Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Tungsten hexacarbonyl (also called tungsten carbonyl) is an organometallic compound with the formula W(CO)6. This complex gave rise to the first example of a dihydrogen complex.[2]
Like its chromium and molybdenum analogs, this colorless compound is noteworthy as a volatile, air-stable derivative of tungsten in its zero oxidation state.
^Even, J.; Yakushev, A.; Dullmann, C. E.; Haba, H.; Asai, M.; Sato, T. K.; Brand, H.; Di Nitto, A.; Eichler, R.; Fan, F. L.; Hartmann, W.; Huang, M.; Jager, E.; Kaji, D.; Kanaya, J.; Kaneya, Y.; Khuyagbaatar, J.; Kindler, B.; Kratz, J. V.; Krier, J.; Kudou, Y.; Kurz, N.; Lommel, B.; Miyashita, S.; Morimoto, K.; Morita, K.; Murakami, M.; Nagame, Y.; Nitsche, H.; et al. (2014). "Synthesis and detection of a seaborgium carbonyl complex". Science. 345 (6203): 1491–3. Bibcode:2014Sci...345.1491E. doi:10.1126/science.1255720. PMID 25237098. S2CID 206558746. (subscription required)
^Kubas, G. J., Metal Dihydrogen and σ-Bond Complexes, Kluwer Academic/Plenum Publishers: New York, 2001
and 24 Related for: Tungsten hexacarbonyl information
Tungstenhexacarbonyl (also called tungsten carbonyl) is an organometallic compound with the formula W(CO)6. This complex gave rise to the first example...
hexacarbonyl (also called molybdenum carbonyl) is the chemical compound with the formula Mo(CO)6. This colorless solid, like its chromium, tungsten,...
hexacarbonyl (also called seaborgium carbonyl) is the organometallic compound with the formula Sg(CO)6. Like its chromium, molybdenum, and tungsten analogs...
Chromium hexacarbonyl (IUPAC name: hexacarbonylchromium) is a chromium(0) organometallic compound with the formula Cr(CO)6. It is a homoleptic complex...
Vanadium hexacarbonyl is the inorganic compound with the formula V(CO)6. It is a blue-black volatile solid. This highly reactive species is noteworthy...
chromium hexacarbonyl, molybdenum hexacarbonyl, and tungstenhexacarbonyl, seaborgium has been shown in 2014 to also form seaborgium hexacarbonyl, Sg(CO)6...
WBr(CO)2(PPh3)2≡C-NR2. Such a compound can be obtained by the reaction of tungstenhexacarbonyl W(CO)6 with lithium diisopropylamide to form (iPr2N)(OLi)C=W(CO)5...
FIB-assisted chemical vapor deposition occurs when a gas, such as tungstenhexacarbonyl (W(CO)6) is introduced to the vacuum chamber and allowed to chemisorb...
originally described process employed catalysts molybdenum hexacarbonyl, tungstenhexacarbonyl, and molybdenum oxide supported on alumina. Blay, Vincent;...
Job and A. Cassal succeed in the preparation of chromium hexacarbonyl and tungstenhexacarbonyl, the first synthesis of other homoleptic metal carbonyls...
described olefin disproportionation with catalysts molybdenum hexacarbonyl, tungstenhexacarbonyl, and molybdenum oxide supported on alumina for example converting...
Another method of producing this compound is by the reaction of tungstenhexacarbonyl and bromine at room temperature, releasing carbon monoxide. It can...
bond distance is 3.222 Å. The compound is prepared by treatment of tungstenhexacarbonyl with sodium cyclopentadienide followed by oxidation of the resulting...
characterized. [C70][S8]6 [C60][γ-cyclodextrin]2 C60 fullerene reacts with tungstenhexacarbonyl W(CO)6 to the (η²-C60)W(CO)5 complex in a hexane solution in direct...
demonstrated an ability to coordinate to metal atoms. UV irradiation of tungstenhexacarbonyl in the presence of the N-aluminylene created an aluminylene-W(CO)5...
of tungsten and silicon oxides at temperatures as high as 450 °C. In 1974 Mortreux reported the use of a homogeneous catalyst—molybdenum hexacarbonyl at...
distance is 3.2325 Å. The compound is prepared by treatment of molybdenum hexacarbonyl with sodium cyclopentadienide followed by oxidation of the resulting...
to the hexacarbonyls of molybdenum and tungsten: M(CO)6 + 4 MeCN + 2 NOBF4 → [M(NO)2(MeCN)4](BF4)2 Nitrosyl chloride and molybdenum hexacarbonyl react...
dimolybdenum compound. The compound is prepared by treatment of chromium hexacarbonyl with sodium cyclopentadienide followed by oxidation of the resulting...
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