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Isobutylene information


Isobutylene
Skeletal formula of isobutylene
Ball-and-stick model of isobutylene
Ball-and-stick model of isobutylene
Space-filling model of isobutylene
Space-filling model of isobutylene
Names
Preferred IUPAC name
2-Methylprop-1-ene
Other names
2-Methylpropene
Isobutene
γ-Butylene
2-Methylpropylene
Methylpropene
Identifiers
CAS Number
  • 115-11-7 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:43907 ☒N
ChemSpider
  • 7957 checkY
ECHA InfoCard 100.003.697 Edit this at Wikidata
EC Number
  • 204-066-3
PubChem CID
  • 8255
RTECS number
  • UD0890000
UNII
  • QA2LMR467H checkY
UN number 1055
In Liquefied petroleum gas: 1075
CompTox Dashboard (EPA)
  • DTXSID9020748 Edit this at Wikidata
InChI
  • InChI=1S/C4H8/c1-4(2)3/h1H2,2-3H3 checkY
    Key: VQTUBCCKSQIDNK-UHFFFAOYSA-N checkY
  • InChI=1/C4H8/c1-4(2)3/h1H2,2-3H3
SMILES
  • CC(=C)C
Properties[1]
Chemical formula
C4H8
Molar mass 56.106 g/mol
Appearance Colorless gas
Density 0.5879 g/cm3, liquid
Melting point −140.3 °C (−220.5 °F; 132.8 K)
Boiling point −6.9 °C (19.6 °F; 266.2 K)
Magnetic susceptibility (χ)
-44.4·10−6 cm3/mol
Hazards[2]
GHS labelling:
Pictograms
Flam. Gas 1Press. Gas
Signal word
Danger
Hazard statements
H220
Precautionary statements
P210, P377, P381, P403
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
4
0
Flash point flammable gas
Autoignition
temperature
465 °C (869 °F; 738 K)
Explosive limits 1.8–9.6%
Related compounds
Related butenes
1-Butene
cis-2-Butene
trans-2-Butene
Related compounds
Isobutane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Isobutylene (or 2-methylpropene) is a hydrocarbon with the chemical formula (CH3)2C=CH2. It is a four-carbon branched alkene (olefin), one of the four isomers of butylene. It is a colorless flammable gas, and is of considerable industrial value.[3]

  1. ^ The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals (11th ed.), Merck, 1989, ISBN 091191028X, 5024.
  2. ^ Isobutene, International Chemical Safety Card 1027, Geneva: International Programme on Chemical Safety, April 2000
  3. ^ Geilen, Frank M.A.; Stochniol, Guido; Peitz, Stephan; Schulte-Koerne, Ekkehard (2014). "Butenes". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a04_483.pub3. ISBN 978-3527306732.

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Isobutylene

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Isobutylene (or 2-methylpropene) is a hydrocarbon with the chemical formula (CH3)2C=CH2. It is a four-carbon branched alkene (olefin), one of the four...

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Methyl methacrylate

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CH2=C(CH3)CO2CH3 + H2O A process using isobutylene as a raw material has been commercialized by Escambia Co. Isobutylene is oxidized to provide α-hydroxy isobutyric...

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Butyl rubber is made by cationic polymerisation of isobutylene with about 2 - 7% isoprene. Isobutylene is also used for the production of methyl tert-butyl...

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~1,000,000 Names Other names Polyisobutylene; Poly(isobutene); Poly(isobutylene); PIB Identifiers CAS Number 9003-27-4 Y ChEBI CHEBI:53725 ECHA InfoCard...

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Raffinate

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1,3-butadiene from C4 raffinate stream and which, mainly consists of isobutylene 40~50 wt% and cis- or trans-2-butene 30~35 wt%. Normally C4R1 is a side...

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Polybutene

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is an organic polymer made from a mixture of 1-butene, 2-butene, and isobutylene. Ethylene steam cracker C4s are also used as supplemental feed for polybutene...

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Pentene

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vacuum gas oil (VGO) as a feedstock to produce primarily propylene, isobutylene, and isoamylene. The rise in demand for polypropylene has encouraged...

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Petrochemical

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amine butene isomers of butylene – useful as monomers or co-monomers isobutylene – feed for making methyl tert-butyl ether (MTBE) or monomer for copolymerization...

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Butyl rubber

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is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene isoprene rubber. Polyisobutylene, also known...

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route to methacrylic acid starts with isobutylene, which obtainable by dehydration of tert-butanol. Isobutylene is oxidized sequentially to methacrolein...

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Living cationic polymerization

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trichloride polymerization (then called quasi-living) in 1982 and that of isobutylene (system with cumyl acetate, 2,4,4-trimethylpentane-2-acetate and BCl3)...

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Phenols

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tert-butyl phenols are produced annually (year: 2000) in this way, using isobutylene (CH2=CMe2) as the alkylating agent. Especially important is 2,6-ditert-butylphenol...

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Butanediol

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1-Butanediol, hydrate of butanal 2,2-Butanediol, hydrate of butanone Isobutylene glycol may be considered a kind of butylene glycol, similarly to butane...

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Ray McIntire

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combined styrene with isobutylene, he created a unique material that was solid yet flexible due to the tiny bubbles formed by isobutylene within the styrene...

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Sulfuric acid

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refining, for example as a catalyst for the reaction of isobutane with isobutylene to give isooctane, a compound that raises the octane rating of gasoline...

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C4H8

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g/mol) may refer to: Butenes (butylenes) 1-Butene, or 1-butylene 2-Butene Isobutylene Cyclobutane Methylcyclopropane This set index page lists chemical structure...

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Butyl group

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introduce the tBu group to a hydroxyl group is by treating the compound with isobutylene in the presence of a Brønsted acid or Lewis acid. Various acids can be...

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Butane

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gases). The others include propane, propylene, butadiene, butylene, isobutylene, and mixtures thereof. Butane burns more cleanly than both gasoline and...

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Chewing gum

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chocolate Nispero Rosidinha Venezuelan chicle Butadiene-styrene rubber Isobutylene-isoprene copolymer (butyl rubber) Paraffin (via the Fischer–Tropsch process)...

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Fawley Refinery

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Fawley. It is used to line tyres. The isobutylene feedstock for the polymers plant comes from the isobutylene plant. The solid halobutyl rubber is formed...

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Carboxylic acid

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for alkenes that generate secondary and tertiary carbocations, e.g. isobutylene to pivalic acid. In the Koch reaction, the addition of water and carbon...

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Steric effects

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Monomer Ceiling temperature (°C) Structure ethylene 610 CH2=CH2 isobutylene 175 CH2=CMe2 1,3-butadiene 585 CH2=CHCH=CH2 isoprene 466 CH2=C(Me)CH=CH2 styrene...

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Butylated hydroxyanisole

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3-tert-butyl-4-hydroxyanisole. It is prepared from 4-methoxyphenol and isobutylene. The conjugated aromatic ring of BHA is able to stabilize free radicals...

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Ineos

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liquids, polypropylene, propane, and propylene Oligomers DIB, the dimer of isobutylene (isoolefins/isoparafins), IA (isoamylene/TAME), linear alpha olefins...

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