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Allotropes of arsenic information


Molecular structures of arsenic allotropes. Top left: Gray (metallic) arsenic, rhombohedral structure. Bottom left: Black arsenic, orthorhombic structure. Right: Yellow arsenic, tetrahedral configuration.[1]

Arsenic in the solid state can be found as gray, black, or yellow allotropes. These various forms feature diverse structural motifs, with yellow arsenic enabling the widest range of reactivity. In particular, reaction of yellow arsenic with main group and transition metal elements results in compounds with wide-ranging structural motifs, with butterfly, sandwich and realgar-type moieties featuring most prominently.

  1. ^ Seidl, Michael; Balázs, Gábor; Scheer, Manfred (2019-03-22). "The Chemistry of Yellow Arsenic". Chemical Reviews. 119 (14): 8406–8434. doi:10.1021/acs.chemrev.8b00713. ISSN 0009-2665. PMID 30900440. S2CID 85448636.

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Allotropes of arsenic

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Arsenic in the solid state can be found as gray, black, or yellow allotropes. These various forms feature diverse structural motifs, with yellow arsenic...

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Arsenic

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various allotropes, but only the grey form, which has a metallic appearance, is important to industry. The primary use of arsenic is in alloys of lead (for...

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Allotropy

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californium have three allotropes each. In 2017, the concept of nanoallotropy was proposed. Nanoallotropes, or allotropes of nanomaterials, are nanoporous...

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Antimony

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the gray allotrope of arsenic, and is formed when molten antimony is cooled slowly. Amorphous black antimony is formed upon rapid cooling of antimony...

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Homonuclear molecule

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phosphorus (P4). Allotropes are different chemical forms of the same element (not containing any other element). In that sense, allotropes are all homonuclear...

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Metalloid

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selenium. Different crystalline forms of an element are called allotropes. Some allotropes, particularly those of elements located (in periodic table terms)...

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Periodic table

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structures: these are called allotropes. For example, diamond and graphite are two allotropes of carbon. The metallicity of an element can be predicted...

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Chalcogen

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allotropes include rhombic sulfur and monoclinic sulfur. Rhombic sulfur is the more stable of the two allotropes. Monoclinic sulfur takes the form of...

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Carbon

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with diverse molecular configurations called allotropes. The three relatively well-known allotropes of carbon are amorphous carbon, graphite, and diamond...

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Allotropes of silicon

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Allotropes of silicon are structurally varied forms of silicon. Amorphous silicon takes the form of a brown powder. Crystalline silicon has a metallic...

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Nonmetal

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have the electronic band structures of semimetals, although both have less stable semiconducting allotropes: arsenic as arsenolamprite, an extremely rare...

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Selenium

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chains is 343.6 pm. Gray selenium is formed by mild heating of other allotropes, by slow cooling of molten selenium, or by condensing selenium vapor just below...

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Pnictogen

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family. Group 15 consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc). Since 1988, IUPAC...

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Chemical element

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densities similar to those of the other elements. When an element has allotropes with different densities, one representative allotrope is typically selected...

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Nitrogen

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at the head of group 15 in the periodic table, its chemistry shows huge differences from that of its heavier congeners phosphorus, arsenic, antimony, and...

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Carbon group

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known allotropes that exist at room temperature. These allotropes are known as the amorphous and the crystalline allotropes. The amorphous allotrope is a...

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Sulfur

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ISBN 978-0-12-352651-9. Steudel, Ralf; Eckert, Bodo (2003). Solid Sulfur Allotropes Sulfur Allotropes. Topics in Current Chemistry. Vol. 230. pp. 1–80. doi:10.1007/b12110...

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Metal

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substances) are expected to metallize. Arsenic (As) has both a stable metallic allotrope and a metastable semiconducting allotrope at standard conditions. Elements...

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Phosphorus

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agents. Phosphorus has several allotropes that exhibit strikingly diverse properties. The two most common allotropes are white phosphorus and red phosphorus...

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Tin

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of stable isotopes in the periodic table, due to its magic number of protons. It has two main allotropes: at room temperature, the stable allotrope is...

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Plutonium

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Plutonium normally has six allotropes and forms a seventh (zeta, ζ) at high temperature within a limited pressure range. These allotropes, which are different...

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Lead compounds

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example, halogenization of lead(II) salts. The alpha allotrope is rhombohedral, and the beta allotrope is tetragonal. Both allotropes are black-brown in color...

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Boron

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produced with difficulty because of contamination by carbon or other elements that resist removal. Several allotropes exist: amorphous boron is a brown...

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Molecular solid

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form, and the weak intermolecular interactions of the molecules. See also higher alkanes Allotropes of phosphorus are useful to further demonstrate this...

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Oxygen

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continuously replenished by the photosynthetic action of living organisms. Another form (allotrope) of oxygen, ozone (O 3), strongly absorbs ultraviolet UVB...

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Caesium

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reflected; hence it appears yellowish. Caesium exists in the form of different allotropes, One of which is a dimer called dicaesium. Caesium metal is highly...

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Coordination number

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corners of a cube. The two most common allotropes of carbon have different coordination numbers. In diamond, each carbon atom is at the centre of a regular...

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Explosive antimony

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Chemistry of Arsenic, Antimony and Bismuth. Springer Science & Business Media. p. 50. ISBN 9780751403893. Retrieved 2016-11-21. Another possible allotrope, known...

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Semimetal

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The classic semimetallic elements are arsenic, antimony, bismuth, α-tin (gray tin) and graphite, an allotrope of carbon. The first two (As, Sb) are also...

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Silicon

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thermodynamically stable allotropes at standard pressure, but several other crystal structures are known at higher pressures. The general trend is one of increasing...

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