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Vibrational spectroscopy of linear molecules information


To determine the vibrational spectroscopy of linear molecules, the rotation and vibration of linear molecules are taken into account to predict which vibrational (normal) modes are active in the infrared spectrum and the Raman spectrum.

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Vibrational spectroscopy of linear molecules

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the vibrational spectroscopy of linear molecules, the rotation and vibration of linear molecules are taken into account to predict which vibrational (normal)...

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Infrared spectroscopy

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Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption...

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Molecular vibration

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giving vibrational fine structure to electronic transitions, particularly for molecules in the gas state. Simultaneous excitation of a vibration and rotations...

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Raman spectroscopy

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spectroscopy (/ˈrɑːmən/) (named after physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules,...

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Rotational spectroscopy

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simultaneously. For rotational spectroscopy, molecules are classified according to symmetry into spherical tops, linear molecules, and symmetric tops; analytical...

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Stimulated Raman spectroscopy

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opposed to spontaneous Raman spectroscopy, is a third-order non-linear phenomenon involving a second photon—the Stokes photon of angular frequency ω S {\displaystyle...

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Diatomic molecule

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Diatomic molecules (from Greek di- 'two') are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists...

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Spectroscopy

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Molecular Vibrational-rotational Spectra: Theory and Applications of High Resolution Infrared, Microwave, and Raman Spectroscopy of Polyatomic Molecules. Amsterdam:...

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Molecular geometry

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IR, microwave and Raman spectroscopy can give information about the molecule geometry from the details of the vibrational and rotational absorbance...

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Raman scattering

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molecule. For a linear molecule, the number of vibrational modes is 3N-5, whereas for a non-linear molecule the number of vibrational modes is 3N-6. Molecular...

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Triatomic molecule

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(ozone) and NO2. The vibrational modes of a triatomic molecule can be determined in specific cases. A symmetric linear molecule ABA can perform: Antisymmetric...

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Molecular symmetry

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molecular symmetry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is...

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Molecule

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of molecules (as in a crystal). Microwave spectroscopy commonly measures changes in the rotation of molecules, and can be used to identify molecules in...

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Circular dichroism

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transitions. Vibrational circular dichroism, which uses light from the infrared energy region, is used for structural studies of small organic molecules, and...

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Microwave spectroscopy

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analyzed the vibrational energy of this molecule and concluded that the vibrational energy would be split into pairs by the presence of these two equilibrium...

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Rovibronic coupling

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rotation/vibration-electron coupling, denotes the simultaneous interactions between rotational, vibrational, and electronic degrees of freedom in a molecule....

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Rotational partition function

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are quantized. For a diatomic molecule like CO or HCl, or a linear polyatomic molecule like OCS in its ground vibrational state, the allowed rotational...

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Rigid rotor

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rigid rotor is the linear rotor requiring only two angles to describe, for example of a diatomic molecule. More general molecules are 3-dimensional, such...

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Normal mode

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materials and boundary conditions. The most general motion of a linear system is a superposition of its normal modes. The modes are normal in the sense that...

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Physical organic chemistry

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zero-point vibrational state of the associated molecules, shorter and stronger bonds in molecules with heavier isotopes and longer, weaker bonds in molecules with...

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Sum frequency generation spectroscopy

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Generation Spectroscopy". Chen, Z.; Shen, Y.R.; Samorjai, G.A.; (2002) "Studies of polymer surfaces by sum frequency generation vibrational spectroscopy". Annual...

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Vibrational circular dichroism

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(1988). "Vibrational Circular Dichroism of Biopolymers". In E. D. Schmid; F. W. Schneider; F. Siebert (eds.). Spectroscopy of Biological Molecules New Advances...

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List of interstellar and circumstellar molecules

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involve more than one of these types of energy level e.g. ro-vibrational spectroscopy changes both the rotational and vibrational energy level. Occasionally...

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Energy level

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refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels...

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