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Thorium dioxide information


Thorium dioxide
Names
IUPAC names
Thorium dioxide
Thorium(IV) oxide
Other names
Thoria
Thorium anhydride
Identifiers
CAS Number
  • 1314-20-1 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:37339
ChemSpider
  • 14124
ECHA InfoCard 100.013.842 Edit this at Wikidata
EC Number
  • 215-225-1
Gmelin Reference
141638
PubChem CID
  • 14808
UNII
  • 9XA7X17UQC checkY
UN number 2910 2909
CompTox Dashboard (EPA)
  • DTXSID0051657 Edit this at Wikidata
InChI
  • Key: ZCUFMDLYAMJYST-UHFFFAOYSA-N
  • InChI=1S/2O.Th
SMILES
  • O=[Th]=O
Properties
Chemical formula
ThO2
Molar mass 264.037 g/mol[1]
Appearance white solid[1]
Odor odorless
Density 10.0 g/cm3[1]
Melting point 3,350 °C (6,060 °F; 3,620 K)[1]
Boiling point 4,400 °C (7,950 °F; 4,670 K)[1]
Solubility in water
insoluble[1]
Solubility insoluble in alkali
slightly soluble in acid[1]
Magnetic susceptibility (χ)
−16.0·10−6 cm3/mol[2]
Refractive index (nD)
2.200 (thorianite)[3]
Structure
Crystal structure
Fluorite (cubic), cF12
Space group
Fm3m, No. 225
Lattice constant
a = 559.74(6) pm[4]
Coordination geometry
Tetrahedral (O2−); cubic (ThIV)
Thermochemistry
Std molar
entropy (S298)
65.2(2) J K−1 mol−1
Std enthalpy of
formation fH298)
−1226(4) kJ/mol
Hazards
GHS labelling:[5]
Pictograms
GHS06: ToxicGHS08: Health hazard
Signal word
Danger
Hazard statements
H301, H311, H331, H350, H373
Precautionary statements
P203, P260, P261, P264, P270, P271, P280, P301+P316, P302+P352, P304+P340, P316, P318, P319, P321, P330, P361+P364, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard RA: Radioactive. E.g. plutonium
2
0
0
Special hazard RA: Radioactive. E.g. plutonium
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
400 mg/kg
Related compounds
Other anions
Thorium(IV) sulfide
Other cations
Hafnium(IV) oxide
Cerium(IV) oxide
Related compounds
Protactinium(IV) oxide
Uranium(IV) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Thorium dioxide (ThO2), also called thorium(IV) oxide, is a crystalline solid, often white or yellow in colour. Also known as thoria, it is mainly a by-product of lanthanide and uranium production.[4] Thorianite is the name of the mineralogical form of thorium dioxide. It is moderately rare and crystallizes in an isometric system. The melting point of thorium oxide is 3300 °C – the highest of all known oxides. Only a few elements (including tungsten and carbon) and a few compounds (including tantalum carbide) have higher melting points.[6] All thorium compounds, including the dioxide, are radioactive because there are no stable isotopes of thorium.

  1. ^ a b c d e f g Haynes, p. 4.95
  2. ^ Haynes, p. 4.136
  3. ^ Haynes, p. 4.144
  4. ^ a b Yamashita, Toshiyuki; Nitani, Noriko; Tsuji, Toshihide; Inagaki, Hironitsu (1997). "Thermal expansions of NpO2 and some other actinide dioxides". J. Nucl. Mater. 245 (1): 72–78. Bibcode:1997JNuM..245...72Y. doi:10.1016/S0022-3115(96)00750-7.
  5. ^ "Thorium dioxide". pubchem.ncbi.nlm.nih.gov.
  6. ^ Emsley, John (2001). Nature's Building Blocks (Hardcover, First ed.). Oxford University Press. pp. 441. ISBN 978-0-19-850340-8.

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