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Molybdate information


Structure of molybdate
3D model of the molybdate ion

In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of 6: O−Mo(=O)2−O. Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state. The larger oxyanions are members of group of compounds termed polyoxometalates, and because they contain only one type of metal atom are often called isopolymetalates.[1] The discrete molybdenum oxyanions range in size from the simplest MoO2−
4
, found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6. Chromium only forms the chromates, CrO2−
4
, Cr
2
O2−
7
, Cr
3
O2−
10
and Cr
4
O2−
13
ions which are all based on tetrahedral chromium. Tungsten is similar to molybdenum and forms many tungstates containing 6 coordinate tungsten.[2]

  1. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  2. ^ Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999), Advanced Inorganic Chemistry (6th ed.), New York: Wiley-Interscience, ISBN 0-471-19957-5

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Molybdate

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In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of 6: O−−Mo(=O)2−O−. Molybdenum can form...

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Sodium molybdate

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Sodium molybdate, Na2MoO4, is useful as a source of molybdenum. This white, crystalline salt is often encountered as the dihydrate, Na2MoO4·2H2O. Dissolution...

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Zinc molybdate

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Zinc molybdate is an inorganic compound with the formula ZnMoO4. It is used as a white pigment, which that is also a corrosion inhibitor. A related pigment...

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Lithium molybdate

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Lithium molybdate (Li2MoO4) is a chemical compound. It is mainly used as an inhibitor in some types of industrial air conditioning. Lithium molybdate is used...

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Ammonium molybdate

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Ammonium molybdate can refer to: Ammonium orthomolybdate, (NH4)2MoO4 Ammonium heptamolybdate, (NH4)6Mo7O24, usually encountered as the tetrahydrate Ammonium...

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Molybdopterin molybdotransferase

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adenylyl-molybdopterin:molybdate molybdate transferase (AMP-forming). This enzyme catalyses the following chemical reaction adenylyl-molybdopterin + molybdate ⇌ {\displaystyle...

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Ammonium heptamolybdate

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referred to as ammonium paramolybdate or simply as ammonium molybdate, although "ammonium molybdate" can also refer to ammonium orthomolybdate, (NH4)2MoO4...

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Ammonium orthomolybdate

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Ammonium orthomolybdate Names Other names Diammonium molybdate Identifiers CAS Number 13106-76-8 3D model (JSmol) Interactive image ChEBI CHEBI:91249 Y...

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Neodymium molybdate

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Neodymium molybdate is an inorganic compound, with the chemical formula of Nd2(MoO4)3. It can be prepared by reacting neodymium oxide and molybdenum trioxide...

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Wulfenite

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Wulfenite is a lead molybdate mineral with the formula PbMoO4. It often occurs as thin tabular crystals with a bright orange-red to yellow-orange color...

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Molybdenum

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when molybdenum-bearing minerals contact oxygen and water, the resulting molybdate ion MoO2− 4 is quite soluble. Industrially, molybdenum compounds (about...

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Aluminium molybdate

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Aluminium molybdate is the chemical compound Al2(MoO4)3. It forms in certain hydrodesulfurization catalysts when alumina is doped with excess molybdenum...

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Froehde reagent

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as other compounds. It is composed of a mixture of molybdic acid or a molybdate salt dissolved in hot, concentrated sulfuric acid, which is then dripped...

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Silver molybdate

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Silver molybdate (Ag2MoO4), a chemical compound, is a yellow, cubic crystalline substance often used in glass. Its crystals present two types of electronic...

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Molybdenite

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by froth flotation, and then oxidized to form soluble molybdate. Reduction of ammonium molybdate yields pure molybdenum metal, which is used for fertilizer...

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Formaldehyde

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silver metal, iron(III) oxide, iron molybdenum oxides [e.g. iron(III) molybdate] with a molybdenum-enriched surface, or vanadium oxides. In the commonly...

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Zinc

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Zn(NO3) 2, chlorate Zn(ClO3) 2, sulfate ZnSO 4, phosphate Zn 3(PO4) 2, molybdate ZnMoO 4, cyanide Zn(CN) 2, arsenite Zn(AsO2) 2, arsenate Zn(AsO4) 2·8H...

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Molybdenum trioxide

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of the dihydrate entails acidification of aqueous solutions of sodium molybdate with perchloric acid: Na2MoO4 + H2O + 2 HClO4 → MoO3·2H2O + 2 NaClO4 The...

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Oxyanion

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form MoO6− 6, but forms the tetrahedral molybdate anion, MoO2− 4. MoO6 units are found in condensed molybdates. Fully protonated oxyanions with an octahedral...

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Tungstate

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Tungstates occur naturally with molybdates. Scheelite, the mineral calcium tungstate, often contains a small amount of molybdate. Wolframite is manganese and...

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Median lethal dose

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original on 2017-07-02. Retrieved 2016-12-31. "Safety (MSDS) data for sodium molybdate". ox.ac.uk. Archived from the original on 2011-01-28. "Safety (MSDS) data...

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Soil

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Mg Mg2+ Boron B H3BO3, H 2BO− 3, B(OH)− 4 Manganese Mn Mn2+ Copper Cu Cu2+ Zinc Zn Zn2+ Molybdenum Mo MoO2− 4 (molybdate) Chlorine Cl Cl− (chloride)...

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Sodium hypochlorite

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cobalt, and iridium. Catalysts like sodium dichromate Na2Cr2O7 and sodium molybdate Na2MoO4 may be added industrially to reduce the oxygen pathway, but a...

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