Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Sodium cyclopentadienide is an organosodium compound with the formula C5H5Na. The compound is often abbreviated as NaCp, where Cp− is the cyclopentadienide anion.[1] Sodium cyclopentadienide is a colorless solid, although samples often are pink owing to traces of oxidized impurities.[2]
^International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005). Cambridge (UK): RSC–IUPAC. ISBN 0-85404-438-8. p. 262. Electronic version.
^Cite error: The named reference Roesky was invoked but never defined (see the help page).
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Sodiumcyclopentadienide is an organosodium compound with the formula C5H5Na. The compound is often abbreviated as NaCp, where Cp− is the cyclopentadienide...
importance is sodiumcyclopentadienide. Sodium tetraphenylborate can also be classified as an organosodium compound since in the solid state sodium is bound...
anions). Some well-known derivatives include sodiumcyclopentadienide (NaC5H5) and trityl sodium ((C6H5)3CNa). Sodium naphthalene, Na+[C10H8•]−, a strong reducing...
common reagent for the preparation of cyclopentadienyl complexes. Sodiumcyclopentadienide Reent Michel; Regine Herbst-Irmer; Dietmar Stalke (2011). "Revealing...
original transmetalation sequence using either commercially available sodiumcyclopentadienide or freshly cracked cyclopentadiene deprotonated with potassium...
typically sodium hydride, sodium metal, and butyl lithium. Salts of this anion are commercially available, including sodiumcyclopentadienide and lithium...
can be obtained by reacting anhydrous yttrium(III) chloride and sodiumcyclopentadienide in tetrahydrofuran. It decomposes when exposed to water to produce...
commercially available. It may be synthesized by the reaction of sodiumcyclopentadienide with a lead(II) source such as lead(II) nitrate or lead(II) iodide...
importance is sodiumcyclopentadienide. Sodium tetraphenylborate can also be classified as an organosodium compound since in the solid state sodium is bound...
the aromatic conjugate base cyclopentadienyl anion, isolable as sodiumcyclopentadienide: 2 Na + 2 C5H6 → 2 NaC5H5 + H2 Aromatization can entail removal...
can be obtained by reacting anhydrous scandium(III) chloride and sodiumcyclopentadienide in tetrahydrofuran. If scandium(III) fluoride and magnesocene are...
110 °C and density 1.995 g/cm3. Reaction of a lead(II) source with sodiumcyclopentadienide gives the lead metallocene, plumbocene. Certain arene compounds...
compounds with transition metal chlorides. Sodiumcyclopentadienide (NaCp) and lithium cyclopentadienide are commonly used. Trimethylsilylcyclopentadiene...
Fischer carbene complexes: Treatment of chromium hexacarbonyl with sodiumcyclopentadienide gives Na+[Cr(CO)3(C5H5)]−. Oxidation of this salt affords...
anions). Some well-known derivatives include sodiumcyclopentadienide (NaC5H5) and trityl sodium ((C6H5)3CNa). Sodium naphthalene, Na+[C10H8•]−, a strong reducing...
compound is prepared by combining molybdenum pentachloride, sodiumcyclopentadienide, and sodium borohydride. The dihydride converts to molybdocene dichloride...
halides generally have very high lattice energies. For example, sodiumcyclopentadienide reacts with ferrous chloride to yield ferrocene: 2 NaC5H5 + FeCl2...
tetrachloride. The original synthesis by Wilkinson and Birmingham, using sodiumcyclopentadienide, is still commonly used: 2 NaC5H5 + TiCl4 → (C5H5)2TiCl2 + 2 NaCl...
prepared by the reaction of sodiumcyclopentadienide (NaC5H5) with anhydrous cobalt(II) chloride in THF solution. Sodium chloride is cogenerated, and...
compounds: Sodiumcyclopentadienide (NaCp) is the preferred reagent for these types of reactions. It is most easily obtained by the reaction of molten sodium and...
kinetically more robust. Treatment of tungsten hexacarbonyl with sodiumcyclopentadienide followed by oxidation of the resulting NaW(CO)3(C5H5) gives...
pentachloride was added to a solution of sodiumcyclopentadienide in tetrahydrofuran and an excess of sodium borohydride with yields reaching 60%, although...
Agency on Corruption Prevention, a government agency in Ukraine Sodiumcyclopentadienide (NaCp), a chemical compound This disambiguation page lists articles...
derivatives. These arise from the salt metathesis reactions of sodiumcyclopentadienide and tantalum pentachloride. An example of this is the first transition...
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