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Selenium tetrachloride information


Selenium tetrachloride
Names
IUPAC name
Selenium tetrachloride
Other names
Selenium(IV) chloride, tetrachloro-λ4-selane
Identifiers
CAS Number
  • 10026-03-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 59590 checkY
ECHA InfoCard 100.030.036 Edit this at Wikidata
EC Number
  • 233-053-5
PubChem CID
  • 66205
RTECS number
  • VS7875000
UNII
  • 4GB8868P5J checkY
CompTox Dashboard (EPA)
  • DTXSID6064903 Edit this at Wikidata
InChI
  • InChI=1S/Cl4Se/c1-5(2,3)4 checkY
    Key: LNBXMNQCXXEHFT-UHFFFAOYSA-N checkY
  • InChI=1/Cl4Se/c1-5(2,3)4
    Key: LNBXMNQCXXEHFT-UHFFFAOYAD
SMILES
  • Cl[Se](Cl)(Cl)Cl
Properties
Chemical formula
SeCl4
Molar mass 220.771 g/mol
Appearance white to yellow crystals
Density 2.6 g/cm3, solid
Melting point sublimes at 191.4 °C[1]
Solubility in water
decomposes in water
Structure
Crystal structure
Monoclinic, mS80
Space group
C12/c1, No. 15
Molecular shape
Seesaw (gas phase)[citation needed]
Hazards[2]
GHS labelling:
Pictograms
GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H301, H331, H373, H410
Precautionary statements
P260, P261, P264, P270, P271, P273, P301+P310, P304+P340, P311, P314, P321, P330, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g. white phosphorusSpecial hazard W: Reacts with water in an unusual or dangerous manner. E.g. sodium, sulfuric acid
3
0
2
W
Flash point non-flammable
Related compounds
Other anions
Selenium tetrafluoride
Selenium tetrabromide
Selenium dioxide
Other cations
Dichlorine monoxide
Sulfur tetrachloride
Tellurium tetrachloride
Related compounds
Selenium dichloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Selenium tetrachloride is the inorganic compound composed with the formula SeCl4. This compound exists as yellow to white volatile solid. It is one of two commonly available selenium chlorides, the other example being selenium monochloride, Se2Cl2. SeCl4 is used in the synthesis of other selenium compounds.

  1. ^ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. p. 487. ISBN 0-8493-0594-2. Retrieved 2008-07-02.
  2. ^ "323527 Selenium tetrachloride". Sigma-Aldrich. Retrieved 2008-07-02.

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