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Physical organic chemistry information


Physical organic chemistry, a term coined by Louis Hammett in 1940, refers to a discipline of organic chemistry that focuses on the relationship between chemical structures and reactivity, in particular, applying experimental tools of physical chemistry to the study of organic molecules. Specific focal points of study include the rates of organic reactions, the relative chemical stabilities of the starting materials, reactive intermediates, transition states, and products of chemical reactions, and non-covalent aspects of solvation and molecular interactions that influence chemical reactivity. Such studies provide theoretical and practical frameworks to understand how changes in structure in solution or solid-state contexts impact reaction mechanism and rate for each organic reaction of interest.

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Physical organic chemistry

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Physical organic chemistry, a term coined by Louis Hammett in 1940, refers to a discipline of organic chemistry that focuses on the relationship between...

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Physical chemistry

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Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics...

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Organic chemistry

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Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds...

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Outline of chemistry

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expression. Bioorganic chemistry – combines organic chemistry and biochemistry toward biology. Biophysical chemistry – is a physical science that uses the...

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Journal of Physical Organic Chemistry

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Physical Organic Chemistry is a monthly peer-reviewed scientific journal, published since 1988 by John Wiley & Sons. It covers research in physical organic...

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The Journal of Physical Chemistry A

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The Journal of Physical Chemistry A is a scientific journal which reports research on the chemistry of molecules - including their dynamics, spectroscopy...

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Organic compound

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frequently considered organic, and fullerene chemistry is usually considered a branch of organic chemistry. The methods of organic synthesis have been applied...

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Outline of physical science

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many branches of physical science also study biological phenomena (organic chemistry, for example). The four main branches of physical science are astronomy...

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Medicinal chemistry

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and physical chemistry. Compounds used as medicines are most often organic compounds, which are often divided into the broad classes of small organic molecules...

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Chemistry

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Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical...

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Conjugated system

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Purdue: Chem 26505: Organic Chemistry I (Lipton) (LibreTexts ed.). Purdue University. P. Atkins and J. de Paula Physical Chemistry (8th ed., W.H.Freeman...

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Nomenclature of Organic Chemistry

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Nomenclature of Organic Chemistry, commonly referred to by chemists as the Blue Book, is a collection of recommendations on organic chemical nomenclature...

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Quantum chemistry

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Quantum chemistry, also called molecular quantum mechanics, is a branch of physical chemistry focused on the application of quantum mechanics to chemical...

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Electrophile

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mechanism. Vollhardt, K. Peter C.; Schore, Neil Eric (January 2014). Organic chemistry : structure and function (7th ed.). New York, NY. ISBN 978-1-4641-2027-5...

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Kinetic isotope effect

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{\text{KIE}}={\frac {k_{12}}{k_{13}}}=1.082\pm 0.008} In physical organic chemistry, a kinetic isotope effect (KIE) is the change in the reaction...

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Hyperconjugation

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In organic chemistry, hyperconjugation (σ-conjugation or no-bond resonance) refers to the delocalization of electrons with the participation of bonds...

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Inductive effect

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basic substituents is apparently reversed. Richard Daley (2005). Organic Chemistry, Part 1 of 1234567893. Lulu.com. pp. 58–. ISBN 978-1-304-67486-9....

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Polymer chemistry

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polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry, analytical chemistry, and physical chemistry...

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William von Eggers Doering

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half a century, he made numerous contributions to the field of physical organic chemistry. Having published his first scientific paper in 1939 and his last...

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Antiaromaticity

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PMID 22801355. S2CID 19920318. Anslyn, Eric V. (2006). Modern Physical Organic Chemistry. University Science Books. ISBN 978-1-891389-31-3. Breslow, Ronald;...

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Anomeric effect

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In organic chemistry, the anomeric effect or Edward-Lemieux effect (after J. T. Edward and Raymond Lemieux) is a stereoelectronic effect that describes...

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Frank Westheimer

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Westheimer did pioneering work in physical organic chemistry, applying techniques from physical to organic chemistry and integrating the two fields. He...

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Conformational isomerism

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28 October 2013. Anslyn, Eric; Dennis Dougherty (2006). Modern Physical Organic Chemistry. University Science. p. 95. ISBN 978-1891389313. Barton, Derek...

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Steric effects

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(see figure). Steric effects are critical to chemistry, biochemistry, and pharmacology. In organic chemistry, steric effects are nearly universal and affect...

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