Palladium hydride is palladium metal with hydrogen within its crystal lattice. Despite its name, it is not an ionic hydride but rather an alloy of palladium with metallic hydrogen that can be written PdHx. At room temperature, palladium hydrides may contain two crystalline phases, α and β (also called α′). Pure α-phase exists at x < 0.017 while pure β-phase exists at x > 0.58; intermediate x values correspond to α-β mixtures.[1]
Hydrogen absorption by palladium is reversible and therefore has been investigated for hydrogen storage.[2] Palladium electrodes have been used in some cold fusion experiments, under the theory that hydrogen can be "squeezed" between palladium atoms to help it fuse at lower temperatures than normal.
^Manchester, F. D.; San-Martin, A.; Pitre, J. M. (February 1994). "The H-Pd (hydrogen-palladium) System". Journal of Phase Equilibria. 15 (1): 62–83. doi:10.1007/BF02667685. S2CID 95343702.
^Grochala, Wojciech; Edwards, Peter P. (March 2004). "Thermal Decomposition of the Non-Interstitial Hydrides for the Storage and Production of Hydrogen". Chemical Reviews. 104 (3): 1283–1316. doi:10.1021/cr030691s. PMID 15008624.
Palladiumhydride is palladium metal with hydrogen within its crystal lattice. Despite its name, it is not an ionic hydride but rather an alloy of palladium...
are also called hydrides: water (H2O) is a hydride of oxygen, ammonia is a hydride of nitrogen, etc. For inorganic chemists, hydrides refer to compounds...
polonium in palladium or platinum that is saturated with hydrogen (see palladiumhydride) may be due to the formation and migration of polonium hydride. Polonium...
useful in carbon monoxide detectors. Palladium readily adsorbs hydrogen at room temperatures, forming palladiumhydride PdHx with x less than 1. While this...
draw the line between a mixture and a compound, as in the case of palladiumhydride. Broader definitions of chemicals or chemical substances can be found...
hydrogen and its isotopes can be absorbed in certain solids, including palladiumhydride, at high densities. This creates a high partial pressure, reducing...
component elements, but proportions that are not integral [e.g., for palladiumhydride, PdHx (0.02 < x < 0.58)]. Chemical compounds have a unique and defined...
PdCH2CH2OAc-containing intermediates. Beta-hydride elimination would generate vinyl acetate and a palladiumhydride, which would be oxidized to give hydroxide...
the gas. Palladium is used in many of these, because it selectively absorbs hydrogen gas and forms the compound palladiumhydride. Palladium-based sensors...
block do not form hydrides (the hydride gap) under standard temperature and pressure with the notable exception of palladium. Palladium can absorb up to...
potassium nitrate. Common fuels used are titanium, titanium(II) hydride, zirconium, zirconium hydride, and boron. The size of the fuel particles is determined...
of the stannane to give a stannyl palladiumhydride. RC2R' + HSnBu3 → RC(H)=C(SnBu3)R' Often, an excess of the hydride reagent is required since some is...
organometallic chemistry that deals with organic palladium compounds and their reactions. Palladium is often used as a catalyst in the reduction of alkenes...
into metal sponge, such as palladium black, platinum sponge, and spongy nickel. Metals such as osmium and palladiumhydride are metaphorically called "metal...
catalytic technologies. Metal hydrides, such as MgH2, NaAlH4, LiAlH4, LiH, LaNi5H6, TiFeH2, ammonia borane, and palladiumhydride represent sources of stored...
has recently investigated the insertion of molecular oxygen into palladium-hydride bonds, with results suggesting that this insertion reaction does not...
aldehyde by a silyl hydride with a palladium catalyst. Acid chlorides can be reduced to give aldehydes with sterically hindered hydride donors. The reducing...
Metal hydrides (sodium hydride, lithium aluminium hydride, uranium trihydride) Partially or fully alkylated derivatives of metal and nonmetal hydrides (diethylaluminium...
agents for the non-catalytic conversion to amines include lithium aluminium hydride, lithium borohydride, diborane, or elemental sodium in alcohol solvents...
thioester is reduced to an aldehyde by a silyl hydride in presence of a catalytic amount of palladium. This reaction was invented in 1990 by Tohru Fukuyama...
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