"Covalent" redirects here. For other uses, see Covalent (disambiguation).
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding.[1] For many molecules, the sharing of electrons allows each atom to attain the equivalent of a full valence shell, corresponding to a stable electronic configuration. In organic chemistry, covalent bonding is much more common than ionic bonding.
Covalent bonding also includes many kinds of interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, three-center two-electron bonds and three-center four-electron bonds.[2][3] The term covalent bond dates from 1939.[4] The prefix co- means jointly, associated in action, partnered to a lesser degree, etc.; thus a "co-valent bond", in essence, means that the atoms share "valence", such as is discussed in valence bond theory.
In the molecule H 2, the hydrogen atoms share the two electrons via covalent bonding.[5] Covalency is greatest between atoms of similar electronegativities. Thus, covalent bonding does not necessarily require that the two atoms be of the same elements, only that they be of comparable electronegativity. Covalent bonding that entails the sharing of electrons over more than two atoms is said to be delocalized.
^Whitten, Kenneth W.; Gailey, Kenneth D.; Davis, Raymond E. (1992). "7-3 Formation of covalent bonds". General Chemistry (4th ed.). Saunders College Publishing. p. 264. ISBN 0-03-072373-6.
^March, Jerry (1992). Advanced Organic Chemistry: Reactions, Mechanisms, and Structure. John Wiley & Sons. ISBN 0-471-60180-2.
^Gary L. Miessler; Donald Arthur Tarr (2004). Inorganic Chemistry. Prentice Hall. ISBN 0-13-035471-6.
A covalentbond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared...
coordinate covalentbond, also known as a dative bond, dipolar bond, or coordinate bond is a kind of two-center, two-electron covalentbond in which the...
covalent bonds. Also, the melting points of such covalent polymers and networks increase greatly. In a simplified view of an ionic bond, the bonding electron...
usually applied to covalent bonds, that is, bonds where the polarity is not complete. To determine the polarity of a covalentbond using numerical means...
chemistry, a double bond is a covalentbond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur...
triple bond in chemistry is a chemical bond between two atoms involving six bonding electrons instead of the usual two in a covalent single bond. Triple...
ionic compounds. It is one of the main types of bonding, along with covalentbonding and metallic bonding. Ions are atoms (or groups of atoms) with an electrostatic...
The covalent radius, rcov, is a measure of the size of an atom that forms part of one covalentbond. It is usually measured either in picometres (pm)...
structurally consist of continuous two-dimensional sheets covalently bonded within the layer, with other bond types holding the layers together. Disordered network...
chemistry, a hydrogen bond (or H-bond) is primarily an electrostatic force of attraction between a hydrogen (H) atom which is covalently bonded to a more electronegative...
bond theory into computer programs, have been solved largely, and valence bond theory has seen a resurgence. According to this theory a covalentbond...
The covalentbond classification (CBC) method, also referred to as LXZ notation, is a way of describing covalent compounds such as organometallic complexes...
the single bond. A covalentbond can also be a double bond or a triple bond. A single bond is weaker than either a double bond or a triple bond. This difference...
pairs form a crystal structure with metallic bonding between them. Another example of a metal–metal covalentbond is the mercurous ion (Hg2+ 2). As chemistry...
forces – the forces which hold a molecule together. For example, the covalentbond, involving sharing electron pairs between atoms, is much stronger than...
present between non-bonding atoms or molecules. The classical model identifies three main types of chemical bonds — ionic, covalent, and metallic — distinguished...
formation of a chemical bond if the outermost shell is not closed. In a single covalentbond, a shared pair forms with both atoms in the bond each contributing...
together by metallic bonding, others point out that metals behave very differently than molecules. A covalentbond is a chemical bond that involves the sharing...
chemistry, bond order is a formal measure of the multiplicity of a covalentbond between two atoms. As introduced by Linus Pauling, bond order is defined...
In organic chemistry, a peptide bond is an amide type of covalent chemical bond linking two consecutive alpha-amino acids from C1 (carbon number one)...
In organic chemistry, a bent bond, also known as a banana bond, is a type of covalent chemical bond with a geometry somewhat reminiscent of a banana. The...
are the strongest type of covalent chemical bond. They are formed by head-on overlapping between atomic orbitals. Sigma bonding is most simply defined for...
called nitriles. In nitriles, the −C≡N group is linked by a single covalentbond to carbon. For example, in acetonitrile (CH3−C≡N), the cyanide group...