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Osmium compounds information


Oxidation states of osmium
−2 Na
2
[Os(CO)
4
]
−1 Na
2
[Os
4
(CO)
13
]
0 Os
3
(CO)
12
+1 OsI
+2 OsI
2
+3 OsBr
3
+4 OsO
2
, OsCl
4
+5 OsF
5
+6 OsF
6
+7 OsOF
5
+8 OsO
4
, Os(NCH
3
)
4

Osmium compounds are compounds containing the element osmium (Os). Osmium forms compounds with oxidation states ranging from −2 to +8. The most common oxidation states are +2, +3, +4, and +8. The +8 oxidation state is notable for being the highest attained by any chemical element aside from iridium's +9[1] and is encountered only in xenon,[2][3] ruthenium,[4] hassium,[5] iridium,[6] and plutonium.[7][8] The oxidation states −1 and −2 represented by the two reactive compounds Na
2
[Os
4
(CO)
13
]
and Na
2
[Os(CO)
4
]
are used in the synthesis of osmium cluster compounds.[9][10]

  1. ^ Stoye, Emma (23 October 2014). "Iridium forms compound in +9 oxidation state". Chemistry World. Royal Society of Chemistry.
  2. ^ Selig, H.; Claassen, H. H.; Chernick, C. L.; Malm, J. G.; et al. (1964). "Xenon tetroxide – Preparation + Some Properties". Science. 143 (3612): 1322–1323. Bibcode:1964Sci...143.1322S. doi:10.1126/science.143.3612.1322. JSTOR 1713238. PMID 17799234. S2CID 29205117.
  3. ^ Huston, J. L.; Studier, M. H.; Sloth, E. N. (1964). "Xenon tetroxide – Mass Spectrum". Science. 143 (3611): 1162–1163. Bibcode:1964Sci...143.1161H. doi:10.1126/science.143.3611.1161-a. JSTOR 1712675. PMID 17833897. S2CID 28547895.
  4. ^ Barnard, C. F. J. (2004). "Oxidation States of Ruthenium and Osmium". Platinum Metals Review. 48 (4): 157. doi:10.1595/147106704X10801.
  5. ^ "Chemistry of Hassium" (PDF). Gesellschaft für Schwerionenforschung mbH. 2002. Archived from the original (PDF) on 2012-01-14. Retrieved 2007-01-31.
  6. ^ Gong, Yu; Zhou, Mingfei; Kaupp, Martin; Riedel, Sebastian (2009). "Formation and Characterization of the Iridium Tetroxide Molecule with Iridium in the Oxidation State +VIII". Angewandte Chemie International Edition. 48 (42): 7879–7883. doi:10.1002/anie.200902733. PMID 19593837.[dead link]
  7. ^ Kiselev, Yu. M.; Nikonov, M. V.; Dolzhenko, V. D.; Ermilov, A. Yu.; Tananaev, I. G.; Myasoedov, B. F. (17 January 2014). "On existence and properties of plutonium(VIII) derivatives". Radiochimica Acta. 102 (3): 227–237. doi:10.1515/ract-2014-2146. S2CID 100915090.
  8. ^ Zaitsevskii, Andréi; Mosyagin, Nikolai S.; Titov, Anatoly V.; Kiselev, Yuri M. (21 July 2013). "Relativistic density functional theory modeling of plutonium and americium higher oxide molecules". The Journal of Chemical Physics. 139 (3): 034307. Bibcode:2013JChPh.139c4307Z. doi:10.1063/1.4813284. PMID 23883027.
  9. ^ Krause, J.; Siriwardane, Upali; Salupo, Terese A.; Wermer, Joseph R.; et al. (1993). "Preparation of [Os3(CO)11]2− and its reactions with Os3(CO)12; structures of [Et4N] [HOs3(CO)11] and H2OsS4(CO)". Journal of Organometallic Chemistry. 454 (1–2): 263–271. doi:10.1016/0022-328X(93)83250-Y.
  10. ^ Carter, Willie J.; Kelland, John W.; Okrasinski, Stanley J.; Warner, Keith E.; et al. (1982). "Mononuclear hydrido alkyl carbonyl complexes of osmium and their polynuclear derivatives". Inorganic Chemistry. 21 (11): 3955–3960. doi:10.1021/ic00141a019.

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Osmium dioxide is an inorganic compound with the formula OsO2. It exists as brown to black crystalline powder, but single crystals are golden and exhibit...

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Osmium hexafluoride, also osmium(VI) fluoride, (OsF6) is a compound of osmium and fluorine, and one of the seventeen known binary hexafluorides. Osmium...

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Osmium iodide refers to compounds of osmium with the formula OsIn. Several have been mentioned in the literature, but only the triiodide has been verified...

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Osmium tetrasulfide

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Osmium tetrasulfide is an inorganic compound, a salt of osmium metal and hydrogen sulfide acid with the chemical formula OsS4. Osmium tetrasulfide can...

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Potassium osmate

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Potassium osmate is the inorganic compound with the formula K2[OsO2(OH)4]. This diamagnetic purple salt contains osmium in the VI (6+) oxidation state....

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Osmium borides

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Osmium borides are compounds of osmium and boron. Their most remarkable property is potentially high hardness. It is thought that a combination of high...

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Osmium heptafluoride

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Osmium heptafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF 7. It was first reported in 1966 by the...

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Osmiridium

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Osmiridium and iridosmine are natural alloys of the elements osmium and iridium, with traces of other platinum-group metals. Osmiridium has been defined...

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Osmium diphosphide

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Osmium diphosphide is a binary inorganic compound of osmium metal and phosphorus with the chemical formula OsP2. Osmium diphosphide can be obtained by...

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Triosmium dodecacarbonyl

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chemical compound with the formula Os3(CO)12. This yellow-colored metal carbonyl cluster is an important precursor to organo-osmium compounds. Many of...

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Iridium

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group, it is considered the second-densest naturally occurring metal (after osmium) with a density of 22.56 g/cm3 (0.815 lb/cu in) as defined by experimental...

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Osmium octafluoride

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Osmium octafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF8. Some sources consider it to be a still...

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Ruthenium

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ruthenium range from 0 to +8, and −2. The properties of ruthenium and osmium compounds are often similar. The +2, +3, and +4 states are the most common. The...

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Ruthenium compounds

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states ranging from 0 to +8, and −2. The properties of ruthenium and osmium compounds are often similar. The +2, +3, and +4 states are the most common. The...

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Tungsten

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Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first...

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Osmium pentafluoride

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Osmium pentafluoride is an inorganic compound with the formula OsF5. It is a blue-green solid. Like the pentafluorides of Ru, Rh, and Ir, OsF5 exists...

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Triazine

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ligands have been used to bind three dinuclear arene ruthenium (or osmium) compounds to form metallaprisms. H. Deim; G. Matthias; R. A. Wagner (2012)....

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Hassium

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compared to osmium; without them, the trends would be reversed. Relativistic effects decrease the atomization energies of the compounds of hassium because...

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Osmium tetrabromide

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Osmium tetrabromide is the inorganic compound with the formula OsBr4. A black solid, this compound can be produced by heating osmium tetrachloride and...

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Tetramesityl compounds

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Iron

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ruthenium and osmium. Iron forms compounds in a wide range of oxidation states, −4 to +7. Iron also forms many coordination compounds; some of them,...

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