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Osmium heptafluoride information


Osmium heptafluoride
Names
Other names
Osmium(VII) fluoride
Identifiers
CAS Number
  • 16949-69-2
3D model (JSmol)
  • Interactive image
InChI
  • InChI=1S/7FH.Os/h7*1H;/q;;;;;;;+7/p-7
    Key: PYLQBEQBIUJFFB-UHFFFAOYSA-G
SMILES
  • F[Os](F)(F)(F)(F)(F)F
Properties
Chemical formula
F7Os
Molar mass 323.22 g·mol−1
Structure
Crystal structure
Pentagonal bipiramidal (calculated)[1]
Related compounds
Related compounds
Rhenium heptafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Osmium heptafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF
7
.[2][3] It was first reported in 1966 by the reaction of fluorine and osmium at 600 °C and 400 atm,[4] but later experiments can’t reproduce this compound.[5]

  1. ^ Bayerische Julius-Maximilians-Universität Würzburg (2006). The Highest Oxidation States of the 5d Transition Metals: a Quantum-Chemical Study (PDF) (Report). Chemical Society. Retrieved 2011-06-20.
  2. ^ "WebElements Periodic Table » Osmium » osmium heptafluoride". webelements.com. Retrieved 19 April 2023.
  3. ^ Hawkins, Donald T. (6 December 2012). Binary Fluorides: Free Molecular Structures and Force Fields A Bibliography (1957–1975). Springer Science & Business Media. p. 42. ISBN 978-1-4684-6147-3. Retrieved 19 April 2023.
  4. ^ Glemser, Oskar; Roesky, Herbert W.; Hellberg, Karl-Heinz; Werther, Heinz-Ulrich (1966). "Darstellung und Eigenschaften von Osmiumheptafluorid". Chemische Berichte. 99 (8). Wiley: 2652–2662. doi:10.1002/cber.19660990834. ISSN 0009-2940.
  5. ^ Shorafa, Hashem; Seppelt, Konrad (1 September 2006). "Osmium(VII) Fluorine Compounds". Inorganic Chemistry. 45 (19): 7929–7934. doi:10.1021/ic0608290. PMID 16961386.

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Osmium heptafluoride

Last Update:

Osmium heptafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF 7. It was first reported in 1966 by the...

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Rhenium heptafluoride

Last Update:

Rhenium heptafluoride is the compound with the formula ReF7. It is a yellow low melting solid and is the only thermally stable metal heptafluoride. It has...

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Osmium fluoride

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Osmium(VI) fluoride (osmium hexafluoride), OsF6 Osmium(VII) fluoride (osmium heptafluoride), OsF7 Osmium(VIII) fluoride (osmium octafluoride), OsF8 This...

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Fluorine compounds

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iridium heptafluoride (report of synthesis is being prepared), technetium heptafluoride, and osmium heptafluoride will also have this structure. Osmium octafluoride...

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List of inorganic compounds

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Nitrosylsulfuric acid – NOHSO4 Osmium hexafluoride – OsF6 Osmium tetroxide (osmium(VIII) oxide) – OsO4 Osmium trioxide (osmium(VI) oxide) – OsO3 Oxybis(tributyltin)...

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Iodine pentafluoride

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heptafluoride: IF5 + F2 → IF7 It has been used as a solvent for handling metal fluorides. For example, the reduction of osmium hexafluoride to osmium...

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Hypothetical chemical compound

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(e.g. tetra-tert-butylmethane, C(C(CH3)3)4, chlorine heptafluoride, ClF7, or bromine heptafluoride, BrF7) or bond stress (e.g. tetrahedrane C4H4). Others...

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List of CAS numbers by chemical compound

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OsI osmium(I) iodide 76758–38–8 OsI2 osmium(II) iodide 59201–57–9 OsI3 osmium(III) iodide 59201–58–0 OsO2 osmium(IV) oxide 12036–02–1 OsO4 osmium(VIII)...

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Roentgenium

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F2. Gold heptafluoride, AuF7, is known as a gold(V) difluorine complex AuF5·F2, which is lower in energy than a true gold(VII) heptafluoride would be;...

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Group 5 element

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an intermediate in the separation of Nb and Ta from the ores. This heptafluoride tends to form the oxopentafluoride more readily than does the tantalum...

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Glossary of chemical formulae

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16921-96-3 F7NS pentafluorosulfanyldifluoroamine 13693-10-2 F7Re rhenium heptafluoride 17029-21-9 F8Si3 octafluorotrisilane 14521-14-3 F10Mo2 molybdenum fluoride...

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Fluorine

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liquid MoF 6 and ReF 6, and gaseous WF 6. Rhenium heptafluoride, the only characterized metal heptafluoride, is a low-melting molecular solid with pentagonal...

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Group 7 element

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molecular binary metal oxide. Other examples are ruthenium(VIII) oxide and osmium(VIII) oxide. It adopts a centrosymmetric corner-shared bi-tetrahedral structure...

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Rhenium

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It is also one of the densest, exceeded only by platinum, iridium and osmium. Rhenium has a hexagonal close-packed crystal structure. Its usual commercial...

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Gold

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with its derivative anion, AuF−6, and its difluorine complex, gold heptafluoride, is the sole example of gold(V), the highest verified oxidation state...

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Niobium

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an intermediate in the separation of Nb and Ta from the ores. This heptafluoride tends to form the oxopentafluoride more readily than does the tantalum...

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Iodine

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more stable than those of bromine and chlorine, for example in iodine heptafluoride. The iodine molecule, I2, dissolves in CCl4 and aliphatic hydrocarbons...

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Oxidation state

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5-Aminotetrazole". J. Am. Chem. Soc. 76 (1): 290–291. doi:10.1021/ja01630a086. Gold heptafluoride is calculated to be the pentafluoride with a molecular F2 ligand. Himmel...

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