors to fatty amine derivatives. Related free radical additions to allylchloride and styrene give 1-bromo-3-chloropropane and phenylethylbromide, respectively...
reactions. One example is the Friedel–Crafts alkylation of benzene by allylchloride to yield beta chloropropylbenzene which is then reacted with ammonia...
hexadiene. Allylchloride can also be used in place of the bromide to give allylmagnesium chloride. These reagents are used to prepare metal allyl complexes...
colorless liquid and a lacrymator. Its properties are similar to those of allylchloride. It is a strong alkylating agent used to install isobutenyl groups....
Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2·nH2O, with n ranging from 0 to 4.5, forming hydrates. Zinc chloride, anhydrous...
Epichlorohydrin is the most important precursor. chlorination of propylene gives allylchloride, which is oxidized with hypochlorite to dichlorohydrin, which reacts...
vinylogous: In allyl compounds, where the next carbon is saturated but substituted once, allylic rearrangement and related reactions are observed. Allyl Grignard...
serves as a source of "Mo(CO)3". For instance treatment with allylchloride gives [MoCl(allyl)(CO)2(MeCN)2], whereas treatment with KTp and sodium cyclopentadienide...
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