Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Allyl bromide (3-bromopropene) is an organic halide. It is an alkylating agent used in synthesis of polymers, pharmaceuticals, perfumes[2] and other organic compounds. Allyl bromide is a colorless liquid, although commercial samples appear yellow or brown. It is an irritant and a potentially dangerous alkylating agent. Allyl bromide is more reactive but more expensive than allyl chloride, and these considerations guide its use.[3]
^ abcdefghiCRC handbook of chemistry and physics : a ready-reference book of chemical and physical data. William M. Haynes, David R. Lide, Thomas J. Bruno (2016-2017, 97th ed.). Boca Raton, Florida. 2016. ISBN 978-1-4987-5428-6. OCLC 930681942.{{cite book}}: CS1 maint: location missing publisher (link) CS1 maint: others (link)
^PubChem. "Hazardous Substances Data Bank (HSDB) : 622". pubchem.ncbi.nlm.nih.gov. Retrieved 2022-03-04.
^Yoffe, David; Frim, Ron; Ukeles, Shmuel D.; Dagani, Michael J.; Barda, Henry J.; Benya, Theodore J.; Sanders, David C. (2013). "Bromine Compounds". Ullmann's Encyclopedia of Industrial Chemistry. pp. 1–31. doi:10.1002/14356007.a04_405.pub2. ISBN 978-3-527-30385-4.
Allylbromide (3-bromopropene) is an organic halide. It is an alkylating agent used in synthesis of polymers, pharmaceuticals, perfumes and other organic...
stronger acid (HBr) and release of the weaker acid (HCl). Allylbromide is prepared by treating allyl alcohol with HBr: CH2=CHCH2OH + HBr → CH2=CHCH2Br + H2O...
Allyl chloride is highly toxic and flammable. Eye effects may be delayed and may lead to possible impairment of vision. AllylAllylbromideAllyl iodide...
commercial synthesis of allylbromide: CH2=CHCH2OH + HBr → CH2=CHCH2Br + H2O Allyl alcohol is hepatotoxic. In rats, in vivo, allyl alcohol is metabolized...
obtained by the reaction of allyl acetate with hydrogen cyanide. A laboratory route to allyl cyanide involves treating allylbromide with copper(I) cyanide...
Allylmagnesium bromide is a Grignard reagent used for introducing the allyl group. It is commonly available as a solution in diethyl ether. It may be synthesized...
of allylbromide: HOCH2CH=CH2 + HBr → BrCH2CH=CH2 + H2O Methyl bromide, another fumigant, is generated from methanol and hydrogen bromide. Bromide ions...
Allyl phenyl ether is prepared by the reaction of sodium phenoxide with allylbromide: C6H5ONa + BrCH2CH=CH2 → C6H5OCH2CH=CH2 + NaBr The yield is almost quantitative...
Group 2A carcinogens as a suspected human carcinogen. Vinyl chloride Allylbromide Bromoethane NIOSH Pocket Guide to Chemical Hazards. "#0657". National...
significant organic compounds prepared from hydrobromic acid include allylbromide, tetrabromobis(phenol), and bromoacetic acid. HBr almost uniquely participates...
stereoselectivity. The resulting enolate can then be allylated using allylbromide to give ketone 11. In the body, in vivo studies indicate that both enantiomers...
Rocuronium bromide (brand names Zemuron, Esmeron) is an aminosteroid non-depolarizing neuromuscular blocker or muscle relaxant used in modern anaesthesia...
bromide, i.e., CH2=C=CHMgBr. Propargyl bromide is a lachrymator and an alkylating agent. Propargyl Propargyl chloride Propargyl alcohol Allylbromide...
Allyl isothiocyanate (AITC) is a naturally occurring unsaturated isothiocyanate. The colorless oil is responsible for the pungent taste of cruciferous...
ether gives the aldehyde (4). Treatment of the crude aldehyde with allylbromide and zinc powder in water with NH4Cl as catalyst resulted in an anti:syn...
conversion to methylenedioxybenzene, which is brominated and coupled with allylbromide. Safrole is a versatile precursor to many compounds. Examples are N-acylarylhydrazones...
preparation of Taxol by this route include verbenone, prenyl bromine, allylbromide, propiolic acid, Gilman reagent, and Eschenmoser's salt. The taxol synthesis...
treated with at least 3 equivalents of an activated halide (such as allylbromide or iodomethane) and CDI yields the corresponding halide with good yield...
3-methyl-2-buten-1-ol is 15%. Allylic shifts occur because the transition state is an allyl intermediate. In other respects they are similar to classical nucleophilic...
The molecular formula C3H5Br may refer to: Allylbromide Bromocyclopropane This set index page lists chemical structure articles associated with the same...
PMID 16900548. In this example the arylzinc iodide continues to react with allylbromide in a nucleophilic displacement Merck Index. Merck & Co. 2001. ISBN 9780911910131...
radicals are responsible for anti-Markovnikov addition of hydrogen bromide to allylbromide. March 10 – Long Beach earthquake in Southern California: First...
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