Organogermanium chemistry is the science of chemical species containing one or more C–Ge bonds. Germanium shares group 14 in the periodic table with carbon, silicon, tin and lead. Historically, organogermanes are considered as nucleophiles and the reactivity of them is between that of organosilicon and organotin compounds. Some organogermanes have enhanced reactivity compared with their organosilicon and organoboron analogues in some cross-coupling reactions.[1]
In general, organogermanium chemistry is much less well-developed than the other group-14 congeners, mainly because germanium is expensive.[2]
^Fricke, Christoph; Schoenebeck, Franziska (2020-11-17). "Organogermanes as Orthogonal Coupling Partners in Synthesis and Catalysis". Accounts of Chemical Research. 53 (11): 2715–2725. doi:10.1021/acs.accounts.0c00527. ISSN 0001-4842. PMID 33118804. S2CID 226044725.
^Akiyama Takahiko (2004). "Germanium in Organic Synthesis". In Yamamoto Hisashi; Oshima Koichiro (eds.). Main Group Metals in Organic Synthesis. ISBN 3-527-30508-4.
and 16 Related for: Organogermanium chemistry information
Organogermaniumchemistry is the science of chemical species containing one or more C–Ge bonds. Germanium shares group 14 in the periodic table with carbon...
element forms a large number of organogermanium compounds, such as tetraethylgermanium, useful in organometallic chemistry. Germanium is considered a technology-critical...
2008-08-20. Satge, Jacques (1984). "Reactive intermediates in organogermaniumchemistry". Pure Appl. Chem. 56 (1): 137–150. doi:10.1351/pac198456010137...
metalloids, germanium has an established organometallic chemistry (see Organogermaniumchemistry). Arsenic is a grey, metallic looking solid. It has a density...
organosulfur compounds Compounds of carbon with other group 14 elements: organogermanium compounds, organotin compounds, organolead compounds Silylenes, the...
H. H. (October 1962). "Boiling Points and Boiling Point Numbers of Organogermanium Compounds". Journal of Chemical & Engineering Data. 7 (4): 565–567...
the epitaxial growth of germanium by MOVPE or chemical beam epitaxy. Organogermanium precursors (e.g. isobutylgermane, alkylgermanium trichlorides, and...
compounds are uncommon, although more common than related divalent organogermanium and organosilicon compounds. The greater stabilization enjoyed by Sn(II)...
single bond, with two lone pairs for each lead atom (figure C). In the organogermanium compound (Scheme 1 in the reference), the effective bond order is also...
Asai Germanium Research Institute in Japan. It is a water-soluble organogermanium compound used as raw material in nutritional supplements. The compound...
as dark spots on the crystalline background. Recently, novel liquid organogermanium precursors, such as isobutylgermane (IBGe) and tetrakis(dimethylamino)germane...
million of soil. Germanium makes up 0.5 parts per trillion of seawater. Organogermanium compounds are also found in seawater. Germanium occurs in the human...
dihalomethanes, or neopentyl haldes they replace the halogen with hydrogen. Organogermanium compounds that can be produced include methyl germane, dimethyl germane...
CESR of Organogermanium, Organotin and Organolead Radicals. The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 1. The Chemistry of Functional...
thermodynamically favored for germylenes.[11] The key of germylene catalysis chemistry is to maintain a balance between oxidative addition and reductive elimination...
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