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Uranium dioxide information


Uranium dioxide
Names
IUPAC names
Uranium dioxide
Uranium(IV) oxide
Other names
Urania
Uranous oxide
Identifiers
CAS Number
  • 1344-57-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10454 checkY
ECHA InfoCard 100.014.273 Edit this at Wikidata
EC Number
  • 215-700-3
PubChem CID
  • 10916
RTECS number
  • YR4705000
UNII
  • L70487KUZO checkY
CompTox Dashboard (EPA)
  • DTXSID8061682 Edit this at Wikidata
InChI
  • InChI=1S/2O.U
    Key: FCTBKIHDJGHPPO-UHFFFAOYSA-N
SMILES
  • O=[U]=O
Properties
Chemical formula
UO2
Molar mass 270.03 g/mol
Appearance black powder
Density 10.97 g/cm3
Melting point 2,865 °C (5,189 °F; 3,138 K)
Solubility in water
insoluble
Structure
Crystal structure
Fluorite (cubic), cF12
Space group
Fm3m, No. 225
Lattice constant
a = 547.1 pm [1]
Coordination geometry
Tetrahedral (O2−); cubic (UIV)
Thermochemistry
Std molar
entropy (S298)
78 J·mol−1·K−1[2]
Std enthalpy of
formation fH298)
−1084 kJ·mol−1[2]
Hazards
GHS labelling:
Pictograms
GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H300, H330, H373, H410
Precautionary statements
P260, P264, P270, P271, P273, P284, P301+P310, P304+P340, P310, P314, P320, P321, P330, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
4
0
0
OX
Flash point N/A
Safety data sheet (SDS) ICSC 1251
Related compounds
Other anions
Uranium(IV) sulfide
Uranium(IV) selenide
Other cations
Protactinium(IV) oxide
Neptunium(IV) oxide
Related uranium oxides
Triuranium octoxide
Uranium trioxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Uranium dioxide or uranium(IV) oxide (UO2), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear reactors. A mixture of uranium and plutonium dioxides is used as MOX fuel. Prior to 1960, it was used as yellow and black color in ceramic glazes and glass.

  1. ^ Leinders, Gregory; Cardinaels, Thomas; Binnemans, Koen; Verwerft, Marc (2015). "Accurate lattice parameter measurements of stoichiometric uranium dioxide". Journal of Nuclear Materials. 459: 135–42. Bibcode:2015JNuM..459..135L. doi:10.1016/j.jnucmat.2015.01.029. S2CID 97183844.
  2. ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A23. ISBN 978-0-618-94690-7.

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at the boundary between the uranium dioxide grains, but the majority of the fission products remain in the uranium dioxide as solid solutions. A paper...

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uranium sesquicarbide (U2C3, CAS number 12076-62-9), and uranium acetylide (UC2, CAS number 12071-33-9). Like uranium dioxide and some other uranium compounds...

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to leak into the environment. Spent uranium dioxide fuel is very insoluble in water, it is likely to release uranium (and fission products) even more slowly...

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said to be similar to that of uranium dioxide dihydrate. It is precipitated by adding aqueous ammonium hydroxide after uranium extraction by tertiary amines...

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