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Perfluorohexane information


Perfluorohexane
Names
Preferred IUPAC name
Tetradecafluorohexane
Other names
FC-72,
Fluorinert FC-72,
Flutec PP1,
Perfluoro-compound FC-72
Identifiers
CAS Number
  • 355-42-0 checkY
3D model (JSmol)
  • Interactive image
Abbreviations PFH
ChEBI
  • CHEBI:39427 checkY
ChemSpider
  • 9262 checkY
ECHA InfoCard 100.005.987 Edit this at Wikidata
KEGG
  • D05437 checkY
PubChem CID
  • 9639
UNII
  • FX3WJ41CMX checkY
CompTox Dashboard (EPA)
  • DTXSID7046548 Edit this at Wikidata
InChI
  • InChI=1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20 checkY
    Key: ZJIJAJXFLBMLCK-UHFFFAOYSA-N checkY
  • InChI=1/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20
    Key: ZJIJAJXFLBMLCK-UHFFFAOYAE
SMILES
  • FC(F)(C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)F
Properties
Chemical formula
C6F14
Molar mass 338.041845
Appearance Clear, colorless
Odor Odorless
Density 1.680 kg/m3 (Liquid)
Melting point −90 °C (−130 °F; 183 K)
Boiling point 56 °C (133 °F; 329 K)
Vapor pressure 30.9 kPa (25 °C)
Thermal conductivity 0.057 W/(m·K)
Viscosity 0.64 cP
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
0
0
0
Lethal dose or concentration (LD, LC):
LD50 (median dose)
> 5 g/kg (rat, oral)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Perfluorohexane (C6F14), or tetradecafluorohexane, is a fluorocarbon. It is a derivative of hexane in which all the hydrogen atoms are replaced by fluorine atoms. It is used in one formulation of the electronic cooling liquid/insulator Fluorinert for low-temperature applications due to its low boiling point of 56 °C and freezing point of −90 °C. It is odorless and colorless. Unlike typical hydrocarbons, the structure features a helical carbon backbone.[1] In medical imaging it is used as a contrast agent.

  1. ^ John A. Gladysz and Markus Jurisch "Structural, Physical, and Chemical Properties of Fluorous Compounds" in István T. Horváth (Ed.) Topics in Current Chemistry 2011 "Fluorous Chemistry" doi:10.1007/128_2011_282

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Perfluorohexane

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Perfluorohexane (C6F14), or tetradecafluorohexane, is a fluorocarbon. It is a derivative of hexane in which all the hydrogen atoms are replaced by fluorine...

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Perfluorohexanesulfonic acid

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Organic Pollutants (1 October 2019). Risk management evaluation on perfluorohexane sulfonic acid (PFHxS), its salts and PFHxS-related compounds (addendum)...

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Fluorinert

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An example of one of the compounds 3M uses is FC-72 (perfluorohexane, C6F14). Perfluorohexane is used for low-temperature heat-transfer applications...

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Cyclodextrin

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surfaces. Using the host-guest interaction between β-Cyclodextrin and Perfluorohexane, acoustically active nanoparticles were created. These nanoparticles...

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Fluorocarbon

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is used as the source of fluorine. Illustrative is the synthesis of perfluorohexane: C6H14 + 28 CoF3 → C6F14 + 14 HF + 28 CoF2 The resulting cobalt difluoride...

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NFPA 704

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typical fire conditions (e.g., carbon tetrachloride, silicon dioxide, perfluorohexane), including intrinsically noncombustible materials such as concrete...

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Hexane

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has been discussed. n-Heptane is a possible alternative. Cyclohexane Perfluorohexane Hofmann, August Wilhelm Von (1 January 1867). "I. On the action of...

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List of refractive indices

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called fused quartz) 589.29 1.458 Other materials Liquid helium 1.025 Perfluorohexane (Fluorinert FC-72) 1.251 Water ice 1.31 TFE/PDD (Teflon AF) 1.315 Cryolite...

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Stockholm Convention on Persistent Organic Pollutants

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for the specified uses Utility poles and cross-arms A: Elimination Perfluorohexane sulfonic acid (PFHxS), its salts and PFHxS-related compounds various...

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Global warming potential

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– PFC-318 c-C4F8 10,300 Perfluouropentane – PFC-4-1-12 C5F12 9,160 Perfluorohexane – PFC-5-1-14 C6F14 9,300 Perfluorodecalin – PFC-9-1-18b C10F18 7,500...

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List of refrigerants

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C5F12 678-26-2 4,100 0 9,160 288 PFC R-5-1-14 Tetradecafluorohexane (Perfluorohexane) C6F14 355-42-0 3,200 0 9,300 338 56 CFC R-400 R-12/114(50/50 wt%)...

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Organofluorine chemistry

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attachment of perfluoroalkyl substituents that confer solubility in perfluorohexane as well as supercritical carbon dioxide. As a specific example, [(C8F17C3H6-4-C6H4)3P...

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Fluorous chemistry

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from organic solvents by extraction with fluorinated solvents such as perfluorohexane. The utility of fluorous chemistry hinges on the partitioning modality...

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Liquid breathing

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minimize lung damage. Vaporization of perfluorohexane with two anesthetic vaporizers calibrated for perfluorohexane has been shown to improve gas exchange...

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Fluorographene

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fluorographene is sp3 hybridized graphane. Similar to other fluorocarbons (e.g. perfluorohexane), fluorographene is highly insulating. Fluorographene is thermally...

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Perfluorooctanoic acid

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perfluorooctanoic acid (PFOA), perfluorooctane sulfonate (PFOS) and perfluorohexane sulfonate (PFHxS) in children and adults from Afghanistan". Sci. Total...

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Thermogravitational cycle

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working fluid that has low chemical affinity for the elastomer such as perfluorohexane (C6F14). It is attached to a strong NdFeB spherical magnet that acts...

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Expedition 52

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a Two Phase Flow experiment that studied interfacial behaviors of perfluorohexane, an electronic coolant, under different conditions. Fischer used the...

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Split and pool synthesis

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extraction using a fluorous solvent like perfluoromethylcyclohexane or perfluorohexane. It can be seen that the function of the Rf groups in the synthesis...

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In vitro maturation

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Joëlle; Sjunnesson, Ylva C.B. (April 2022). "Bovine oocyte exposure to perfluorohexane sulfonate (PFHxS) induces phenotypic, transcriptomic, and DNA methylation...

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Fowler process

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2 CoF2 + F2 → 2 CoF3 During the second stage, in this instance to make perfluorohexane, the hydrocarbon feed is introduced and is fluorinated by the cobalt(III)...

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