Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Cyclopentadienyliron dicarbonyl dimer is an organometallic compound with the formula [(η5-C5H5)Fe(CO)2]2, often abbreviated to Cp2Fe2(CO)4, [CpFe(CO)2]2 or even Fp2, with the colloquial name "fip dimer". It is a dark reddish-purple crystalline solid, which is readily soluble in moderately polar organic solvents such as chloroform and pyridine, but less soluble in carbon tetrachloride and carbon disulfide. Cp2Fe2(CO)4 is insoluble in but stable toward water. Cp2Fe2(CO)4 is reasonably stable to storage under air and serves as a convenient starting material for accessing other Fp (CpFe(CO)2) derivatives (described below).[1]
^Kelly, William J. (2001). "Bis(dicarbonylcyclopentadienyliron)". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rb139. ISBN 0471936235.
and 15 Related for: Cyclopentadienyliron dicarbonyl dimer information
Cyclopentadienylirondicarbonyldimer is an organometallic compound with the formula [(η5-C5H5)Fe(CO)2]2, often abbreviated to Cp2Fe2(CO)4, [CpFe(CO)2]2...
as in ferraboranes. Cyclopentadienylirondicarbonyl iodide is synthesized by the reaction of cyclopentadienylirondicarbonyldimer with I2: Cp2Fe2(CO)4...
greatly benefited from its relevance to industry. Examples: Cyclopentadienylirondicarbonyldimer (C5H5)Fe(CO)2CH3, ferrocene Fe(C5H5)2, molybdenum hexacarbonyl...
complexes that exhibit this process are cobalt carbonyl and cyclopentadienylirondicarbonyldimer: Co2(μ-CO)2(CO)6 ⇌ Co2(μ-CO)2(CO)4(CO)2 (C5H5)2Fe2(μ-CO)2(CO)2...
with cyclopentadiene to give the dinuclear Fe(I) species cyclopentadienylirondicarbonyldimer ([FeCp(CO)2]2), often abbreviated as Fp2. Pyrolysis of Fp2...
dicyclopentadiene to form [Fe(C5H5)(CO)2]2, cyclopentadienylirondicarbonyldimer. This compound, called "Fp dimer" can be considered a hybrid of ferrocene...
is analogous to the route to the related Cp complex, see cyclopentadienylirondicarbonyldimer. Some Cp* complexes are prepared using silyl transfer: Cp*Li...
decarbonylation. Here decarbonylation accompanies the preparation of cyclopentadienylirondicarbonyldimer: 2 Fe ( CO ) 5 + C 10 H 12 ⟶ ( η 5 − C 5 H 5 ) 2 Fe 2 (...
or allyl. Compounds such as the cyclopentadienylirondicarbonyldimer and cyclopentadienylmolybdenumtricarbonyl dimer can be considered a special case...
Fp2 may refer to: Cyclopentadienylirondicarbonyldimer, an organometallic compound Fp2: an EEG electrode site according to the 10-20 system FP2: Beats...
of reactivity is analogous to that for the more popular cyclopentadienylirondicarbonyldimer. The Mn(I) compound BrMn(CO)5 is also the precursor to many...
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