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Xenon tetrachloride information


Xenon tetrachloride
Identifiers
CAS Number
  • 14989-42-5 checkY
3D model (JSmol)
  • Interactive image
PubChem CID
  • 149605668
InChI
  • InChI=1S/Cl4Xe/c1-5(2,3)4
    Key: YPLOYFASLUPKHY-UHFFFAOYSA-N
SMILES
  • Cl[Xe](Cl)(Cl)Cl
Properties
Chemical formula
Cl4Xe
Molar mass 273.09 g·mol−1
Related compounds
Related compounds
XeF4, XeCl2, XeCl
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Xenon tetrachloride is an unstable[1] inorganic compound with the chemical formula XeCl4. Unlike other noble gas/halide compounds, it cannot be synthesized by simply combining the elements, by using a more-active halogenating agent, or by substitution of other halides on tetrahaloxenon compounds. Instead, a decay technique can be used, starting with K129ICl4. The iodine-129 atom of the 129
ICl
4
covalent cluster is radioactive and undergoes beta decay to become xenon-129.[2][3] The resulting XeCl4 molecule has a square planar molecular geometry analogous to xenon tetrafluoride.[4]

Alternately, the product can be obtained by subjecting the elements to an electric discharge.[1]

  1. ^ a b Holleman, A.F.; Wiberg, E.; Wiberg, N.; Eagleson, M.; Brewer, W. (2001). Inorganic Chemistry. Academic Press. p. 394. ISBN 9780123526519. LCCN 2001091215.
  2. ^ Bell, C.F. (2013). Syntheses and Physical Studies of Inorganic Compounds. Elsevier Science. p. 143. ISBN 9781483280608.
  3. ^ Cockett, A.H.; Smith, K.C.; Bartlett, N. (2013). The Chemistry of the Monatomic Gases: Pergamon Texts in Inorganic Chemistry. Elsevier Science. p. 292. ISBN 9781483157368.
  4. ^ Perlow, G. J.; Perlow, M. R. (15 August 1964). "Mössbauer Effect Evidence for the Existence and Structure of XeCl4". The Journal of Chemical Physics. 41 (4): 1157–1158. Bibcode:1964JChPh..41.1157P. doi:10.1063/1.1726022.

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Xenon tetrachloride

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Xenon tetrachloride is an unstable inorganic compound with the chemical formula XeCl4. Unlike other noble gas/halide compounds, it cannot be synthesized...

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Tetrachloride

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reagent in the preparation of vanadium compounds Xenon tetrachloride, XeCl4 Zirconium tetrachloride, ZrCl4, an intermediate in the conversion of zirconium...

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Xenon

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molecule XeCl 2 is less stable than the van der Waals complex. Xenon tetrachloride and xenon dibromide are even more unstable and they cannot be synthesized...

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Xenon compounds

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molecule XeCl 2 is less stable than the van der Waals complex. Xenon tetrachloride and xenon dibromide are more unstable that they cannot be synthesized...

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Xenon monochloride

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xenon (3P2), argon (3P0) and argon (3P2) atoms by fluorine-containing molecules: Silane, dichlorosilane, trichlorosilane, and silicon tetrachloride"...

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Glossary of chemical formulae

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14989-42-5 XeCl4 Xenon tetrachloride 13780-38-6 XeF Xenon monofluoride XeF2 Xenon difluoride 13709-36-9 XeF4 Xenon tetrafluoride 13709-61-0 XeF6 Xenon hexafluoride...

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Iodine

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among other polyiodides. Nonpolar solvents such as hexane and carbon tetrachloride provide a higher solubility. Polar solutions, such as aqueous solutions...

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List of inorganic compounds

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Vanadium tetrachloride – VCl4 Vanadium tetrafluoride – VF4 Water – H2O Perxenic acid – H4XeO6 Xenon difluoride – XeF2 Xenon hexafluoride – XeF6 Xenon hexafluoroplatinate...

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Clathrate compound

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Frampton, C. S.; Schrobilgen, G. J.; Valsdóttir, J. (1989). "Β-Hydroquinone xenon clathrate". Acta Crystallographica Section C Crystal Structure Communications...

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Kinetic diameter

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Hydrogen bromide HBr 81 350 Krypton Kr 84 360 Xenon Xe 131 396 Sulfur hexafluoride SF6 146 550 Carbon tetrachloride CCl4 154 590 Bromine Br2 160 350...

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Titanium

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the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and titanium trichloride...

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Lava lamp

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translucent, or opaque mix of mineral oil, paraffin wax, and carbon tetrachloride.p. 2, line 30 The clear water or mineral oil can optionally be coloured...

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Tetrahedral molecular geometry

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(Pd[P(C6H5)3]4), nickel carbonyl (Ni(CO)4), and titanium tetrachloride (TiCl4). Many complexes with incompletely filled d-shells are often...

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Octahedral molecular geometry

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tetrahalides often exist as polymers with edge-sharing octahedra. Zirconium tetrachloride is an example. Compounds with face-sharing octahedral chains include...

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Chlorine

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tetrachloride, or an organic chloride. For instance, zirconium dioxide reacts with chlorine at standard conditions to produce zirconium tetrachloride...

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Organotellurium chemistry

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departure from sulfur and selenium chemistry is the availability of the tetrachloride, TeCl4. It reacts with arenes to give aryltellurium trichlorides: ArH...

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Inorganic chemistry

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gas compounds include several derivatives of xenon and krypton. Examples: xenon hexafluoride XeF6, xenon trioxide XeO3, and krypton difluoride KrF2 Usually...

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List of viscosities

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618 2.51 Argon Ar 22.61 0.0178 313 2.52 Krypton Kr 25.38 0.0094 149 2.49 Xenon Xe 23.08 0.0056 95.0 2.55 Radon Rn ≈26 ≈0.00364 56.2 T = 26.85 °C; k {\displaystyle...

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List of CAS numbers by chemical compound

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XeF xenon monofluoride 16757–14–5 XeF2 xenon difluoride 13709–36–9 XeF4 xenon tetrafluoride 13709–61–0 XeF6 xenon hexafluoride 13693–09–9 XeOF4 xenon oxytetrafluoride...

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MEMS

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small molecules rich in chlorine or fluorine. For instance, carbon tetrachloride (CCl4) etches silicon and aluminium, and trifluoromethane etches silicon...

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Germanium

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also determined an atomic weight of 72.32 by analyzing pure germanium tetrachloride (GeCl 4), while Lecoq de Boisbaudran deduced 72.3 by a comparison of...

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Osmium compounds

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any chemical element aside from iridium's +9 and is encountered only in xenon, ruthenium, hassium, iridium, and plutonium. The oxidation states −1 and...

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Monosodium xenate

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owing to being a highly reactive compound of xenon. Monosodium xenate can be made by mixing solutions of xenon trioxide and sodium hydroxide, followed by...

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Bromine

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reversible direct reaction of its elements in the gas phase or in carbon tetrachloride. Bromine monofluoride in ethanol readily leads to the monobromination...

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Plutonium

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135 °C the metal will ignite in air and will explode if placed in carbon tetrachloride. Plutonium is a reactive metal. In moist air or moist argon, the metal...

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Silicon

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discovery. The same year, Berzelius became the first to prepare silicon tetrachloride; silicon tetrafluoride had already been prepared long before in 1771...

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Protactinium

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It becomes superconductive at temperatures below 1.4 K. Protactinium tetrachloride is paramagnetic at room temperature, but becomes ferromagnetic when...

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