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Butyl group information


In organic chemistry, butyl is a four-carbon alkyl radical or substituent group with general chemical formula −C4H9, derived from either of the two isomers (n-butane and isobutane) of butane.

The isomer n-butane can connect in two ways, giving rise to two "-butyl" groups:

  • If it connects at one of the two terminal carbon atoms, it is normal butyl or n-butyl: −CH2−CH2−CH2−CH3 (preferred IUPAC name: butyl)
  • If it connects at one of the non-terminal (internal) carbon atoms, it is secondary butyl or sec-butyl: −CH(CH3)−CH2−CH3 (preferred IUPAC name: butan-2-yl)

The second isomer of butane, isobutane, can also connect in two ways, giving rise to two additional groups:

  • If it connects at one of the three terminal carbons, it is isobutyl: −CH2−CH(CH3)2 (preferred IUPAC name: 2-methylpropyl)
  • If it connects at the central carbon, it is tertiary butyl, tert-butyl or t-butyl: −C(CH3)3 (preferred IUPAC name: tert-butyl)

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Butyl group

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"-butyl" groups: If it connects at one of the two terminal carbon atoms, it is normal butyl or n-butyl: −CH2−CH2−CH2−CH3 (preferred IUPAC name: butyl)...

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Butyl ester

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Butyl ester may refer to: Butyl nitrite The family of organic chemical compounds containing an ester group and a butyl group including: Butyl acetate...

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Pentanenitrile

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valeronitrile or butyl cyanide is a nitrile with the formula C4H9CN. This can be written BuCN, with Bu representing an n-butyl (linear butyl group). Pentanenitrile...

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Butanol

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alcohol to a branched-chain tertiary alcohol; all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, 1-BuOH, i-BuOH, and...

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Butyl rubber

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Butyl rubber, sometimes just called "butyl", is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene...

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Ester

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hydrogen in the case of esters of formic acid. For example, butyl acetate (systematically butyl ethanoate), derived from butanol and acetic acid (systematically...

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Benzyl butyl phthalate

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Benzyl butyl phthalate (BBP) is an organic compound historically used a plasticizer, but which has now been largely phased out due to health concerns...

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A value

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A methyl group has an A-value of 1.74 while tert-butyl group has an A-value of ~5. Because the A-value of tert-butyl is higher, tert-butyl has a larger...

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Protecting group

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the amine group, and a tert-butyl ether on the phenol group. The benzyl ester can be removed by hydrogenolysis, the fluorenylmethylenoxy group (Fmoc) by...

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Skeletal formula

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for the secondary butyl group t-Bu or tBu for the tertiary butyl group Pn for the pentyl group (or Am for the synonymous amyl group, although Am is also...

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Electrophilic aromatic directing groups

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nitration. The methyl group in toluene is small and will lead the ortho product being the major product. On the other hand, the t-butyl group is very bulky (there...

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Tetrabutylammonium

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cation with the formula [N(C4H9)4]+, also denoted [NBu4]+ (where Bu = butyl group). It is used in the research laboratory to prepare lipophilic salts of...

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Labetalol

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attached to the amine becomes greater, particularly with respect to a t-butyl group, then the molecule typically is found to have receptor affinity without...

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C4mim

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C4mim is a shorthand for the 1-n-butyl-3-methylimidazolium cation; where C4 refers to the butyl group. It is also abbreviated Bmim, and (rarely) Bumim...

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