Palladium fluoride is the name of a series of binary compounds of palladium and fluorine. These include:
Palladium(II) fluoride or palladium difluoride, PdF2
Palladium(II,IV) fluoride or palladium trifluoride, PdF3. It is not palladium(III) fluoride (which is unknown), and is often described as palladium(II) hexafluoropalladate(IV), PdII[PdIVF6][1]
Palladium(IV) fluoride, or palladium tetrafluoride, PdF4
Palladium(VI) fluoride, or palladium hexafluoride, PdF6, which is calculated to be stable[2]
Palladium-fluorine coordination complexes have been developed to catalyse the synthesis of aryl fluorides, which are otherwise difficult to make.[3][4]
^Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1152–1153. ISBN 978-0-08-037941-8.
^Aullón, G.; Alvarez, S. (2007). "On the Existence of Molecular Palladium(VI) Compounds: Palladium Hexafluoride". Inorg. Chem.46 (7): 2700–2703. doi:10.1021/ic0623819. PMID 17326630.
^Grushin, V. V. (2002). "Palladium Fluoride Complexes: One More Step toward Metal-Mediated C-F Bond Formation". Chem. Eur. J.8 (5): 1006–1014. doi:10.1002/1521-3765(20020301)8:5<1006::AID-CHEM1006>3.0.CO;2-M. PMID 11891886.
^Watson, D. A.; Su, M.; Teverovskiy, G.; Zhang, Y.; García-Fortanet, J.; Kinzel, T.; Buchwald, S. L. (2009). "Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides". Science. 325 (5948): 1661–1664. Bibcode:2009Sci...325.1661W. doi:10.1126/science.1178239. PMC 3038120. PMID 19679769.
and 20 Related for: Palladium fluoride information
Palladiumfluoride is the name of a series of binary compounds of palladium and fluorine. These include: Palladium(II) fluoride or palladium difluoride...
Palladium (IV) fluoride, also known as palladium tetrafluoride, is the chemical compound of palladium and fluorine with the chemical formula PdF4. The...
compound. This is one of many palladiumfluorides. Fluorination of palladium powder with atomic fluoride at 900–1700 Pa. Palladium hexafluoride is predicted...
Perfluorobutanesulfonyl fluoride (nonafluorobutanesulfonyl fluoride, NfF) is a colorless, volatile liquid that is immiscible with water but soluble in...
Hiyama, to have reactivity when activated by a fluoride source. This reactivity, when combined with a palladium salt, creates a carbon-carbon bond with an...
but for larger palladium and platinum +6 is still "low". Note that aside from the molecular one, other forms of the highest fluorides are not considered...
such as atorvastatin and fluoxetine contain C−F bonds. The fluoride ion from dissolved fluoride salts inhibits dental cavities, and so finds use in toothpaste...
Fluoride volatility is the tendency of highly fluorinated molecules to vaporize at comparatively low temperatures. Heptafluorides, hexafluorides and pentafluorides...
original Suzuki coupling using palladium, including substrates such as phenols, aryl ethers, esters, phosphates, and fluorides. Investigation into the nickel...
products before 107Ag are palladium (element 46) isotopes, and the primary products after are cadmium (element 48) isotopes. The palladium isotope 107Pd decays...
include heating to drive off volatile elements, burning via oxidation, and fluoride volatility (which uses extremely reactive Fluorine). Each process results...
provide the other coupling partner. The Stille reaction is one of many palladium-catalyzed coupling reactions. R 1 − Sn ( Alkyl ) 3 + R 2 − X → ligand...
Because of its highly basic nature and its resistance to oxidation, the fluoride ligand stabilizes some metals in otherwise rare high oxidation states,...
structures, such as palladium chloride. Sodium chloride crystal structure Discrete UF6 molecules Infinite chains of one form of palladium chloride The halogens...
react with metals, they produce a wide range of salts, including calcium fluoride, sodium chloride (common table salt), silver bromide and potassium iodide...
→ (CH3)3CCO2H Such reactions require an acid catalyst such as hydrogen fluoride. tert-Butyl alcohol and isobutyl alcohol can also be used in place of isobutene...
more unusual. Fluoride ions form very strong bonds to silicon; thus silicon protecting groups are almost invariably removed by fluoride ions. Each type...
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