Study of chemical compounds containing carbon-silver chemical bonds
Structure of silver mesityl tetramer.
Organosilver chemistry is the study of organometallic compounds containing a carbon to silver chemical bond.[1] The theme is less developed than organocopper chemistry.
The first attempts in organosilver were recorded by Buckton in 1859[2] and by J. A. Wanklyn & L. Carius in 1861.[3] The synthesis of methyl silver was described by Semerano and Riccoboni[4] Poor thermal stability is reflected in decomposition temperatures of AgMe (-50 °C) versus CuMe (-15 °C) and PhAg (74 °C) vs PhCu (100 °C).[5]
^Pouwer, Rebecca H.; Williams, Craig M. (2010). "Silver Alkyls, Alkenyls, Aryls, and Alkynyls in Organic Synthesis". Silver in Organic Chemistry. pp. 1–41. doi:10.1002/9780470597521.ch1. ISBN 9780470597521.
^Buckton, G. B. (1859). "Untersuchungen über organische Metallverbindungen". Annalen der Chemie und Pharmacie. 109 (2): 218–227. doi:10.1002/jlac.18591090216.
^Wanklyn, J. A.; Carius, L. (1861). "10. Ueber eine neue Wasserstoffverbindung des Eisens". Annalen der Chemie und Pharmacie. 120 (1): 69. doi:10.1002/jlac.18611200107.
^Semerano, G.; Riccoboni, L. (1941). "Beitrag zur Kenntnis der metallorganischen Verbindungen, I. Mitteil.: Silbermethyl, Silber-äthyl und Silber-n-propyl". Berichte der Deutschen Chemischen Gesellschaft (A and B Series). 74 (7): 1089. doi:10.1002/cber.19410740703.
^Greenwood and Earnshaw, pp. 1199–200
and 28 Related for: Organosilver chemistry information
Organosilverchemistry is the study of organometallic compounds containing a carbon to silver chemical bond. The theme is less developed than organocopper...
arsenate) which is reddish brown. In one of the most famous reactions in chemistry, the addition of colorless aqueous silver nitrate to an equally colorless...
Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics...
and Chemical Bonding of the High-Temperature Phase of AgN3". Inorganic Chemistry. 46 (3): 907–916. doi:10.1021/ic061963n. PMID 17257034.{{cite journal}}:...
Phenylsilver is an organosilver compound with the chemical formula C6H5Ag. It is a white solid. The structure is a one-dimensional coordination polymer...
precipitate if I− is used. This reaction is commonly used in inorganic chemistry to abstract halides: Ag+ (aq) + X− (aq) → AgX(s) where X− = Cl− , Br−...
Glemser, H. Saur "Silver Iodide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1036-7...
Massey, A. G.; Thompson, N. R.; Johnson, B. F. G. (6 June 2016). The Chemistry of Copper, Silver and Gold: Pergamon International Library of Science...
fulminate International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005). Cambridge (UK): RSC–IUPAC...
qualitative inorganic analysis. Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0...
This paper triggered a large amount of research in fields of solid-state chemistry and physics, as well more specifically in silver halide photosensitivity...
precipitation of silver phosphate is useful in traditional analytical chemistry. Precipitation of silver phosphate is also used in silver staining of...
1021/ja00822a054 Wiberg, Egon; Holleman, Arnold Frederick (2001). Inorganic Chemistry. Elsevier. ISBN 0-12-352651-5. (1848), "On the formation of hyponitrite...
highest oxidation states of the transition metal elements". Coordination Chemistry Reviews. 253 (5–6): 606–24. doi:10.1016/j.ccr.2008.07.014. Greenwood and...
"silver nitride". Chemister. Edward S. Shanley, John L. Ennis (1991). "The Chemistry and Free Energy Formation of Silver Nitride". Ind. Eng. Chem. Res. 30...
Bestimmung und Trennung der Cyanate, Cyanide, Rhodanide und Sulfide in Fresenius' Journal of Analytical Chemistry 42 (1903) 77–95, doi:10.1007/BF01302741....
This reaction is important for two uses in the laboratory: in analytical chemistry it constitutes the basis for the Mohr method of argentometry, whereas...
and in C-H bond activation. Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0...
CF3SO2OAg + RX → CF3SO2OR + AgX (X = iodide usually) In coordination chemistry, the salt is also useful to replace halide ligands with the more labile...
agent. As a simple metal salt, it is a common chemical in basic inorganic chemistry experiments. It is light-sensitive, so it must be stored in tightly closed...
presence of perchlorate presents risks. It is used as a catalyst in organic chemistry. Silver perchlorate is created by heating a mixture of perchloric acid...
oxide in the presence of benzene. In the inorganic and organometallic chemistry laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4"...
Increasing Structural Dimensionality via M−M' and M···NC Interactions". Inorganic Chemistry. 41 (25): 6743–6753. doi:10.1021/ic025850p. PMID 12470070. v t e...
Ag2Cr2O7 (s) + 2 KNO3 (aq) Related complexes are used as oxidants in organic chemistry. For instance, tetrakis(pyridine)silver dichromate, [Ag2(py)4]2+[Cr2O7]2−...
compounds with carbon number 1 John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632. Zumdahl...
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