Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Titanocene dichloride is the organotitanium compound with the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common reagent in organometallic and organic synthesis. It exists as a bright red solid that slowly hydrolyzes in air.[2] It shows antitumour activity and was the first non-platinum complex to undergo clinical trials as a chemotherapy drug.[3]
^"Summary of Classification and Labelling". Retrieved 5 December 2021.
^Budaver, S., ed. (1989). The Merck Index (11th ed.). Merck & Co., Inc.
^Cite error: The named reference anti-cancer was invoked but never defined (see the help page).
and 25 Related for: Titanocene dichloride information
Titanocenedichloride is the organotitanium compound with the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common...
reduction of aldehydes. Cp2Ti(CO)2 is prepared by the reduction of titanocenedichloride with magnesium as a slurry in THT under an atmosphere of carbon...
Titanocene Y also known as bis[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dichloride or dichloridobis(η5-(p-methoxybenzyl)cyclopentadienyl)titanium...
1861, the first example was not reported until 1954. In that year titanocenedichloride was described by Wilkinson and Birmingham. Independently, titanium-based...
metallocenes are the metallocene derivatives, e.g. titanocenedichloride or vanadocene dichloride. Certain metallocenes and their derivatives exhibit...
ExCl2, to afford titanocenedichloride and various S5+x and S5Sex rings. Illustrative is the synthesis of S7 from disulfur dichloride: (C5H5)2TiS5 + S2Cl2...
Vanadocene dichloride is an organometallic complex with formula (η5-C5H5)2VCl2 (commonly abbreviated as Cp2VCl2). It is a structural analogue of titanocene dichloride...
is an aluminium-containing derivative of titanocene that arises from the reaction of titanocenedichloride with trimethylaluminium. It is used for the...
contiguous (connected to each other), the η-notation is used, as e.g. in titanocenedichloride: dichlorobis(η5-2,4-cyclopentadien-1-yl)titanium. Molecules with...
[Au(SH)2]− and (C5H5)2Ti(SH)2, derived from gold(I) chloride and titanocenedichloride, respectively. Bisulfide salts are corrosive, strongly alkaline...
some organic solvents. The lighter homologues zirconacene dichloride and titanocenedichloride have received much more attention. While hafnocene is only...
Molybdocene dichloride is the organomolybdenum compound with the formula (η5-C5H5)2MoCl2 and IUPAC name dichlorobis(η5-cyclopentadienyl)molybdenum(IV)...
HOMO in this class of complex. Unlike the related zirconacene and titanocenedichlorides, no applications have been found for this compound, although it...
intensively studied. The most common organotitanium complex is titanocenedichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and Petasis...
ketones, is prepared from TMA and titanocenedichloride. In combination with 20 to 100 mol % Cp2ZrCl2 (zirconocene dichloride), the (CH3)2Al-CH3 adds "across"...
Zirconocene dichloride is an organozirconium compound composed of a zirconium central atom, with two cyclopentadienyl and two chloro ligands. It is a colourless...
via salt metathesis reactions. Illustrative is the methylation of titanocenedichloride to give the Petasis reagent: (C5H5)2TiCl2 + 2 ClMgCH3 → (C5H5)2Ti(CH3)2...
metathesis reaction of methylmagnesium chloride or methyllithium with titanocenedichloride: Cp2TiCl2 + 2 CH3MgCl → Cp2Ti(CH3)2 + 2 MgCl2 This compound is used...
follows with preservation of conformation via elemental zinc or with titanocenedichloride. Protection through a Diels-Alder reaction: the transformation of...
photocatalytic approach was also developed: the use of catalytic titanocenedichloride in the presence of a red-absorbing organic dye as the photosensitizer...
completely inert. For example, attempts to prepare titanocene by reduction of titanocenedichloride affords complexes of fulvalene ligands. Bent metallocenes...
precursor to many organotitanium complexes. The complex is related to titanocenedichloride, which lacks the methyl groups. The complex is prepared by the reaction...
intensively studied. The most common organotitanium complex is titanocenedichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and Petasis...
hydrogen polysulfides with polysulfur dichloride: H2Sx + SyCl2 → cyclo-Sx+y + 2 HCl A second strategy uses titanocene pentasulfide as a source of the S2−5...
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